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Abstract:

Experimental evidence of the variation in redox potential of osmium pyridine complexes tethered to a Au surface by thiol or diazonium chemistry at different ionic concentration and electrolyte pH is described. The interplay between the charged redox and acid groups is described by a charge regulation model based on PM-IRRAS spectroscopic evidence on the different degrees of surface protonation. © the Owner Societies 2012.

Registro:

Documento: Artículo
Título:Charge regulation in redox active monolayers embedded in proton exchanger surfaces
Autor:Ricci, A.M.; Tagliazucchi, M.; Calvo, E.J.
Filiación:Chemistry Department, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, United States
ALUAR S.A. Aluminio Argentino, Puerto Madryn, Chubut, Argentina
INQUIMAE-DQIAyQF, Facultad de Ciencias Exactas y Naturales, UBA Pabellon 2, Ciudad Universitaria, Buenos Aires, Argentina
Año:2012
Volumen:14
Número:28
Página de inicio:9988
Página de fin:9995
DOI: http://dx.doi.org/10.1039/c2cp40695k
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v14_n28_p9988_Ricci

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Citas:

---------- APA ----------
Ricci, A.M., Tagliazucchi, M. & Calvo, E.J. (2012) . Charge regulation in redox active monolayers embedded in proton exchanger surfaces. Physical Chemistry Chemical Physics, 14(28), 9988-9995.
http://dx.doi.org/10.1039/c2cp40695k
---------- CHICAGO ----------
Ricci, A.M., Tagliazucchi, M., Calvo, E.J. "Charge regulation in redox active monolayers embedded in proton exchanger surfaces" . Physical Chemistry Chemical Physics 14, no. 28 (2012) : 9988-9995.
http://dx.doi.org/10.1039/c2cp40695k
---------- MLA ----------
Ricci, A.M., Tagliazucchi, M., Calvo, E.J. "Charge regulation in redox active monolayers embedded in proton exchanger surfaces" . Physical Chemistry Chemical Physics, vol. 14, no. 28, 2012, pp. 9988-9995.
http://dx.doi.org/10.1039/c2cp40695k
---------- VANCOUVER ----------
Ricci, A.M., Tagliazucchi, M., Calvo, E.J. Charge regulation in redox active monolayers embedded in proton exchanger surfaces. Phys. Chem. Chem. Phys. 2012;14(28):9988-9995.
http://dx.doi.org/10.1039/c2cp40695k