Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

In this work, the ethanol steam reforming on Ni/γAl2O3 catalyst at temperatures between 573 and 773 K was studied and an overall reaction scheme as a function of temperature was proposed. It can be concluded that higher water/ethanol ratio (6:1) and higher temperature (773 K) promote hydrogen production (91% selectivity). Over Ni-based catalyst there would not be evidences that water gas shift reaction occurs. The presence of oxygen in the feed produces a favorable effect on carbon deposition; nevertheless the carbon monoxide production is not reduced. © 2003 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:Bio-ethanol steam reforming on Ni/Al2O3 catalyst
Autor:Comas, J.; Marino, F.; Laborde, M.; Amadeo, N.
Filiación:Lab. de Procesos Cataliticos, Depto. Ingenieria Química, Fac. de Ing. Pabellon de Industrias, Buenos Aires 1428, Argentina
Palabras clave:Ethanol reforming; Fuel cell; Hydrogen production; Ni-based catalyst; Alumina; Carbon monoxide; Deposition; Ethanol; High temperature effects; Hydrogen; Nickel; Steam; Gas shift reactions; Steam reforming; Catalysts; fuel cell
Año:2004
Volumen:98
Número:1-2
Página de inicio:61
Página de fin:68
DOI: http://dx.doi.org/10.1016/S1385-8947(03)00186-4
Título revista:Chemical Engineering Journal
Título revista abreviado:Chem. Eng. J.
ISSN:13858947
CODEN:CMEJA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13858947_v98_n1-2_p61_Comas

Referencias:

  • Klouz, V., Fierro, V., Denton, P., Katz, H., Lisse, J.P., Bouvot-Mauduit, S., Mirodatos, C., (2002) J. Power Sour., 105, p. 26
  • Peppley, B.A., Amhlett, J.C., Kearns, L.M., Mann, R.F., (1999) Appl. Catal. A, 179, p. 21
  • Peppley, B.A., Amhlett, J.C., Kearns, L.M., Mann, R.F., (1999) Appl. Catal. A, 179, p. 31
  • Lindstrom, B., Pettersson, L.J., (2001) Int. J. Hydrogen Energy, 26, p. 923
  • Garća, E.Y., Laborde, M.A., (1991) Int. J. Hydrogen Energy, 16, p. 307
  • Vasudeva, K., Mitra, N., Umansankar, P., Dhingra, S.C., (1996) Int. J. Hydrogen Energy, 2, p. 13
  • Iwasa, N., Takezawa, N., (1991) Bull. Chem. Soc. Jpn., 64, p. 2619
  • Cavallaro, S., Freni, S., (1996) Int. J. Hydrogen Energy, 216, p. 465
  • Marino, F.J., Cerrella, E.G., Duhalde, S., Jobbagy, M., Laborde, M., (1998) Int. J. Hydrogen Energy, 2312, p. 1095
  • Marino, F.J., Jobbagy, M., Baronetti, G., Laborde, M., (2000) Stud. Surf. Sci. Catal. C, 130, p. 2147
  • Cavallaro, S., (2000) Energy Fuels, 14, pp. 1195-1199
  • Freni, S., Mondello, N., Cavallaro, S., Cacciola, G., Parmon, V.N., Sobyanin, V.A., (2000) React. Kinet. Catal. Lett., 711, pp. 143-152
  • Galvita, V.V., Semin, G.L., Belyaev, V.D., Semikolenov, V.A., Tsiakaras, P., Sobyanin, V.A., (2001) Appl. Catal. A, 220, pp. 123-127
  • Liguras, D.K., Kondarides, D.I., Verykios, X.E., (2003) Appl. Catal. B, 43, pp. 345-354
  • Aupretre, F., Descome, C., Duprez, D., (2002) Catal. Commun., 3, pp. 263-267
  • Llorca, J., Homs, N., Sales, J., Ramirez de la Piscina, P., (2002) J. Catal., 209, pp. 306-317
  • Descorme, C., Madier, Y., Duprez, D., Birchem, T., (2000) Stud. Surf. Sci. Catal., 130, p. 347
  • Jiang, C.J., Trimm, D.L., Wainwright, M.S., Cant, N., (1993) Appl. Catal. A, 93, pp. 245-255
  • Jiang, C.J., Trimm, D.L., Wainwright, M.S., Cant, N., (1993) Appl. Catal. A, 97, pp. 145-158
  • Joensen, F., Rostrup-Nielsen, J.R., (2001) J. Power Sour., 4566, pp. 1-7
  • Haga, F., Nakajima, T., Miya, H., Mishima, S., (1997) Catal. Lett., 48, p. 223
  • Rostrup-Nielsen, J.R., Hojlund, N., (1985) Deactivation and Poisoning of Catalyst, p. 57. , J. Oudar, H. Wise (Eds.), Marcel Dekker, New York, Basel
  • Ioannides, T., (2001) J. Power Sour., 92, pp. 17-25

Citas:

---------- APA ----------
Comas, J., Marino, F., Laborde, M. & Amadeo, N. (2004) . Bio-ethanol steam reforming on Ni/Al2O3 catalyst. Chemical Engineering Journal, 98(1-2), 61-68.
http://dx.doi.org/10.1016/S1385-8947(03)00186-4
---------- CHICAGO ----------
Comas, J., Marino, F., Laborde, M., Amadeo, N. "Bio-ethanol steam reforming on Ni/Al2O3 catalyst" . Chemical Engineering Journal 98, no. 1-2 (2004) : 61-68.
http://dx.doi.org/10.1016/S1385-8947(03)00186-4
---------- MLA ----------
Comas, J., Marino, F., Laborde, M., Amadeo, N. "Bio-ethanol steam reforming on Ni/Al2O3 catalyst" . Chemical Engineering Journal, vol. 98, no. 1-2, 2004, pp. 61-68.
http://dx.doi.org/10.1016/S1385-8947(03)00186-4
---------- VANCOUVER ----------
Comas, J., Marino, F., Laborde, M., Amadeo, N. Bio-ethanol steam reforming on Ni/Al2O3 catalyst. Chem. Eng. J. 2004;98(1-2):61-68.
http://dx.doi.org/10.1016/S1385-8947(03)00186-4