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Ricci, A.M.; Tognalli, N.; De La Llave, E.; Vericat, C.; Méndez De Leo, L.P.; Williams, F.J.; Scherlis, D.; Salvarezza, R.; Calvo, E.J. "Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions" (2011) Physical Chemistry Chemical Physics. 13(12):5336-5345
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Abstract:

Osmium pyridine-bipyridine redox centers have been tethered to Au electrodes by chemical modification through Au-S and Au-C bonds respectively. 4-mercapto benzoic acid and the reduction product of the aryl diazonium salt of 4-amino benzoic acid were reacted on Au surfaces, with further post-functionalization by chemical reaction of the osmium complex amino-pyridine derivative with the surface carboxylates. The resulting modified Au surfaces were characterized by polarization modulated infrared reflection absorption spectroscopy (PM-IRRAS), scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), resonant raman spectroscopy and cyclic voltammetry. © the Owner Societies.

Registro:

Documento: Artículo
Título:Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions
Autor:Ricci, A.M.; Tognalli, N.; De La Llave, E.; Vericat, C.; Méndez De Leo, L.P.; Williams, F.J.; Scherlis, D.; Salvarezza, R.; Calvo, E.J.
Filiación:INQUIMAE, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
Centro Atómico Bariloche, Instituto Balseiro, Comisión Nacional de Energía Atómica, 8400 S. C. de Bariloche, Río Negro, Argentina
INIFTA, Universidad Nacional de La Plata, CONICET, Sucursal 4 Casilla de Correo 16, 1900 La Plata, Argentina
Palabras clave:4 aminobenzoic acid; gold; osmium; pyridine; pyridine derivative; article; chemical structure; chemistry; electrochemistry; electrode; oxidation reduction reaction; Raman spectrometry; scanning tunneling microscopy; surface property; X ray photoelectron spectroscopy; 4-Aminobenzoic Acid; Electrochemistry; Electrodes; Gold; Microscopy, Scanning Tunneling; Molecular Structure; Osmium; Oxidation-Reduction; Photoelectron Spectroscopy; Pyridines; Spectrum Analysis, Raman; Surface Properties
Año:2011
Volumen:13
Número:12
Página de inicio:5336
Página de fin:5345
DOI: http://dx.doi.org/10.1039/c0cp02409k
Título revista:Physical Chemistry Chemical Physics
Título revista abreviado:Phys. Chem. Chem. Phys.
ISSN:14639076
CODEN:PPCPF
CAS:4 aminobenzoic acid, 150-13-0; gold, 7440-57-5; osmium, 7440-04-2; pyridine, 110-86-1; 4-Aminobenzoic Acid, 150-13-0; Gold, 7440-57-5; Osmium, 7440-04-2; Pyridines; pyridine, 110-86-1
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v13_n12_p5336_Ricci

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Citas:

---------- APA ----------
Ricci, A.M., Tognalli, N., De La Llave, E., Vericat, C., Méndez De Leo, L.P., Williams, F.J., Scherlis, D.,..., Calvo, E.J. (2011) . Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions. Physical Chemistry Chemical Physics, 13(12), 5336-5345.
http://dx.doi.org/10.1039/c0cp02409k
---------- CHICAGO ----------
Ricci, A.M., Tognalli, N., De La Llave, E., Vericat, C., Méndez De Leo, L.P., Williams, F.J., et al. "Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions" . Physical Chemistry Chemical Physics 13, no. 12 (2011) : 5336-5345.
http://dx.doi.org/10.1039/c0cp02409k
---------- MLA ----------
Ricci, A.M., Tognalli, N., De La Llave, E., Vericat, C., Méndez De Leo, L.P., Williams, F.J., et al. "Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions" . Physical Chemistry Chemical Physics, vol. 13, no. 12, 2011, pp. 5336-5345.
http://dx.doi.org/10.1039/c0cp02409k
---------- VANCOUVER ----------
Ricci, A.M., Tognalli, N., De La Llave, E., Vericat, C., Méndez De Leo, L.P., Williams, F.J., et al. Electrochemistry of Os(2,2′-bpy)2ClPyCH2NHCOPh tethered to Au electrodes by S-Au and C-Au junctions. Phys. Chem. Chem. Phys. 2011;13(12):5336-5345.
http://dx.doi.org/10.1039/c0cp02409k