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Cadranel, A.; Tate, J.E.; Oviedo, P.S.; Yamazaki, S.; Hodak, J.H.; Baraldo, L.M.; Kleiman, V.D. "Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization" (2017) Physical Chemistry Chemical Physics. 19(4):2882-2893
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Abstract:

Multi-metallic complexes based on {Ru-Cr}, {Ru-Ru} and {Ru-Ru-Cr} fragments are investigated for their light-harvesting and long-range energy transfer properties. We report the synthesis and characterization of [Ru(tpy)(bpy)(μ-CN)Ru(py)4Cl]2+ and [Ru(tpy)(bpy)(μ-CN)Ru(py)4(μ-NC)Cr(CN)5]. The intercalation of {RuII(py)4} linked by cyanide bridges between {Ru(tpy)(bpy)} and {Cr(CN)5} results in efficient, distant energy transfer followed by emission from the Cr moiety. Characterization of the energy transfer process based on photophysical and ultrafast time-resolved absorption suggests the delocalization of holes in the excited state, providing a pathway for energy transfer between the end moieties. The proposed mechanism opens the door to utilize this family of complexes as an appealing platform for the design of antenna compounds as the properties of the fragments could be tuned independently. © 2017 the Owner Societies.

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Documento: Artículo
Título:Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization
Autor:Cadranel, A.; Tate, J.E.; Oviedo, P.S.; Yamazaki, S.; Hodak, J.H.; Baraldo, L.M.; Kleiman, V.D.
Filiación:Departamento de Química Analítica, Inorgánica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Department of Chemistry, University of Florida, PO BOX 117200, Gainesville, FL 32611-7200, United States
Año:2017
Volumen:19
Número:4
Página de inicio:2882
Página de fin:2893
DOI: http://dx.doi.org/10.1039/c6cp06562g
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v19_n4_p2882_Cadranel

Referencias:

  • Harriman, A., Hissler, M., Trompette, O., Ziessel, R., (1999) J. Am. Chem. Soc., 121, pp. 2516-2525
  • Balzani, V., Credi, A., Venturi, M., (2008) ChemSusChem, 1, pp. 26-58
  • Furue, M., Naiki, M., Kanematsu, Y., Kushida, T., Kamachi, M., (1991) Coord. Chem. Rev., 111, pp. 221-226
  • Knight, T.E., Guo, D., Claude, J.P., McCusker, J.K., (2008) Inorg. Chem., 47, pp. 7249-7261
  • Xi, B., Liu, I.P.C., Xu, G.L., Choudhuri, M.M.R., Derosa, M.C., Crutchley, R.J., Ren, T., (2011) J. Am. Chem. Soc., 133, pp. 15094-15104
  • Gagliardo, M., Rizzo, F., Lutz, M., Spek, A.L., Van Klink, G.P.M., Merbach, A.E., De Cola, L., Van Koten, G., (2007) Eur. J. Inorg. Chem., pp. 2853-2861
  • Guldi, D.M., (2002) Chem. Soc. Rev., 31, pp. 22-36
  • Bignozzi, C.A., Argazzi, R., Schoonover, J.R., Meyer, G.J., Scandola, F., (1995) Sol. Energy Mater. Sol. Cells, 38, pp. 187-198
