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Ebrahimipour, S.Y.; Sheikhshoaie, I.; Mohamadi, M.; Suarez, S.; Baggio, R.; Khaleghi, M.; Torkzadeh-Mahani, M.; Mostafavi, A. "Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes" (2015) Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 142:410-422
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Abstract:

Two new Cu(II) complexes, [Cu(L)(phen)] (1), [Cu(L)(bipy)] (2), where L2- = (3-methoxy-2oxidobenzylidene)benzohydrazidato, phen = 1,10 phenanthroline, and bipy = 2,2′ bipyridine, were prepared and fully characterized using elemental analyses, FT-IR, molar conductivity, and electronic spectra. The structures of both complexes were also determined by X-ray diffraction. It was found that, both complexes possessed square pyramidal coordination environment in which, Cu(II) ions were coordinated by donor atoms of HL and two nitrogens of heterocyclic bases. Computational studies were performed using DFT calculations at B3LYP/6-311+G(d,p) level of theory. DNA binding activities of these complexes were also investigated using electronic absorption, competitive fluorescence titration and cyclic voltammetry studies. The obtained results indicated that binding of the complexes to DNA was of intercalative mode. Furthermore, antimicrobial activities of these compounds were screened against microorganisms. © 2015 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes
Autor:Ebrahimipour, S.Y.; Sheikhshoaie, I.; Mohamadi, M.; Suarez, S.; Baggio, R.; Khaleghi, M.; Torkzadeh-Mahani, M.; Mostafavi, A.
Filiación:Department of Chemistry, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran
Department of Chemistry, Payame Noor University (PNU), Tehran, 19395-4697, Iran
Departamento de Química Inorgínica, Analítica y Química, Física/INQUIMAE-CONICET, Universidad de Buenos Aires, Buenos Aires, Argentina
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Department of Biology, Faculty of Science, Shahid Bahonar University of Kerman, Kerman, Iran
Department of Biotechnology, Institute of Science, High Technology and Environmental Science, Graduate University of Advance Technology, Kerman, Iran
Palabras clave:Antimicrobial activity; Crystal structure; Cu(II) complex; DFT calculation; DNA binding; Hydrazone; Schiff base; Chelation; Complexation; Computation theory; Coordination reactions; Crystal structure; Cyclic voltammetry; Density functional theory; DNA; Functional groups; Microorganisms; Synthesis (chemical); X ray diffraction; Anti-microbial activity; Cu complexes; DFT calculation; DNA binding; Hydrazones; Schiff-base; Copper compounds; 2,2' bipyridine; antiinfective agent; coordination compound; copper; DNA; intercalating agent; phenanthroline derivative; animal; Bacterial Infections; bacterium; chemical structure; chemistry; drug effects; fungus; human; metabolism; Mycoses; salmonine; X ray crystallography; 2,2'-Dipyridyl; Animals; Anti-Infective Agents; Bacteria; Bacterial Infections; Coordination Complexes; Copper; Crystallography, X-Ray; DNA; Fungi; Humans; Intercalating Agents; Models, Molecular; Mycoses; Phenanthrolines; Salmon
Año:2015
Volumen:142
Página de inicio:410
Página de fin:422
DOI: http://dx.doi.org/10.1016/j.saa.2015.01.088
Título revista:Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Título revista abreviado:Spectrochim. Acta Part A Mol. Biomol. Spectrosc.
ISSN:13861425
CODEN:SAMCA
CAS:2,2' bipyridine, 366-18-7; copper, 15158-11-9, 7440-50-8; DNA, 9007-49-2; 2,2'-Dipyridyl; Anti-Infective Agents; Coordination Complexes; Copper; DNA; Intercalating Agents; Phenanthrolines
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13861425_v142_n_p410_Ebrahimipour

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Citas:

---------- APA ----------
Ebrahimipour, S.Y., Sheikhshoaie, I., Mohamadi, M., Suarez, S., Baggio, R., Khaleghi, M., Torkzadeh-Mahani, M.,..., Mostafavi, A. (2015) . Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 142, 410-422.
http://dx.doi.org/10.1016/j.saa.2015.01.088
---------- CHICAGO ----------
Ebrahimipour, S.Y., Sheikhshoaie, I., Mohamadi, M., Suarez, S., Baggio, R., Khaleghi, M., et al. "Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes" . Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 142 (2015) : 410-422.
http://dx.doi.org/10.1016/j.saa.2015.01.088
---------- MLA ----------
Ebrahimipour, S.Y., Sheikhshoaie, I., Mohamadi, M., Suarez, S., Baggio, R., Khaleghi, M., et al. "Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes" . Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, vol. 142, 2015, pp. 410-422.
http://dx.doi.org/10.1016/j.saa.2015.01.088
---------- VANCOUVER ----------
Ebrahimipour, S.Y., Sheikhshoaie, I., Mohamadi, M., Suarez, S., Baggio, R., Khaleghi, M., et al. Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 2015;142:410-422.
http://dx.doi.org/10.1016/j.saa.2015.01.088