Artículo
Baggio, R.; Calvo, R.; Garland, M.T.; Peña, O.; Perec, M.; Slep, L.D. "A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline)" (2007) Inorganic Chemistry Communications. 10(11):1249-1252
Consulte la política de Acceso Abierto del editor
Abstract:
The oxydiacetate-bridged copper(II) complex [Cu(oda)(1,10-phen)] · 3H2O (oda = oxydiacetate dianion, 1,10-phen = 1,10-phenanthroline) has been characterized. The complex is dinuclear and centrosymmetric with each copper atom residing in a CuN2O4 octahedral environment. The Cu(II) ions are bridged by two carboxylate-oxygen atoms in a strictly planar Cu2O2 core with a Cu-Cu distance of 3.417(2) Å. The magnetic susceptibility measurements (2-300 K) show weak ferromagnetic coupling between the copper ions with J = 3.3 cm-1. The results are compared with those of the homologous [Cu(tda)(1,10-phen)]2tda (tda = thiodiacetate dianion). A model proposed for the electronic structures of the complexes based on the density functional theory (DFT) satisfactorily accounts for the magnetic results. © 2007 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline) |
| Autor: | Baggio, R.; Calvo, R.; Garland, M.T.; Peña, O.; Perec, M.; Slep, L.D. |
| Filiación: | Departamento de Física, Comisión Nacional de Energia Atómica, Av. Gral Paz 1499, 1650 San Martín, Buenos Aires, Argentina Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral, Güemes 3450, 3000 Santa Fe, Argentina Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Av. Blanco Encalada 2008, Santiago, Chile Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, Rennes, 35042 Rennes Cedex, France Departamento de Química Inorgánica Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina |
| Palabras clave: | Copper(II); Crystal structure; Magnetism; Oxydiacetate |
| Año: | 2007 |
| Volumen: | 10 |
| Número: | 11 |
| Página de inicio: | 1249 |
| Página de fin: | 1252 |
| DOI: | http://dx.doi.org/10.1016/j.inoche.2007.07.028 |
| Título revista: | Inorganic Chemistry Communications |
| Título revista abreviado: | Inorg. Chem. Commun. |
| ISSN: | 13877003 |
| CODEN: | ICCOF |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13877003_v10_n11_p1249_Baggio |
Referencias:
- Bleaney, B., Bowers, K.D., (1952) Proc. Roy. Soc. London A, 214, p. 451
- Kahn, O., (1993) Molecular Magnetism, , VCH Publ., New York
- Willet, R.D., Gatteschi, D., Kahn, O., (1985) Magneto-Structural Correlations in Exchange Coupled Systems, C140. , Reidel, Dordrecht, The Netherlands
- Gatteschi, D., Kahn, O., Miller, J.S., Palacio, F., (1991) Magnetic Molecular Materials, E198. , Plenum, New York
- Oldham, C., (1987) Comprehensive Coordination Chemistry, 2, p. 435. , Wilkinson G., Gillard R.D., and McCleverty J.A. (Eds), Pergamon, London
- Grirrane, A., Pastor, A., Ienco, A., Mealli, C., Galindo, A., (2002) J. Chem. Soc. Dalton Trans., p. 371. , and references therein
- Whitlow, S., Davey, G., (1975) J. Chem. Soc. Dalton Trans., p. 1228
- Cao, L., Li, N., Xu, D.-J., (2004) Acta Crystallogr. E, 60, pp. m1066
- Gonzalez-Pérez, J.M., Alarcón-Payer, C., Castiñeiras, A., Pivetta, T., Lezama, L., Choquesillo- Lazarte, D., Crisponi, G., Niclós-Gutiérrez, J., (2006) Inorg. Chem., 45, p. 877
- Bonomo, R.P., Rizzarelli, E., Bresciani Pahor, N., Nardin, G., (1981) Inorg. Chim. Acta, 54, pp. L17
- Bresciani Pahor, N., Nardin, G., Bonomo, R.P., Rizzarelli, E., (1983) J. Chem. Soc. Dalton Trans., p. 1797
- Wu, Z.-Y., Xu, D.-J., Luo, Y., Wu, J.-Y., Chiang, M.Y., (2003) Acta Crystallogr. C, 59, pp. m307
- Baggio, R., Garland, M.T., Manzur, J., Peña, O., Perec, M., Spodine, E., Vega, A., (1999) Inorg. Chim. Acta, 286, p. 74
- Grirrane, A., Pastor, A., Álvarez, E., Mealli, C., Ienco, I., Galindo, A., (2006) Inorg. Chem. Commun., 9, p. 160
- Grirrane, A., Pastor, A., Galindo, A., del Rio, D., Orlandini, A., Mealli, C., Ienco, I., Sanz, J.F., (2005) Angew. Chem. Int. Ed., 44, p. 3429
- note; note; Spek, A.L., (2003) J. Appl. Crystallogr., 36, p. 7. , PLATON:
- Sheldrick, G.M., (1997), SHELXL97:, University of Göttingen, Germany; Bruker, (2001) (Version 6.10) for Windows NT, , SHELXTL-NT:, Bruker AXS Inc., Madison, Wisconsin, USA
- Allen, F.H., (2002) Acta Crystallogr. B, 58, p. 380. , CDS:
- note; Soda, T., Kitagawa, Y., Onishi, T., Takano, Y., Shigeta, Y., Nagao, H., Yoshioka, Y., Yamaguchi, K., (2000) Chem. Phys. Lett., 319, p. 223
- Frisch, M.J., (2004) Gaussian 03, Revision D.01, , Gaussian Inc., Wallingford, CT
Citas:
---------- APA ----------
Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M. & Slep, L.D. (2007) . A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline). Inorganic Chemistry Communications, 10(11), 1249-1252.http://dx.doi.org/10.1016/j.inoche.2007.07.028
---------- CHICAGO ----------
Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M., Slep, L.D. "A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline)" . Inorganic Chemistry Communications 10, no. 11 (2007) : 1249-1252.http://dx.doi.org/10.1016/j.inoche.2007.07.028
---------- MLA ----------
Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M., Slep, L.D. "A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline)" . Inorganic Chemistry Communications, vol. 10, no. 11, 2007, pp. 1249-1252.http://dx.doi.org/10.1016/j.inoche.2007.07.028
---------- VANCOUVER ----------
Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M., Slep, L.D. A new copper(II) di-μ2-carboxylato bridged dinuclear complex: [Cu(oda)phen]2 · 6H2O (oda = oxydiacetate, phen = phenanthroline). Inorg. Chem. Commun. 2007;10(11):1249-1252.http://dx.doi.org/10.1016/j.inoche.2007.07.028