  • Puntoriero, F., Serroni, S., Galletta, M., Juris, A., Licciardello, A., Chiorboli, C., Campagna, S., Scandola, F., (2005) ChemPhysChem, 6, pp. 129-138
  • Araki, K., Losco, P., Engelmann, F.M., Winnischofer, H., Toma, H.E., (2001) J. Photochem. Photobiol., A, 142, pp. 25-30
  • Puntoriero, F., Nastasi, F., Campagna, S., Bura, T., Ziessel, R., (2010) Chem.-Eur. J., 16, pp. 8832-8845
  • Abrahamsson, M., Jager, M., Kumar, R.J., Osterman, T., Persson, P., Becker, H.-C., Johansson, O., Hammarstrom, L., (2008) J. Am. Chem. Soc., 130, pp. 15533-15542
  • Sauvage, J.P., Collin, J.P., Chambron, J.C., Guillerez, S., Coudret, C., Balzani, V., Barigelletti, F., Flamigni, L., (1994) Chem. Rev., 94, pp. 993-1019
  • Balzani, V., Juris, A., Venturi, M., Campagna, S., Serroni, S., (1996) Chem. Rev., 96, pp. 759-834
  • Chiorboli, C., Indelli, M.T., Scandola, F., (2005) Top. Curr. Chem., 257, pp. 63-102
  • Benniston, A.C., Harriman, A., (2008) Coord. Chem. Rev., 252, pp. 2528-2539
  • Albores, P., Slep, L.D., Eberlin, L.S., Corilo, Y.E., Eberlin, M.N., Benitez, G., Vela, M.E., Baraldo, L.M., (2009) Inorg. Chem., 48, pp. 11226-11235
  • Pieslinger, G.E., Albores, P., Slep, L.D., Baraldo, L.M., (2014) Angew. Chem., Int. Ed., 53, pp. 1293-1296
  • Sun, Y., Chen, Z., Puodziukynaite, E., Jenkins, D.M., Reynolds, J.R., Schanze, K.S., (2012) Macromolecules, 45, pp. 2632-2642
  • Wu, S.J., Chen, C.Y., Chen, J.G., Li, J.Y., Tung, Y.L., Ho, K.C., Wu, C.G., (2010) Dyes Pigm., 84, pp. 95-101
  • Bignozzi, C.A., Indelli, M.T., Scandola, F., (1989) J. Am. Chem. Soc., 111, pp. 5192-5198
  • Scandola, F., Argazzi, R., Bignozzi, C.A., Chiorboli, C., Indelli, M.T., (1993) Coord. Chem. Rev., 125, pp. 283-292
  • Argazzi, R., Bignozzi, C.A., Hasselmann, G.M., Meyer, G.J., (1998) Inorg. Chem., 37, pp. 4533-4537
  • Argazzi, R., Bignozzi, C.A., Heimer, T.A., Meyer, G.J., (1997) Inorg. Chem., 36, pp. 2-3
  • Rangan, K., Arachchige, S.M., Brown, J.R., Brewer, K.J., (2009) Energy Environ. Sci., 2, pp. 410-419
  • House, R.L., Iha, N.Y.M., Coppo, R.L., Alibabaei, L., Sherman, B.D., Kang, P., Brennaman, M.K., Meyer, T.J., (2015) J. Photochem. Photobiol., C, 25, pp. 32-45
  • Ashford, D.L., Glasson, C.R.K., Norris, M.R., Concepcion, J.J., Keinan, S., Brennaman, M.K., Templeton, J.L., Meyer, T.J., (2014) Inorg. Chem., 53, pp. 5637-5646
  • Ashford, D.L., Brennaman, M.K., Brown, R.J., Keinan, S., Concepcion, J.J., Papanikolas, J.M., Templeton, J.L., Meyer, T.J., (2015) Inorg. Chem., 54, pp. 460-469
  • Welby, C.E., Rice, C.R., Elliott, P.I.P., (2013) Angew. Chem., Int. Ed., 52, pp. 10826-10829
  • Keene, F.R., (1997) Coord. Chem. Rev., 166, pp. 121-159
  • Hewitt, J.T., Vallett, P.J., Damrauer, N.H., (2012) J. Phys. Chem. A, 116, pp. 11536-11547
