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Abstract:

A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. "chemical equation presented" © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,.

Registro:

Documento: Artículo
Título:A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine
Autor:Alborés, P.; Rentschler, E.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física-INQUIMAE (CONICET), Universidad de Buenos Aires, Buenos Aires, Argentina
Institut für Anorganische und Analytische Chemie, Johannes-Gutenberg-Universität, 55099 Mainz, Germany
Palabras clave:Cluster compounds; Cobalt; Dicarboxypyrazine; Magnetic properties; Chemical equations; Cluster compounds; Dinuclear; Mixed-valent compounds; Spin ground state; Chemical reactions; Cobalt; Magnetic properties; Cobalt compounds
Año:2009
Volumen:48
Número:49
Página de inicio:9366
Página de fin:9370
DOI: http://dx.doi.org/10.1002/anie.200904743
Título revista:Angewandte Chemie - International Edition
Título revista abreviado:Angew. Chem. Int. Ed.
ISSN:14337851
CODEN:ACIEA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n49_p9366_Albores

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Citas:

---------- APA ----------
Alborés, P. & Rentschler, E. (2009) . A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine. Angewandte Chemie - International Edition, 48(49), 9366-9370.
http://dx.doi.org/10.1002/anie.200904743
---------- CHICAGO ----------
Alborés, P., Rentschler, E. "A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine" . Angewandte Chemie - International Edition 48, no. 49 (2009) : 9366-9370.
http://dx.doi.org/10.1002/anie.200904743
---------- MLA ----------
Alborés, P., Rentschler, E. "A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine" . Angewandte Chemie - International Edition, vol. 48, no. 49, 2009, pp. 9366-9370.
http://dx.doi.org/10.1002/anie.200904743
---------- VANCOUVER ----------
Alborés, P., Rentschler, E. A Co36 cluster assembled from the reaction of cobalt pivalate with 2,3-dicarboxypyrazine. Angew. Chem. Int. Ed. 2009;48(49):9366-9370.
http://dx.doi.org/10.1002/anie.200904743