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Abstract:

The series of polycrystalline heteronuclear complexes, Bi1-xNdx[Fe(CN)6]·4H2O (0 ≤ x ≤ 0.3), was successfully synthesized and characterized, by means of powder X-ray diffraction (PXRD) and infrared spectroscopy. The thermal behaviour was studied by thermogravimetric and differential thermal analysis. The crystal structure of the complexes was refined by Rietveld analysis. It was found that they crystallized in the orthorhombic crystal system, space group Cmcm. The lattice parameters and unit cell volume decrease with an increase in Nd concentration. In order to obtain the oxides Bi1-xNdxFeO3, the thermal decomposition of the inorganic complexes, Bi1-xNdx[Fe(CN)6]·4H2O, has been investigated. By Rietveld analysis of PXRD data, the synthesis of the oxides was confirmed, evidencing in the series, a gradual change in crystal structure from rhombohedra to triclinic. Furthermore, with an increase in Nd content in Bi1-xNdxFeO3 oxides, impurity phases, such as Bi2O3, Bi2Fe4O9 and Bi25FeO39 associated with the synthesis of BiFeO3, are reduced. The morphology and chemical composition were investigated by microscopy electronic scattering and energy-dispersive X-ray spectroscopy. The electrical and magnetic properties have been determined to characterize the obtained oxides. © 2015 Akadémiai Kiadó, Budapest, Hungary.

Registro:

Documento: Artículo
Título:Synthesis and characterization of Bi1-xNdxFeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1-xNdx[Fe(CN)6]·4H2O
Autor:Navarro, M.C.; Jorge, G.; Negri, R.M.; Saleh Medina, L.M.; Gómez, M.I.
Filiación:Instituto de Química Inorgánica, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471, San Miguel de Tucumán, 4000, Argentina
Instituto de Ciencias, Universidad Nacional de General Sarmiento, Buenos Aires, Argentina
Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Hexacyanoferrate (III); Mixed oxides; Rietveld method; Thermal decomposition; X-ray diffraction; Bismuth compounds; Crystal impurities; Decomposition; Differential thermal analysis; Energy dispersive spectroscopy; Infrared spectroscopy; Iron compounds; Iron oxides; Neodymium alloys; Pyrolysis; Rietveld analysis; Rietveld method; Synthesis (chemical); Thermoanalysis; Thermogravimetric analysis; X ray diffraction; X ray spectroscopy; Electrical and magnetic property; Energy dispersive X ray spectroscopy; Heteronuclear complexes; Hexacyanoferrates; Mixed oxide; Orthorhombic crystal system; Powder X-ray diffraction (pXRD); Synthesis and characterizations; Crystal structure
Año:2015
Volumen:122
Número:1
Página de inicio:73
Página de fin:80
DOI: http://dx.doi.org/10.1007/s10973-015-4669-y
Título revista:Journal of Thermal Analysis and Calorimetry
Título revista abreviado:J Therm Anal Calor
ISSN:13886150
CODEN:JTACF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13886150_v122_n1_p73_Navarro

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Citas:

---------- APA ----------
Navarro, M.C., Jorge, G., Negri, R.M., Saleh Medina, L.M. & Gómez, M.I. (2015) . Synthesis and characterization of Bi1-xNdxFeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1-xNdx[Fe(CN)6]·4H2O. Journal of Thermal Analysis and Calorimetry, 122(1), 73-80.
http://dx.doi.org/10.1007/s10973-015-4669-y
---------- CHICAGO ----------
Navarro, M.C., Jorge, G., Negri, R.M., Saleh Medina, L.M., Gómez, M.I. "Synthesis and characterization of Bi1-xNdxFeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1-xNdx[Fe(CN)6]·4H2O" . Journal of Thermal Analysis and Calorimetry 122, no. 1 (2015) : 73-80.
http://dx.doi.org/10.1007/s10973-015-4669-y
---------- MLA ----------
Navarro, M.C., Jorge, G., Negri, R.M., Saleh Medina, L.M., Gómez, M.I. "Synthesis and characterization of Bi1-xNdxFeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1-xNdx[Fe(CN)6]·4H2O" . Journal of Thermal Analysis and Calorimetry, vol. 122, no. 1, 2015, pp. 73-80.
http://dx.doi.org/10.1007/s10973-015-4669-y
---------- VANCOUVER ----------
Navarro, M.C., Jorge, G., Negri, R.M., Saleh Medina, L.M., Gómez, M.I. Synthesis and characterization of Bi1-xNdxFeO3 (0 ≤ x ≤ 0.3) prepared by thermal decomposition of Bi1-xNdx[Fe(CN)6]·4H2O. J Therm Anal Calor. 2015;122(1):73-80.
http://dx.doi.org/10.1007/s10973-015-4669-y