  • Thompson, D.W., Ito, A., Meyer, T.J., (2013) Pure Appl. Chem., 85, pp. 1257-1305
  • Winkler, J.R., Netzel, T.L., Creutz, C., Sutin, N., (1987) J. Am. Chem. Soc., 109, pp. 2381-2392
  • Hofmeier, H., Schubert, U.S., (2004) Chem. Soc. Rev., 33, pp. 373-399
  • Brown, D.G., Sanguantrakun, N., Schulze, B., Schubert, U.S., Berlinguette, C.P., (2012) J. Am. Chem. Soc., 134, pp. 12354-12357
  • Sun, Q.C., Mosquera-Vazquez, S., Suffren, Y., Hankache, J., Amstutz, N., Daku, L.M.L., Vauthey, E., Hauser, A., (2015) Coord. Chem. Rev., 282, pp. 87-99
  • Cadranel, A., Albores, P., Yamazaki, S., Kleiman, V.D., Baraldo, L.M., (2012) Dalton Trans., 41, pp. 5343-5350
  • Cadranel, A., Troselj, B.M.A., Yamazaki, S., Albores, P., Kleiman, V.D., Baraldo, L.M., (2013) Dalton Trans., 42, pp. 16723-16732
  • Prado, Y., Lisnard, L., Heurtaux, D., Rogez, G., Gloter, A., Stéphan, O., Dia, N., Mallah, T., (2011) Chem. Commun., 47, pp. 1051-1053
  • Culp, J.T., Park, J.H., Frye, F., Huh, Y.D., Meisel, M.W., Talham, D.R., (2005) Coord. Chem. Rev., 249, pp. 2642-2648
  • Coe, B.J., Meyer, T.J., White, P.S., (1995) Inorg. Chem., 34, pp. 593-602
  • Alborés, P., Slep, L.D., Weyhermüller, T., Rentschler, E., Baraldo, L.M., (2006) Dalton Trans., pp. 948-954
  • Altomare, A., Burla, M.C., Camalli, M., Cascarano, G.L., Giacovazzo, C., Guagliardi, A., Moliterni, A.G.G., Spagna, R., (1999) J. Appl. Crystallogr., 32, pp. 115-119
  • Sheldrick, G.M., (1997) SHELXS97 and SHELXL97: Programs for Crystal Structure Resolution
  • Sheldrick, G.M., (2015) Acta Crystallogr., Sect. A: Found. Adv., 71, pp. 3-8
  • Farrugia, L.J., (2012) J. Appl. Crystallogr., 45, pp. 849-854
  • Noviandri, I., Brown, K.N., Fleming, D.S., Gulyas, P.T., Lay, P.A., Masters, A.F., Phillips, L., (1999) J. Phys. Chem. B, 103, pp. 6713-6722
  • Marcolongo, J.P., Weyhermuller, T., Slep, L.D., (2015) Inorg. Chim. Acta, 429, pp. 174-182
  • Lebon, E., Dixon, I.M., Vendier, L., Igau, A., Sutra, P., (2007) Inorg. Chim. Acta, 360, pp. 1235-1239
  • Dixon, I.M., Lebon, E., Loustau, G., Sutra, P., Vendier, L., Igau, A., Juris, A., (2008) Dalton Trans., pp. 5627-5635
  • Yang, X.J., Drepper, F., Wu, B., Sun, W.H., Haehnel, W., Janiak, C., (2005) Dalton Trans., pp. 256-267
  • Nagao, H., Mizukawa, T., Tanaka, K., (1994) Inorg. Chem., 33, pp. 3415-3420
  • Adcock, P.A., Keene, F.R., Smythe, R.S., Snow, M.R., (1984) Inorg. Chem., 23, pp. 2336-2343
  • Rasmussen, S.C., Ronco, S.E., Mlsna, D.A., Billadeau, M.A., Pennington, W.T., Kolis, J.W., Petersen, J.D., (1995) Inorg. Chem., 34, pp. 821-829
  • Pieslinger, G.E., Albores, P., Slep, L.D., Coe, B.J., Timpson, C.J., Baraldo, L.M., (2013) Inorg. Chem., 52, pp. 2906-2917
  • Bignozzi, C.A., Bortolini, O., Chiorboli, C., Indelli, M.T., Rampi, M.A., Scandola, F., (1992) Inorg. Chem., 31, pp. 172-177
