Abstract:
We present a photocleavable protecting group based on ruthenium bipyridyl complexes and suitable for amino acid photodelivery. We discuss the photochemical properties of the caged glutamate, which is a major neurotransmitter in the CNS. The molar absorptivity for the caged glutamate at 450 nm is ε = 4200 M-1cm-1 and its quantum yield of photore-lease at 450 nm is ?̈PD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other ?́-amino acids. © Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
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Citas:
---------- APA ----------
Salierno, M., Fameli, C. & Etchenique, R.
(2008)
. Caged amino acids for visible-light photodelivery. European Journal of Inorganic Chemistry(7), 1125-1128.
http://dx.doi.org/10.1002/ejic.200700963---------- CHICAGO ----------
Salierno, M., Fameli, C., Etchenique, R.
"Caged amino acids for visible-light photodelivery"
. European Journal of Inorganic Chemistry, no. 7
(2008) : 1125-1128.
http://dx.doi.org/10.1002/ejic.200700963---------- MLA ----------
Salierno, M., Fameli, C., Etchenique, R.
"Caged amino acids for visible-light photodelivery"
. European Journal of Inorganic Chemistry, no. 7, 2008, pp. 1125-1128.
http://dx.doi.org/10.1002/ejic.200700963---------- VANCOUVER ----------
Salierno, M., Fameli, C., Etchenique, R. Caged amino acids for visible-light photodelivery. Eur. J. Inorg. Chem. 2008(7):1125-1128.
http://dx.doi.org/10.1002/ejic.200700963