Artículo

Zayat, L.; Filevich, O.; Baraldo, L.M.; Etchenique, R. "Ruthenium polypyridyl phototriggers: From beginnings to perspectives" (2013) Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences. 371(1995)
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Abstract:

Octahedral Ru(II) polypyridyl complexes constitute a superb platform to devise photoactive triggers capable of delivering entire molecules in a reliable, fast, efficient and clean way. Ruthenium coordination chemistry opens the way to caging a wide range of molecules, such as amino acids, nucleotides, neurotransmitters, fluorescent probes and genetic inducers. Contrary to other phototriggers, these Rubased caged compounds are active with visible light, and can be photolysed even at 532nm (green), enabling the use of simple and inexpensive equipment. These compounds are also active in the two-photon regime, a property that extends their scope to systems where IR light must be used to achieve high precision and penetrability. The state of the art and the future of ruthenium polypyridyl phototriggers are discussed, and several new applications are presented. © 2013 The Author(s) Published by the Royal Society. All rights reserved.

Registro:

Documento: Artículo
Título:Ruthenium polypyridyl phototriggers: From beginnings to perspectives
Autor:Zayat, L.; Filevich, O.; Baraldo, L.M.; Etchenique, R.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria Pabellón 2 Piso 3, Buenos Aires, Argentina
Palabras clave:Caged compounds; Gene inducer; Glutamate; Lac operon introduction; Neurotransmitters; Ruthenium; Amino acids; Coordination reactions; Molecules; Neurophysiology; Caged compounds; Co-ordination chemistries; Fluorescent probes; Glutamate; Inexpensive equipment; Lac operon; Neurotransmitters; New applications; Ruthenium
Año:2013
Volumen:371
Número:1995
DOI: http://dx.doi.org/10.1098/rsta.2012.0330
Título revista:Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
Título revista abreviado:Philos. Trans. R. Soc. A Math. Phys. Eng. Sci.
ISSN:1364503X
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1364503X_v371_n1995_p_Zayat

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Citas:

---------- APA ----------
Zayat, L., Filevich, O., Baraldo, L.M. & Etchenique, R. (2013) . Ruthenium polypyridyl phototriggers: From beginnings to perspectives. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 371(1995).
http://dx.doi.org/10.1098/rsta.2012.0330
---------- CHICAGO ----------
Zayat, L., Filevich, O., Baraldo, L.M., Etchenique, R. "Ruthenium polypyridyl phototriggers: From beginnings to perspectives" . Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 371, no. 1995 (2013).
http://dx.doi.org/10.1098/rsta.2012.0330
---------- MLA ----------
Zayat, L., Filevich, O., Baraldo, L.M., Etchenique, R. "Ruthenium polypyridyl phototriggers: From beginnings to perspectives" . Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol. 371, no. 1995, 2013.
http://dx.doi.org/10.1098/rsta.2012.0330
---------- VANCOUVER ----------
Zayat, L., Filevich, O., Baraldo, L.M., Etchenique, R. Ruthenium polypyridyl phototriggers: From beginnings to perspectives. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 2013;371(1995).
http://dx.doi.org/10.1098/rsta.2012.0330