  • Macatangay, A.V., Mazzetto, S.E., Endicott, J.F., (1999) Inorg. Chem., 38, pp. 5091-5101
  • Juris, A., Balzani, V., Barigelletti, F., Campagna, S., Belser, P., Vonzelewsky, A., (1988) Coord. Chem. Rev., 84, pp. 85-277
  • Campagna, S., Puntoriero, F., Nastasi, F., Bergamini, G., Balzani, V., (2007) Photochemistry and Photophysics of Coordination Compounds: Ruthenium, 280, pp. 117-214. , ed. V. Balzani and S. Campagna, Topics in Current Chemistry, Springer-Verlag Berlin
  • Siebert, R., Hunger, C., Guthmuller, J., Schlutter, F., Winter, A., Schubert, U.S., Gonzalez, L., Popp, J., (2011) J. Phys. Chem. C, 115, pp. 12677-12688
  • Majewski, M.B., De Tacconi, N.R., MacDonnell, F.M., Wolf, M.O., (2011) Inorg. Chem., 50, pp. 9939-9941
  • Barthelmes, K., Jager, M., Kubel, J., Friebe, C., Winter, A., Wachtler, M., Dietzek, B., Schubert, U.S., (2016) Inorg. Chem., 55, pp. 5152-5167
  • Knoll, J.D., Albani, B.A., Turro, C., (2015) Acc. Chem. Res., 48, pp. 2280-2287
  • Damrauer, N.H., McCusker, J.K., (1999) J. Phys. Chem. A, 103, pp. 8440-8446
  • Pan, Q., Mecozzi, F., Korterik, J.P., Vos, J.G., Browne, W.R., Huijser, A., (2016) ChemPhysChem, 17, pp. 2654-2659
  • McFarland, S.A., Lee, F.S., Cheng, K., Cozens, F.L., Schepp, N.P., (2005) J. Am. Chem. Soc., 127, pp. 7065-7070
  • Bignozzi, C.A., Argazzi, R., Schoonover, J.R., Gordon, K.C., Dyer, R.B., Scandola, F., (1992) Inorg. Chem., 31, pp. 5260-5267
  • Alexander, J.J., Gray, H.B., (1968) J. Am. Chem. Soc., 90, pp. 4260-4271
  • Bignozzi, C.A., Roffia, S., Chiorboli, C., Davila, J., Indelli, M.T., Scandola, F., (1989) Inorg. Chem., 28, pp. 4350-4358

Citas:

---------- APA ----------
Cadranel, A., Tate, J.E., Oviedo, P.S., Yamazaki, S., Hodak, J.H., Baraldo, L.M. & Kleiman, V.D. (2017) . Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization. Physical Chemistry Chemical Physics, 19(4), 2882-2893.
http://dx.doi.org/10.1039/c6cp06562g
---------- CHICAGO ----------
Cadranel, A., Tate, J.E., Oviedo, P.S., Yamazaki, S., Hodak, J.H., Baraldo, L.M., et al. "Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization" . Physical Chemistry Chemical Physics 19, no. 4 (2017) : 2882-2893.
http://dx.doi.org/10.1039/c6cp06562g
---------- MLA ----------
Cadranel, A., Tate, J.E., Oviedo, P.S., Yamazaki, S., Hodak, J.H., Baraldo, L.M., et al. "Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization" . Physical Chemistry Chemical Physics, vol. 19, no. 4, 2017, pp. 2882-2893.
http://dx.doi.org/10.1039/c6cp06562g
---------- VANCOUVER ----------
Cadranel, A., Tate, J.E., Oviedo, P.S., Yamazaki, S., Hodak, J.H., Baraldo, L.M., et al. Distant ultrafast energy transfer in a trimetallic {Ru-Ru-Cr} complex facilitated by hole delocalization. Phys. Chem. Chem. Phys. 2017;19(4):2882-2893.
http://dx.doi.org/10.1039/c6cp06562g