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Montenegro, A.C.; Amorebieta, V.T.; Slep, L.D.; Martín, D.F.; Roncaroli, F.; Murgida, D.H.; Bari, S.E.; Olabe, J.A. "Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform" (2009) Angewandte Chemie - International Edition. 48(23):4213-4216
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Abstract:

Not so elusive: [FeII(CN)5(HNO)]3- has been characterized spectroscopically after the two-electron reduction of nitroprusside (see scheme). The complex is stable at pH 6, slowly decomposing to [Fe(CN)6]4- and N2O. It is deprotonated at increasing pH value with oxidation of bound NO- to [Fe II(CN)5(NO)]3-. [FeII(CN) 5 (HNO)]3- is the first non-heme iron-nitroxyl complex prepared in aqueous solution that is reversibly redox-active under biologically relevant conditions. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Registro:

Documento: Artículo
Título:Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform
Autor:Montenegro, A.C.; Amorebieta, V.T.; Slep, L.D.; Martín, D.F.; Roncaroli, F.; Murgida, D.H.; Bari, S.E.; Olabe, J.A.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and INQUIMAE, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Departamento de Química, Facultad de Ciencias Exactas Universidad Nacional de Mar del Plata, Funesy Roca, Mar del Plata, B7602AYL, Argentina
Palabras clave:Cyanides; Iron; Nitrogen oxides; Nitroxyl complex; Redox chemistry; Aqueous solutions; Heme iron; Nitroxyl complex; Pentacyanoferrate; pH value; Redox chemistry; Redox state; Redox-active; Two-electron reduction; Cyanides; Iron oxides; Nitric oxide; Nitrogen oxides; Porphyrins; Iron compounds; ferrous ion; nitric oxide; nitroprusside sodium; pentacyanoferrate (II); chemistry; infrared spectroscopy; nuclear magnetic resonance spectroscopy; oxidation reduction reaction; Ferrous Compounds; Magnetic Resonance Spectroscopy; Nitric Oxide; Nitroprusside; Oxidation-Reduction; Spectroscopy, Fourier Transform Infrared
Año:2009
Volumen:48
Número:23
Página de inicio:4213
Página de fin:4216
DOI: http://dx.doi.org/10.1002/anie.200806229
Título revista:Angewandte Chemie - International Edition
Título revista abreviado:Angew. Chem. Int. Ed.
ISSN:14337851
CODEN:ACIEA
CAS:ferrous ion, 15438-31-0; nitric oxide, 10102-43-9; nitroprusside sodium, 14402-89-2, 15078-28-1; Ferrous Compounds; Nitric Oxide; Nitroprusside; pentacyanoferrate (II)
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v48_n23_p4213_Montenegro

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Citas:

---------- APA ----------
Montenegro, A.C., Amorebieta, V.T., Slep, L.D., Martín, D.F., Roncaroli, F., Murgida, D.H., Bari, S.E.,..., Olabe, J.A. (2009) . Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform. Angewandte Chemie - International Edition, 48(23), 4213-4216.
http://dx.doi.org/10.1002/anie.200806229
---------- CHICAGO ----------
Montenegro, A.C., Amorebieta, V.T., Slep, L.D., Martín, D.F., Roncaroli, F., Murgida, D.H., et al. "Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform" . Angewandte Chemie - International Edition 48, no. 23 (2009) : 4213-4216.
http://dx.doi.org/10.1002/anie.200806229
---------- MLA ----------
Montenegro, A.C., Amorebieta, V.T., Slep, L.D., Martín, D.F., Roncaroli, F., Murgida, D.H., et al. "Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform" . Angewandte Chemie - International Edition, vol. 48, no. 23, 2009, pp. 4213-4216.
http://dx.doi.org/10.1002/anie.200806229
---------- VANCOUVER ----------
Montenegro, A.C., Amorebieta, V.T., Slep, L.D., Martín, D.F., Roncaroli, F., Murgida, D.H., et al. Three redox states of nitrosyl: NO+, NO•, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform. Angew. Chem. Int. Ed. 2009;48(23):4213-4216.
http://dx.doi.org/10.1002/anie.200806229