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Frantz, S.; Sarkar, B.; Sieger, M.; Kaim, W.; Roncaroli, F.; Olabe, J.A.; Záliš, S. "EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k" (2004) European Journal of Inorganic Chemistry(14):2902-2907
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Abstract:

A survey of 18 paramagnetic species [LnRu(NO)]k, including seven new examples studied by in situ electrolysis, reveals a surprisingly narrow range of EPR parameters despite a wide variety of ligands such as pyridine, polypyridines, imines, amines, nitriles, phosphanes, carbonyl, cyclopentadienides, halides, hydride, hydroxide, thiocyanate or cyanide: g 1 = 2.015 ± 0.02, g2 = 1.990 ± 0.015, g 3 = 1.892 ± 0.03, gav = 1.968 ± 0.02, Δg = g1 - g3 = 0.122 ± 0.037, A 2(14N) = 3.3 ± 0.5 mT. This rather small variability, smaller still if the organometallic compounds are excluded, differs from the wider range of EPR data reported for nitrosyliron species with S = 1/2; apparently, the [RuNO]7 configuration involves a rather invariant and relatively covalent metal-NO interaction. DFT calculations were employed for [(NC)5Ru(NO)]3-to reproduce the EPR data, to evaluate the spin distribution (58% spin density on NO), and to reveal structural changes on reduction such as the Ru-N-O bending and Ru-NO bond lengthening. In addition, the possibility of staggered and eclipsed conformations is discussed. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Registro:

Documento: Artículo
Título:EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k
Autor:Frantz, S.; Sarkar, B.; Sieger, M.; Kaim, W.; Roncaroli, F.; Olabe, J.A.; Záliš, S.
Filiación:Institut fur Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany
Depto. de Quimica Inorganica, UBA, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina
J. Heyrovsky Inst. of Phys. Chem., Acad. of Sci. of the Czech Republic, Dolejškova 3, 18223 Prague, Czech Republic
Palabras clave:Density functional calculations; EPR spectroscopy; Nitric oxide; Radical complexes; Ruthenium; amine; carbonyl derivative; cyanide; cyclopentadiene derivative; halide; hydroxide; imine; ligand; metal; nitric oxide; nitrile; nitrogen; organometallic compound; oxygen; pyridine; ruthenium; thiocyanate; analytic method; article; calculation; complex formation; electrolysis; electron spin resonance; magnetism; nitrosylation
Año:2004
Número:14
Página de inicio:2902
Página de fin:2907
DOI: http://dx.doi.org/10.1002/ejic.200400042
Título revista:European Journal of Inorganic Chemistry
Título revista abreviado:Eur. J. Inorg. Chem.
ISSN:14341948
CODEN:EJICF
CAS:cyanide, 57-12-5; hydroxide, 14280-30-9; imine, 13774-92-0; nitric oxide, 10102-43-9; nitrogen, 7727-37-9; oxygen, 7782-44-7; pyridine, 110-86-1; ruthenium, 7440-18-8; thiocyanate, 302-04-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14341948_v_n14_p2902_Frantz

Referencias:

  • Playfair, L., (1849) Proc. Roy. Soc., (London), 5, p. 846
  • Playfair, L., (1850) Ann. Pharm., 74, p. 317
  • Swinehart, J.H., (1967) Coord. Chem. Rev., 2, p. 385
  • McCleverty, J.A., (1979) Chem. Rev., 79, p. 53
  • Feltham, R.D., Enemark, J.H., (1981) Top. Stereochem., 12, p. 155
  • Wanat, A., Schneppensieper, T., Stochel, G., Van Eldik, R., Bill, E., Wieghardt, K., (2002) Inorg. Chem., 41, p. 4
  • Li, M., Bonnet, D., Bill, E., Neese, F., Weyhermüller, T., Blum, N., Sellmann, D., Wieghardt, K., (2002) Inorg. Chem., 41, p. 3444
  • Schneppensieper, T., Wanat, A., Stochel, G., Goldstein, S., Meyerstein, D., Van Eldik, R., (2001) Eur. J. Inorg. Chem., p. 2317
  • Averill, B.A., (1996) Chem. Rev., 96, p. 2951
  • Trofimova, N.S., Safronov, A.Y., Ikeda, O., (2003) Inorg. Chem., 42, p. 1945. , and references cited therein
  • Scheidt, W.R., Ellison, M.K., (1999) Acc. Chem. Res., 32, p. 350
  • Wayland, B.B., Olson, L.W., (1974) J. Am. Chem. Soc., 96, p. 6037
  • Chen, Y., Sweetland, M.A., Shepherd, R.E., (1997) Inorg. Chim. Acta, 260, p. 163
  • Couture, C., Morton, J.R., Preston, K.F., Strach, S.J., (1980) J. Magn. Reson., 41, p. 88
  • Tom Dieck, H., Bruder, H., Kühl, E., Junghans, D., Hellfeldt, K., (1989) New. J. Chem., 13, p. 259
  • Hauser, C., Glaser, T., Bill, E., Weyhermüller, T., Wieghardt, K., (2000) J. Am. Chem. Soc., 122, p. 4352
  • Olabe, J.A., Slep, L., (1993) Comprehensive Coordination Chemistry II, 1, pp. 603-623. , (Eds.: J. A. McCleverty, T. J. Meyer), Pergamon
  • Olabe, J.A., Adv. Inorg. Chem., , in press
  • Enemark, J.H., Feltham, R.D., (1974) Coord. Chem. Rev., 13, p. 339
  • Richter-Addo, G.B., Legzdins, P., (1992) Metal Nitrosyls, , Oxford University Press, New York
  • (1996) Methods in Nitric Oxide Research, , (Eds.: M. Feelisch, J. S. Stamler), Wiley, Chichester
  • Ford, P.C., Lorkovic, I.M., (2002) Chem. Rev., 102, p. 993
  • Wang, P.G., Xian, M., Tang, X., Wu, X., Wen, Z., Cai, T., Janczuk, A., (2002) Chem. Rev., 102, p. 1091
  • Hrabie, J.A., Keefer, L.K., (2002) Chem. Rev., 102, p. 1135
  • Murad, F., (1999) Angew. Chem. Int. Ed., 28, p. 1856
  • Ruggiero, C.E., Carrier, S.M., Antholine, W.E., Whittaker, J.W., Cramer, C.J., Tolman, W.B., (1993) J. Am. Chem. Soc., 115, p. 11285
  • Ferguson, S.J., (1998) Curr. Opin. Chem. Biol., 2, p. 182
  • Iwamoto, M., Hamada, H., (1991) Catal. Today, 10, p. 57
  • Groothaert, M.H., Van Bokhoven, J.A., Battiston, A.A., Weckhuysen, B.M., Schoonheydt, R.A., (2003) J. Am. Chem. Soc., 125, p. 7629
  • Cameron, B.R., Darkes, M.C., Yee, H., Olsen, M., Fricker, S.P., Skerlj, R.T., Bridger, G.J., Zubieta, J., (2003) Inorg. Chem., 42, p. 1868
  • Serli, B., Zangrando, E., Gianferrara, T., Yellowlees, L.J., Alessio, E., (2003) Coord. Chem. Rev., 245, p. 73
  • Rhodes, M.R., Barley, M.H., Meyer, T.J., (1991) Inorg. Chem., 39, p. 629
  • Wolak, M., Van Eldik, R., (2002) Coord. Chem. Rev., 230, p. 263
