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Abstract:

A chemometric procedure to deal with spectroscopically monitored processes involving photochemical steps is fully described. The methodology makes it possible to work with reactions that involve several components with unknown (and eventually overlapping) spectra and provides a tool for the simultaneous determination of both the quantum yields of the reaction and the spectra of all the species present in a multi-step photochemical process. As a benchmark, we apply these ideas to extract the quantum yields of photodetachment of coordinated ligands employing data recorded over the course of the decomposition of [Ru(tpm)(bpy)(CH3CN)]2+ and cis-[Ru(bpy)2(CH3CN)2]2+ under stationary photolysis conditions. The approach is fast and robust and it is easily implemented in scientific programming languages. © 2017 the Owner Societies.

Registro:

Documento: Artículo
Título:A chemometric approach for determining the reaction quantum yields in consecutive photochemical processes
Autor:Marcolongo, J.P.; Schmidt, J.; Levin, N.; Slep, L.D.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Universidad de Buenos Aires-CONICET, Ciudad Universitaria, Pabellón 2, 3er piso, Ciudad Autónoma de Buenos Aires, C1428EHA, Argentina
Año:2017
Volumen:19
Número:32
Página de inicio:21373
Página de fin:21381
DOI: http://dx.doi.org/10.1039/c7cp03619a
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v19_n32_p21373_Marcolongo

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Citas:

---------- APA ----------
Marcolongo, J.P., Schmidt, J., Levin, N. & Slep, L.D. (2017) . A chemometric approach for determining the reaction quantum yields in consecutive photochemical processes. Physical Chemistry Chemical Physics, 19(32), 21373-21381.
http://dx.doi.org/10.1039/c7cp03619a
---------- CHICAGO ----------
Marcolongo, J.P., Schmidt, J., Levin, N., Slep, L.D. "A chemometric approach for determining the reaction quantum yields in consecutive photochemical processes" . Physical Chemistry Chemical Physics 19, no. 32 (2017) : 21373-21381.
http://dx.doi.org/10.1039/c7cp03619a
---------- MLA ----------
Marcolongo, J.P., Schmidt, J., Levin, N., Slep, L.D. "A chemometric approach for determining the reaction quantum yields in consecutive photochemical processes" . Physical Chemistry Chemical Physics, vol. 19, no. 32, 2017, pp. 21373-21381.
http://dx.doi.org/10.1039/c7cp03619a
---------- VANCOUVER ----------
Marcolongo, J.P., Schmidt, J., Levin, N., Slep, L.D. A chemometric approach for determining the reaction quantum yields in consecutive photochemical processes. Phys. Chem. Chem. Phys. 2017;19(32):21373-21381.
http://dx.doi.org/10.1039/c7cp03619a