Abstract:
Gravimetric measurements during electrochemical redox switching of an Os-containing hydrogel film in contact with aqueous electrolyte have been obtained beyond the Sauerbrey rigid mass limit of the electrochemical quartz crystal microbalance (EQCM). For an acoustically non-rigid film the frequency-to-mass Sauerbrey relationship is not valid and the mass has been obtained from the experimental electroacoustic impedance data collected simultaneously with electrochemical experiments interpreted using Martin's viscoelastic model.
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Citas:
---------- APA ----------
Etchenique, R.A. & Calvo, E.J.
(1999)
. Gravimetric measurement in redox polymer electrodes with the EQCM beyond the Sauerbrey limit. Electrochemistry Communications, 1(5), 167-170.
http://dx.doi.org/10.1016/S1388-2481(99)00031-4---------- CHICAGO ----------
Etchenique, R.A., Calvo, E.J.
"Gravimetric measurement in redox polymer electrodes with the EQCM beyond the Sauerbrey limit"
. Electrochemistry Communications 1, no. 5
(1999) : 167-170.
http://dx.doi.org/10.1016/S1388-2481(99)00031-4---------- MLA ----------
Etchenique, R.A., Calvo, E.J.
"Gravimetric measurement in redox polymer electrodes with the EQCM beyond the Sauerbrey limit"
. Electrochemistry Communications, vol. 1, no. 5, 1999, pp. 167-170.
http://dx.doi.org/10.1016/S1388-2481(99)00031-4---------- VANCOUVER ----------
Etchenique, R.A., Calvo, E.J. Gravimetric measurement in redox polymer electrodes with the EQCM beyond the Sauerbrey limit. Electrochem. Commun. 1999;1(5):167-170.
http://dx.doi.org/10.1016/S1388-2481(99)00031-4