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Abstract:

Get wired! The layer-by-layer electrostatic self-assembly of a redox enzyme as glucose oxidase (GOx) and a redox polymer mediator allowed different spatial organizations of both components to be explored. These organized systems (see picture) can work efficiently in molecular recognition, redox mediation, and generation of an electrical signal. Moreover, differences in GOx electrical wiring efficiency have been detected with the different assembling strategies.

Registro:

Documento: Artículo
Título:Supramolecular architectures of electrostatic self-assembled glucose oxidase enzyme electrodes
Autor:Calvo, E.J.; Wolosiuk, A.
Filiación:Depto. Quim. Inorg. Analit./Quim. F., Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Dept. of Mat. Sci. and Engineering, University of Illinois, Urbana Champaign, IL 61801, United States
Palabras clave:Electrochemistry; Enzyme catalysis; Monolayers; Nanostructures; Sensors; glucose oxidase; oxidoreductase; article; catalysis; chemical structure; cyclic potentiometry; electricity; enzyme electrode; molecular recognition; oxidation reduction reaction; reaction analysis; supramolecular chemistry; Biosensing Techniques; Catalysis; Electrodes; Enzymes, Immobilized; Flavin-Adenine Dinucleotide; Gluconates; Glucose; Glucose Oxidase; Kinetics; Membranes, Artificial; Oxidation-Reduction; Polyamines; Potentiometry
Año:2004
Volumen:5
Número:2
Página de inicio:235
Página de fin:239
DOI: http://dx.doi.org/10.1002/cphc.200300930
Título revista:ChemPhysChem
Título revista abreviado:ChemPhysChem
ISSN:14394235
CODEN:CPCHF
CAS:glucose oxidase, 9001-37-0; oxidoreductase, 9035-73-8, 9035-82-9, 9037-80-3, 9055-15-6; Enzymes, Immobilized; Flavin-Adenine Dinucleotide, 146-14-5; Gluconates; gluconic acid, 526-95-4; Glucose Oxidase, EC 1.1.3.4; Glucose, 50-99-7; Membranes, Artificial; polyallylamine, 30551-89-4; Polyamines
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14394235_v5_n2_p235_Calvo

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Citas:

---------- APA ----------
Calvo, E.J. & Wolosiuk, A. (2004) . Supramolecular architectures of electrostatic self-assembled glucose oxidase enzyme electrodes. ChemPhysChem, 5(2), 235-239.
http://dx.doi.org/10.1002/cphc.200300930
---------- CHICAGO ----------
Calvo, E.J., Wolosiuk, A. "Supramolecular architectures of electrostatic self-assembled glucose oxidase enzyme electrodes" . ChemPhysChem 5, no. 2 (2004) : 235-239.
http://dx.doi.org/10.1002/cphc.200300930
---------- MLA ----------
Calvo, E.J., Wolosiuk, A. "Supramolecular architectures of electrostatic self-assembled glucose oxidase enzyme electrodes" . ChemPhysChem, vol. 5, no. 2, 2004, pp. 235-239.
http://dx.doi.org/10.1002/cphc.200300930
---------- VANCOUVER ----------
Calvo, E.J., Wolosiuk, A. Supramolecular architectures of electrostatic self-assembled glucose oxidase enzyme electrodes. ChemPhysChem. 2004;5(2):235-239.
http://dx.doi.org/10.1002/cphc.200300930