Artículo

Ricci, A.; Rolli, C.; Rothacher, S.; Baraldo, L.; Bonazzola, C.; Calvo, E.J.; Tognalli, N.; Fainstein, A. "Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes" (2007) Journal of Solid State Electrochemistry. 11(11):1511-1520
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Abstract:

Chemically modified electrodes by the osmium complex [Os(bpy) 2Clpy - X] + PF - 6 tethered to Au surfaces by (1) reaction of cysteamine with the aldehyde (X=CHO), (2) mercapto alkanoic acid reaction with amine [X= (CH 2) 2NH 2], and (3) reduction of the diazonium salt of paminobenzoic acid and further amidation reaction with the amine derivative of the osmium complex [X=(CH 2) 2NH 2] were performed to explore the electron transfer properties of these redox-modified surfaces. The modified Au surfaces were characterized by infrared reflection absorption spectroscopy and resonant Raman spectroscopy. Cyclic voltammetry was used to study the electrochemical properties of the osmium complexes covalently attached to the surface as a function of the type and length of the tether. © 2007 Springer-Verlag.

Registro:

Documento: Artículo
Título:Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes
Autor:Ricci, A.; Rolli, C.; Rothacher, S.; Baraldo, L.; Bonazzola, C.; Calvo, E.J.; Tognalli, N.; Fainstein, A.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Centro Atómico Bariloche, Instituto Balseiro, Comisión Nacional de Energía Atómica, 8400 San Carlos de Bariloche, Argentina
Palabras clave:Charge transfer; Diazonium; FTIR-RAS; Osmium bipyridil; Resonant Raman; SAM; Thiol; Amine derivatives; Chemically modified electrodes; Cysteamine; Electron transfer; Absorption spectroscopy; Aldehydes; Amines; Electron transitions; Gold; Osmium compounds; Pyridine; Raman spectroscopy; Surfaces
Año:2007
Volumen:11
Número:11
Página de inicio:1511
Página de fin:1520
DOI: http://dx.doi.org/10.1007/s10008-007-0339-8
Título revista:Journal of Solid State Electrochemistry
Título revista abreviado:J. Solid State Electrochem.
ISSN:14328488
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14328488_v11_n11_p1511_Ricci

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Citas:

---------- APA ----------
Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E.J., Tognalli, N.,..., Fainstein, A. (2007) . Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes. Journal of Solid State Electrochemistry, 11(11), 1511-1520.
http://dx.doi.org/10.1007/s10008-007-0339-8
---------- CHICAGO ----------
Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E.J., et al. "Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes" . Journal of Solid State Electrochemistry 11, no. 11 (2007) : 1511-1520.
http://dx.doi.org/10.1007/s10008-007-0339-8
---------- MLA ----------
Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E.J., et al. "Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes" . Journal of Solid State Electrochemistry, vol. 11, no. 11, 2007, pp. 1511-1520.
http://dx.doi.org/10.1007/s10008-007-0339-8
---------- VANCOUVER ----------
Ricci, A., Rolli, C., Rothacher, S., Baraldo, L., Bonazzola, C., Calvo, E.J., et al. Electron transfer at Au surfaces modified by Tethered Osmium bipyridine-pyridine complexes. J. Solid State Electrochem. 2007;11(11):1511-1520.
http://dx.doi.org/10.1007/s10008-007-0339-8