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Abstract:

Ruthenium polypyridine complexes have proved to be useful caging groups for visible-light photodelivery of biomolecules. In most photoreactions, one ligand is expelled upon irradiation, yielding ruthenium mono-aqua complexes and no other photoproduct. In this work we show that a long-lived transient photoproduct is generated when the ruthenium complexes involve indolamines. The spatial conformation of this species is compatible with a cyclic structure that contains both the amine and the normally non-coordinating aromatic ring coordinated to the ruthenium center. © 2017 the Owner Societies.

Registro:

Documento: Artículo
Título:Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines
Autor:Carrone, G.; Zayat, L.; Slep, L.D.; Etchenique, R.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, AR1428EHA, Argentina
Año:2017
Volumen:19
Número:3
Página de inicio:2140
Página de fin:2147
DOI: http://dx.doi.org/10.1039/c6cp06580e
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v19_n3_p2140_Carrone

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Citas:

---------- APA ----------
Carrone, G., Zayat, L., Slep, L.D. & Etchenique, R. (2017) . Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines. Physical Chemistry Chemical Physics, 19(3), 2140-2147.
http://dx.doi.org/10.1039/c6cp06580e
---------- CHICAGO ----------
Carrone, G., Zayat, L., Slep, L.D., Etchenique, R. "Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines" . Physical Chemistry Chemical Physics 19, no. 3 (2017) : 2140-2147.
http://dx.doi.org/10.1039/c6cp06580e
---------- MLA ----------
Carrone, G., Zayat, L., Slep, L.D., Etchenique, R. "Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines" . Physical Chemistry Chemical Physics, vol. 19, no. 3, 2017, pp. 2140-2147.
http://dx.doi.org/10.1039/c6cp06580e
---------- VANCOUVER ----------
Carrone, G., Zayat, L., Slep, L.D., Etchenique, R. Transient photocyclization in ruthenium(II) polypyridine complexes of indolamines. Phys. Chem. Chem. Phys. 2017;19(3):2140-2147.
http://dx.doi.org/10.1039/c6cp06580e