Abstract:
DMSO has been widely investigated as a potential electrolyte for the Li-air battery systems, however its stability has been a topic of debate in the research community. In this communication we have identified the side reaction products during the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on Au in dimethyl sulfoxide-based electrolyte for Li-air battery by a combination of in-situ analytical tools: EQCM, SNIFTIRS, DEMS and XPS, in particular the evolution of CO2 from the solvent decomposition. © 2017 Elsevier B.V.
Registro:
Documento: |
Artículo
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Título: | Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution |
Autor: | Mozhzhukhina, N.; Marchini, F.; Torres, W.R.; Tesio, A.Y.; Mendez De Leo, L.P.; Williams, F.J.; Calvo, E.J. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
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Palabras clave: | Air; Battery; CO2; DMSO; Lithium; Oxygen; Air; Carbon; Carbon dioxide; Dimethyl sulfoxide; Electric batteries; Electrolytes; Electrolytic reduction; Lithium; Organic solvents; Oxygen; Battery; Carbon dioxide evolution; DMSO; Li-air batteries; Oxygen evolution reaction; Oxygen reduction reaction; Research communities; Solvent decompositions; Lithium batteries |
Año: | 2017
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Volumen: | 80
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Página de inicio: | 16
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Página de fin: | 19
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DOI: |
http://dx.doi.org/10.1016/j.elecom.2017.05.004 |
Título revista: | Electrochemistry Communications
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Título revista abreviado: | Electrochem. Commun.
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ISSN: | 13882481
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CODEN: | ECCMF
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13882481_v80_n_p16_Mozhzhukhina |
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Citas:
---------- APA ----------
Mozhzhukhina, N., Marchini, F., Torres, W.R., Tesio, A.Y., Mendez De Leo, L.P., Williams, F.J. & Calvo, E.J.
(2017)
. Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution. Electrochemistry Communications, 80, 16-19.
http://dx.doi.org/10.1016/j.elecom.2017.05.004---------- CHICAGO ----------
Mozhzhukhina, N., Marchini, F., Torres, W.R., Tesio, A.Y., Mendez De Leo, L.P., Williams, F.J., et al.
"Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution"
. Electrochemistry Communications 80
(2017) : 16-19.
http://dx.doi.org/10.1016/j.elecom.2017.05.004---------- MLA ----------
Mozhzhukhina, N., Marchini, F., Torres, W.R., Tesio, A.Y., Mendez De Leo, L.P., Williams, F.J., et al.
"Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution"
. Electrochemistry Communications, vol. 80, 2017, pp. 16-19.
http://dx.doi.org/10.1016/j.elecom.2017.05.004---------- VANCOUVER ----------
Mozhzhukhina, N., Marchini, F., Torres, W.R., Tesio, A.Y., Mendez De Leo, L.P., Williams, F.J., et al. Insights into dimethyl sulfoxide decomposition in Li-O2 battery: Understanding carbon dioxide evolution. Electrochem. Commun. 2017;80:16-19.
http://dx.doi.org/10.1016/j.elecom.2017.05.004