  • Tfouni, E., Krieger, M., McGarvey, B.R., Franco, D.W., (2003) Coord. Chem. Rev., 236, p. 57
  • Borges, S.S.S., Davanzo, C.U., Castellano, E.E., Schpector, J.Z., Silva, S.C., Franco, D.W., (1998) Inorg. Chem., 37, p. 2670
  • Bezerra, C.W.B., Silva, C.S., Gambardella, M.T.P., Santos, R.H.A., Plicas, L.M.A., Tfouni, E., Franco, D.W., (1999) Inorg. Chem., 38, p. 5660
  • Callahan, R.W., Meyer, T.J., (1977) Inorg. Chem., 16, p. 574
  • Lang, D.R., Davis, J.A., Lopes, L.G.F., Ferro, A.A., Vasconcellos, L.C.G., Franco, D.W., Tfouni, E., Clarke, M.J., (2000) Inorg. Chem., 39, p. 2294
  • Zampieri, R.C.L., Von Poelhsitz, G., Batista, A.A., Nascimento, O.R., Ellena, J., Castellano, E.E., (2002) J. Inorg. Biochem., 92, p. 82
  • McGarvey, B.R., Ferro, A.A., Tfouni, E., Brito Bezerra, C.W., Bagatin, I., Franco, D.W., (2000) Inorg. Chem., 39, p. 3577
  • Gomez, J.A., Guenzburger, D., (2000) Chem. Phys., 253, p. 73
  • Wanner, M., Scheiring, T., Kaim, W., Slep, L.D., Baraldo, L.M., Olabe, J.A., Zalis, S., Baerends, E.J., (2001) Inorg. Chem., 40, p. 5704
  • Roncaroli, F., Baraldo, L.M., Slep, L.D., Olabe, J.A., (2002) Inorg. Chem., 41, p. 1930
  • De Souza, V.R., De Costa Ferreira, A.M., Toma, H.E., (2003) Dalton Trans., p. 458
  • Diversi, P., Fontani, M., Fuligni, M., Laschi, F., Marchetti, F., Matteoni, S., Pinzino, C., Zanello, P., (2003) J. Organomet. Chem., 675, p. 21
  • Marchenko, A.V., Vedernikov, A.N., Dye, D.F., Pink, M., Zaleski, J.M., Caulton, K.G., (2004) Inorg. Chem., 43, p. 351
  • Van Voorst, J.D.W., Hemmerich, P.J., (1966) Chem. Phys., 45, p. 3914
  • Reginato, N., Ccrory, C.T.C.M., Pervitsky, D., Li, L., (1999) J. Am. Chem. Soc., 121, p. 10217
  • Pipes, D.W., Meyer, T.J., (1984) Inorg. Chem., 23, p. 2466
  • Kaim, W., (1987) Coord. Chem. Rev., 76, p. 187
  • Neyman, K.M., Ganyushin, D.I., Nasluzov, V.A., Rösch, N., Pöppl, A., Hartmann, M., (2003) Phys. Chem. Chem. Phys., 5, p. 2429
  • Pietrzyk, P., Piskorz, W., Sojka, Z., Broclawik, E., (2003) J. Phys. Chem. B, 107, p. 6105
  • Glidewell, C., Johnson, I.L., (1987) Inorg. Chim. Acta, 132, p. 145
  • Waldhör, E., Kaim, W., Olabe, J.A., Slep, L.D., Fiedler, J., (1997) Inorg. Chem., 36, p. 2969
  • Waldhör, E., Poppe, J., Kaim, W., Cutin, E., Garcia Posse, M., Katz, N.E., (1995) Inorg. Chem., 34, p. 3093
  • Krejcik, M., Zalis, S., Klima, J., Sykora, D., Matheis, W., Klein, A., Kaim, W., (1993) Inorg. Chem., 32, p. 3362
  • Bianchini, C., Laschi, F., Peruzzini, M., Zanello, P., (1994) Gazz. Chim. Ital., 124, p. 271
  • Kadish, K.M., Adamian, V.A., Caemelbecke, E.V., Tan, Z., Tagliatesta, P., Bianco, P., Boschi, T., Richter-Addo, G., (1996) Inorg. Chem., 35, p. 1343
  • Miranda, K.M., Bu, X., Lorkovic, I., Ford, P.C., (1997) Inorg. Chem., 36, p. 4838
  • Bohle, D.S., Hung, C.H., Smith, B.D., (1998) Inorg. Chem., 37, p. 5798
  • Richter-Addo, G.B., Wheeler, R.A., Hixson, C.A., Chen, L., Kahn, M.A., Ellison, M.K., Schulz, C.E., Scheidt, W.R., (2001) J. Am. Chem. Soc., 123, p. 6314
