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Abstract:

Biological, photo-Fenton (PF) and photo-Fenton mediated by ferrioxalate complexes (PF/Ferrioxalate) processes were examined for the degradation of a synthetic cotton-textile dyeing wastewater. Aerobic biological treatment had a negligible effect on discolouration whereas total organic content decreased mainly due to the biodegradation of acetic acid initially present in the wastewater. PF process yielded a fast and pronounced dissolved organic carbon concentration decay, mostly associated to the abrupt precipitation of Fe(III)-organic complexes. The addition of oxalic acid limited iron precipitation, allowing mineralization of most organic contaminants. The influence of the different dyes and main dyeing auxiliary constituents of the synthetic textile wastewater on the PF and the PF/Ferrioxalate efficiency was systematically analysed. The suitability of combining PF/Ferrioxalate with conventional biological processes as a pre and/or post treatment was evaluated.This study highlights the potential of PF/Ferrioxalate reaction to mineralize the synthetic cotton-textile wastewater under appropriate experimental conditions, the best being: [Fe3+]=40mgL-1, iron/oxalate molar ratio=1:3, pH=4.0 and [H2O2]=50-100 (1.5-2.9)mgL-1 (mmolL-1). At these conditions, the PF/Ferrioxalate treatment was carried out under natural sunlight in a pilot plant equipped with compound parabolic collectors. © 2015 Elsevier B.V.

Registro:

Documento: Artículo
Título:Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater
Autor:Doumic, L.I.; Soares, P.A.; Ayude, M.A.; Cassanello, M.; Boaventura, R.A.R.; Vilar, V.J.P.
Filiación:LSRE - Laboratory of Separation and Reaction Engineering, Associate Laboratory LSRE/LCM, Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, Porto, 4200-465, Portugal
División Catalizadores y Superficies, Instituto de Investigaciones en Ciencia y Tecnología de Materiales - INTEMA, Departamento de Ingeniería Química, Universidad Nacional de Mar del Plata, J.B. Justo 4302, Mar del Plata, 7600, Argentina
Laboratorio de Reactores y Sistemas para la Industria - LARSI, Departamento Industrias, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Buenos Aires, C1428BGA, Argentina
Palabras clave:Auxiliary products; Cotton-textile dyeing wastewater; Dyes; Ferrioxalate complexes; Solar photo-Fenton; Biodegradation; Chemicals removal (water treatment); Cotton; Decay (organic); Dyeing; Dyes; Iron compounds; Organic carbon; Oxalic acid; Oxidation; Pilot plants; Textile fibers; Textiles; Wastewater treatment; Aerobic biological treatment; Auxiliary products; Compound parabolic collector; Cotton textiles; Dissolved organic carbon; Experimental conditions; Ferrioxalate; Solar photo-Fenton; Biological water treatment; Gossypium hirsutum
Año:2015
Volumen:277
Página de inicio:86
Página de fin:96
DOI: http://dx.doi.org/10.1016/j.cej.2015.04.074
Título revista:Chemical Engineering Journal
Título revista abreviado:Chem. Eng. J.
ISSN:13858947
CODEN:CMEJA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13858947_v277_n_p86_Doumic

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Citas:

---------- APA ----------
Doumic, L.I., Soares, P.A., Ayude, M.A., Cassanello, M., Boaventura, R.A.R. & Vilar, V.J.P. (2015) . Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater. Chemical Engineering Journal, 277, 86-96.
http://dx.doi.org/10.1016/j.cej.2015.04.074
---------- CHICAGO ----------
Doumic, L.I., Soares, P.A., Ayude, M.A., Cassanello, M., Boaventura, R.A.R., Vilar, V.J.P. "Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater" . Chemical Engineering Journal 277 (2015) : 86-96.
http://dx.doi.org/10.1016/j.cej.2015.04.074
---------- MLA ----------
Doumic, L.I., Soares, P.A., Ayude, M.A., Cassanello, M., Boaventura, R.A.R., Vilar, V.J.P. "Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater" . Chemical Engineering Journal, vol. 277, 2015, pp. 86-96.
http://dx.doi.org/10.1016/j.cej.2015.04.074
---------- VANCOUVER ----------
Doumic, L.I., Soares, P.A., Ayude, M.A., Cassanello, M., Boaventura, R.A.R., Vilar, V.J.P. Enhancement of a solar photo-Fenton reaction by using ferrioxalate complexes for the treatment of a synthetic cotton-textile dyeing wastewater. Chem. Eng. J. 2015;277:86-96.
http://dx.doi.org/10.1016/j.cej.2015.04.074