Artículo
Bossi, M.L.; Aramendía, P.F. "Photomodulation of macroscopic properties" (2011) Journal of Photochemistry and Photobiology C: Photochemistry Reviews. 12(3):154-166
Consulte la política de Acceso Abierto del editor
Abstract:
We review macroscopic properties of materials that can be modulated by light through switching between the two stable states of a photochromic system. In special cases, the photochromic compound is the only component of the material, but in most cases it is either embedded or covalently linked to a suitable host, which is normally a liquid crystalline phase, a glassy or a rubbery polymer, or an interface. We analyze examples that illustrate changes in refractive index, transmission of polarized light, reflectivity, light dispersion, polarization, charge transport capability, dielectrical properties, stable phase, microscopic surface relief in large areas, hydrophobicity of the surface, permeability, and even bulk mechanical deformations. The basis of such changes at a molecular level is associated with a difference in the shape, dipole moment, polarizability, or electronic features of the photochromic species, and their different interaction with the environment. In some cases, studies were performed at the single molecule level. Each effect is discussed stressing the favorable features of the particular photochromic compounds to induce the changes and its interaction with the environment that make it suitable for the appointed application. © 2011 Elsevier B.V.
Registro:
| Documento: | Artículo |
| Título: | Photomodulation of macroscopic properties |
| Autor: | Bossi, M.L.; Aramendía, P.F. |
| Filiación: | INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires Ciudad Universitaria, Pabellón 2, 1428 Buenos Aires, Argentina |
| Palabras clave: | Liquid crystals; Photochromism; Photomodulation; Photoswitching; Polymers; Dielectrical properties; Light dispersion; Liquid crystalline phase; Macroscopic properties; Mechanical deformation; Microscopic surface; Molecular levels; Photo modulation; Photochromic compound; Photochromic systems; Photoswitching; Polarizabilities; Rubbery polymers; Single molecule level; Stable phase; Stable state; Interfaces (materials); Light transmission; Liquid crystals; Materials properties; Mechanical permeability; Polarization; Polymers; Refractive index; Surface properties; Photochromism |
| Año: | 2011 |
| Volumen: | 12 |
| Número: | 3 |
| Página de inicio: | 154 |
| Página de fin: | 166 |
| DOI: | http://dx.doi.org/10.1016/j.jphotochemrev.2011.09.002 |
| Título revista: | Journal of Photochemistry and Photobiology C: Photochemistry Reviews |
| Título revista abreviado: | J. Photochem. Photobiol. C Photochem. Rev. |
| ISSN: | 13895567 |
| CODEN: | JPPCA |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13895567_v12_n3_p154_Bossi |
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Citas:
---------- APA ----------
Bossi, M.L. & Aramendía, P.F. (2011) . Photomodulation of macroscopic properties. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 12(3), 154-166.http://dx.doi.org/10.1016/j.jphotochemrev.2011.09.002
---------- CHICAGO ----------
Bossi, M.L., Aramendía, P.F. "Photomodulation of macroscopic properties" . Journal of Photochemistry and Photobiology C: Photochemistry Reviews 12, no. 3 (2011) : 154-166.http://dx.doi.org/10.1016/j.jphotochemrev.2011.09.002
---------- MLA ----------
Bossi, M.L., Aramendía, P.F. "Photomodulation of macroscopic properties" . Journal of Photochemistry and Photobiology C: Photochemistry Reviews, vol. 12, no. 3, 2011, pp. 154-166.http://dx.doi.org/10.1016/j.jphotochemrev.2011.09.002
---------- VANCOUVER ----------
Bossi, M.L., Aramendía, P.F. Photomodulation of macroscopic properties. J. Photochem. Photobiol. C Photochem. Rev. 2011;12(3):154-166.http://dx.doi.org/10.1016/j.jphotochemrev.2011.09.002
