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Foi, A.; Di Salvo, F.; Doctorovich, F.; Roy, T.G.; Stirnat, K.; Biewer, C.; Klein, A. "Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-" (2015) European Journal of Inorganic Chemistry. 2015(6):1033-1040
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Abstract:

The previously reported complex [Ph4P][Fe(bpy)(CN)3(NO)] (bpy = 2,2-bipyridine) was synthesised and characterised in detail using UV/Vis absorption and IR spectroscopy, cyclic voltammetry, and single-crystal XRD. Detailed spectroelectrochemical (UV/Vis, IR and EPR) insight adds perfectly to the previous electrochemical characterisation of this complex. The description of this {Fe(NO)}7 complex as a low-spin FeII-NO· system based on the spectroscopic results is supported by DFT calculations. Reversible oxidation leads to the corresponding {Fe(NO)}6 (FeII-NO+) complex, whereas the reduction to the formal {Fe(NO)}8 species [presumably (FeII-NO-)] occurs irreversibly. When trying to synthesise further derivatives that contain other α-diimine ligands, only for the 1,10-phenanthroline (phen) derivative were some results obtained. For other ligands the obtained materials were too reactive. The reasons for such behaviour are also discussed. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Registro:

Documento: Artículo
Título:Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-
Autor:Foi, A.; Di Salvo, F.; Doctorovich, F.; Roy, T.G.; Stirnat, K.; Biewer, C.; Klein, A.
Filiación:Departamento de Química Inorgánica, Analítica, y Química Física, Universidad de Buenos Aires, Pabellõn 2, Piso 3, Buenos Aires, C1428EHA, Argentina
University of Chittagong, Chittagong, 4331, Bangladesh
Universität zu Köln, Institut für Anorganische Chemie, Greinstraße 6, Köln, 50939, Germany
Palabras clave:Diimines; Electrochemistry; IR spectroscopy; Iron; Nitrogen oxides
Año:2015
Volumen:2015
Número:6
Página de inicio:1033
Página de fin:1040
DOI: http://dx.doi.org/10.1002/ejic.201403145
Título revista:European Journal of Inorganic Chemistry
Título revista abreviado:Eur. J. Inorg. Chem.
ISSN:14341948
CODEN:EJICF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14341948_v2015_n6_p1033_Foi

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Citas:

---------- APA ----------
Foi, A., Di Salvo, F., Doctorovich, F., Roy, T.G., Stirnat, K., Biewer, C. & Klein, A. (2015) . Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-. European Journal of Inorganic Chemistry, 2015(6), 1033-1040.
http://dx.doi.org/10.1002/ejic.201403145
---------- CHICAGO ----------
Foi, A., Di Salvo, F., Doctorovich, F., Roy, T.G., Stirnat, K., Biewer, C., et al. "Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-" . European Journal of Inorganic Chemistry 2015, no. 6 (2015) : 1033-1040.
http://dx.doi.org/10.1002/ejic.201403145
---------- MLA ----------
Foi, A., Di Salvo, F., Doctorovich, F., Roy, T.G., Stirnat, K., Biewer, C., et al. "Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-" . European Journal of Inorganic Chemistry, vol. 2015, no. 6, 2015, pp. 1033-1040.
http://dx.doi.org/10.1002/ejic.201403145
---------- VANCOUVER ----------
Foi, A., Di Salvo, F., Doctorovich, F., Roy, T.G., Stirnat, K., Biewer, C., et al. Tracing the iron nitrosyl complex [Fe(2,2-bipyridine)(CN)3(NO)]-. Eur. J. Inorg. Chem. 2015;2015(6):1033-1040.
http://dx.doi.org/10.1002/ejic.201403145