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Abstract:

We report the properties of a trinuclear cyanido-bridged complex, trans-(dmap)4RuII(Âμ-NC)OsIII(CN) 524- [14-; dmap = 4-(dimethylamino)pyridine], whose structure and electronic and vibrational spectra present strong evidence of partial redox states for the three metal ions, an unprecedented feature for cyanido-bridged systems. Matching the energy of metal fragments bonded by a cyanido bridge results in asystem that is better described as having partial RuII/III and OsII/ III character as evidenced by its structure and its spectroscopic analysis. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex
Autor:Rossi, M.B.; Abboud, K.A.; Alborés, P.; Baraldo, L.M.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires INQUIMAE(CONICET), Buenos Aires C1428EHA, Argentina
Department of Chemistry, University of Florida, Gainesville, FL 32611, United States
Palabras clave:Cyanido bridge; Delocalization; Mixed-valent compounds; Osmium; Ruthenium
Año:2010
Número:36
Página de inicio:5613
Página de fin:5616
DOI: http://dx.doi.org/10.1002/ejic.201000912
Título revista:European Journal of Inorganic Chemistry
Título revista abreviado:Eur. J. Inorg. Chem.
ISSN:14341948
CODEN:EJICF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14341948_v_n36_p5613_Rossi

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Citas:

---------- APA ----------
Rossi, M.B., Abboud, K.A., Alborés, P. & Baraldo, L.M. (2010) . Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex. European Journal of Inorganic Chemistry(36), 5613-5616.
http://dx.doi.org/10.1002/ejic.201000912
---------- CHICAGO ----------
Rossi, M.B., Abboud, K.A., Alborés, P., Baraldo, L.M. "Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex" . European Journal of Inorganic Chemistry, no. 36 (2010) : 5613-5616.
http://dx.doi.org/10.1002/ejic.201000912
---------- MLA ----------
Rossi, M.B., Abboud, K.A., Alborés, P., Baraldo, L.M. "Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex" . European Journal of Inorganic Chemistry, no. 36, 2010, pp. 5613-5616.
http://dx.doi.org/10.1002/ejic.201000912
---------- VANCOUVER ----------
Rossi, M.B., Abboud, K.A., Alborés, P., Baraldo, L.M. Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex. Eur. J. Inorg. Chem. 2010(36):5613-5616.
http://dx.doi.org/10.1002/ejic.201000912