Artículo

Noble, J.A.; Broquier, M.; Grégoire, G.; Soorkia, S.; Pino, G.; Marceca, E.; Dedonder-Lardeux, C.; Jouvet, C. "Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene" (2018) Physical Chemistry Chemical Physics. 20(9):6134-6145
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Abstract:

Experimental and theoretical investigations of the excited states of protonated 1- and 2-aminonaphthalene are presented. The electronic spectra are obtained by laser induced photofragmentation of the ions captured in a cold ion trap. Using ab initio calculations, the electronic spectra can be assigned to different tautomers which have the proton on the amino group or on the naphthalene moiety. It is shown that the tautomer distribution can be varied by changing the electrospray source conditions, favoring either the most stable form in solution (amino protonation) or that in the gas phase (aromatic ring protonation). Calculations for larger amino-polyaromatics predict that these systems should behave as "proton sponges" i.e. have a proton affinity larger than 11 eV. © 2018 the Owner Societies.

Registro:

Documento: Artículo
Título:Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene
Autor:Noble, J.A.; Broquier, M.; Grégoire, G.; Soorkia, S.; Pino, G.; Marceca, E.; Dedonder-Lardeux, C.; Jouvet, C.
Filiación:CNRS, Aix Marseille Université, Physique des Interactions Ioniques et Moléculaires, UMR 7345, Marseille, 13397, France
CNRS, Univ. Paris-Sud, Université Paris-Saclay, Institut des Sciences Moléculaires d'Orsay (ISMO), Orsay, F-91405, France
Univ. Paris-Sud, CNRS, IOGS, Université Paris-Saclay, Centre Laser de l'Université Paris-Sud (CLUPS/LUMAT), Orsay, F-91405, France
INFIQC (CONICET-Universidad Nacional de Cordoba), Ciudad Universitaria, Cordoba, X5000HUA, Argentina
Dpto. de Fisicoquimica, Facultad de Ciencias Quimicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Cordoba, X5000HUA, Argentina
Centro Laser de Ciencias Moleculares, Universidad Nacional de Cordoba, Ciudad Universitaria, Cordoba, X5000HUA, Argentina
INQUIMAE (CONICET-Universidad de Buenos Aires), DQIAQF-Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, 3er piso, Pab. II, Buenos Aires, 1428, Argentina
Año:2018
Volumen:20
Número:9
Página de inicio:6134
Página de fin:6145
DOI: http://dx.doi.org/10.1039/c8cp00218e
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v20_n9_p6134_Noble

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Citas:

---------- APA ----------
Noble, J.A., Broquier, M., Grégoire, G., Soorkia, S., Pino, G., Marceca, E., Dedonder-Lardeux, C.,..., Jouvet, C. (2018) . Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene. Physical Chemistry Chemical Physics, 20(9), 6134-6145.
http://dx.doi.org/10.1039/c8cp00218e
---------- CHICAGO ----------
Noble, J.A., Broquier, M., Grégoire, G., Soorkia, S., Pino, G., Marceca, E., et al. "Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene" . Physical Chemistry Chemical Physics 20, no. 9 (2018) : 6134-6145.
http://dx.doi.org/10.1039/c8cp00218e
---------- MLA ----------
Noble, J.A., Broquier, M., Grégoire, G., Soorkia, S., Pino, G., Marceca, E., et al. "Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene" . Physical Chemistry Chemical Physics, vol. 20, no. 9, 2018, pp. 6134-6145.
http://dx.doi.org/10.1039/c8cp00218e
---------- VANCOUVER ----------
Noble, J.A., Broquier, M., Grégoire, G., Soorkia, S., Pino, G., Marceca, E., et al. Tautomerism and electronic spectroscopy of protonated 1- and 2-aminonaphthalene. Phys. Chem. Chem. Phys. 2018;20(9):6134-6145.
http://dx.doi.org/10.1039/c8cp00218e