  • Patterson, J.C., Lorkovic, I.M., Ford, P.C., (2003) Inorg. Chem., 42, p. 4902
  • Kaim, W., Ernst, S., Kasack, V., (1990) J. Am. Chem. Soc., 112, p. 173
  • Bottomley, F., Mukaida, M., (1982) J. Chem. Soc., Dalton Trans., p. 1933
  • Nishimura, H., Matsuzawa, H., Togano, T., Mukaida, M., Kakihana, H., (1990) J. Chem. Soc., Dalton Trans., p. 137
  • Nagao, H., Ito, K., Tsuboya, N., Ooyama, D., Nagao, N., Howell, S.F., Mukaida, M., (1999) Inorg. Chim. Acta, 290, p. 113
  • Weil, J.A., Bolton, J.R., Wertz, J.E., (1994) Electron Paramagnetic Resonance, , Wiley, New York
  • Bessel, C.A., Leising, R.A., Szczepura, L.F., Ferez, W.J., Vo, H., My, H., Takeuchi, K.J., (1988) Inorg. Synth., 32, p. 186
  • Te Velde, G., Bickelhaupt, F.M., Van Gisbergen, S.J.A., Fonseca Guerra, C., Baerends, E.J., Snijders, J.G., Ziegler, T., (2001) J. Comput. Chem., 22, p. 931
  • Fonseca Guerra, C., Snijders, J.G., Te Velde, G., Baerends, E.J., (1998) Theor. Chim. Acc., 99, p. 391
  • Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G., Pople, J.A., (1998) Gaussian 98, Revision A.11, , Gaussian. Inc.: Pittsburgh, PA
  • Becke, A.D., (1988) Phys. Rev. A, 38, p. 3098
  • Perdew, J.P., (1986) Phys. Rev. A, 33, p. 8822
  • Schipper, P.R.T., Gritsenko, O.V., Van Gisbergen, S.J.A., Baerends, E.J., (2000) J. Chem. Phys., 112, p. 1344
  • Van Lenthe, E., Van Der Avoird, A., Wormer, P.E.S., (1997) J. Chem. Phys., 107, p. 2488
  • Van Lenthe, E., Van Der Avoird, A., Wormer, P.E.S., (1998) J. Chem. Phys., 108, p. 4783
  • Schrenkenbach, G., Ziegler, T., (1997) J. Phys. Chem. A, 101, p. 3388
  • Woon, D.E., Dunning Jr., T.H., (1993) J. Chem. Phys., 98, p. 1358
  • Andrae, D., Häussermann, U., Dolg, M., Stoll, H., Preuss, H., (1990) Theor. Chim. Acta, 77, p. 123
  • Stephens, P.J., Devlin, F.J., Cabalowski, C.F., Frisch, M.J., (1994) J. Phys. Chem., 98, p. 11623

Citas:

---------- APA ----------
Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J.A. & Záliš, S. (2004) . EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k. European Journal of Inorganic Chemistry(14), 2902-2907.
http://dx.doi.org/10.1002/ejic.200400042
---------- CHICAGO ----------
Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J.A., et al. "EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k" . European Journal of Inorganic Chemistry, no. 14 (2004) : 2902-2907.
http://dx.doi.org/10.1002/ejic.200400042
---------- MLA ----------
Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J.A., et al. "EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k" . European Journal of Inorganic Chemistry, no. 14, 2004, pp. 2902-2907.
http://dx.doi.org/10.1002/ejic.200400042
---------- VANCOUVER ----------
Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J.A., et al. EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k. Eur. J. Inorg. Chem. 2004(14):2902-2907.
http://dx.doi.org/10.1002/ejic.200400042