Abstract:
Probe beam deflection during chronoamperometric oxidation-reduction of osmium complex in layer-by-layer self-assembled redox active polyelectrolyte multilayers has shown that the nature of the charge in the topmost layer determines the ion flux that balances the redox charge. © 2004 The Royal Society of Chemistry.
Registro:
Documento: |
Artículo
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Título: | Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films |
Autor: | Grumelli, D.E.; Wolosiuk, A.; Forzani, E.; Planes, G.A.; Barbero, C.; Calvo, E.J. |
Filiación: | INQUIMAE-Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, AR-1428, Argentina Departamento de Química, Universidad Nacional de Río Cuarto (UNRC), Agencia Postal No. 3, Río Cuarto, AR-5800, Argentina
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Palabras clave: | osmium; polyelectrolyte; amperometry; article; complex formation; electricity; film; ion exchange; molecular probe; oxidation reduction reaction |
Año: | 2003
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Volumen: | 3
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Número: | 24
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Página de inicio: | 3014
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Página de fin: | 3015
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DOI: |
http://dx.doi.org/10.1039/b308449c |
Título revista: | Chemical Communications
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Título revista abreviado: | Chem. Commun.
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ISSN: | 13597345
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CAS: | osmium, 7440-04-2
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13597345_v3_n24_p3014_Grumelli |
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Citas:
---------- APA ----------
Grumelli, D.E., Wolosiuk, A., Forzani, E., Planes, G.A., Barbero, C. & Calvo, E.J.
(2003)
. Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films. Chemical Communications, 3(24), 3014-3015.
http://dx.doi.org/10.1039/b308449c---------- CHICAGO ----------
Grumelli, D.E., Wolosiuk, A., Forzani, E., Planes, G.A., Barbero, C., Calvo, E.J.
"Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films"
. Chemical Communications 3, no. 24
(2003) : 3014-3015.
http://dx.doi.org/10.1039/b308449c---------- MLA ----------
Grumelli, D.E., Wolosiuk, A., Forzani, E., Planes, G.A., Barbero, C., Calvo, E.J.
"Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films"
. Chemical Communications, vol. 3, no. 24, 2003, pp. 3014-3015.
http://dx.doi.org/10.1039/b308449c---------- VANCOUVER ----------
Grumelli, D.E., Wolosiuk, A., Forzani, E., Planes, G.A., Barbero, C., Calvo, E.J. Probe beam deflection study of ion exchange in self-assembled redox polyelectrolyte thin films. Chem. Commun. 2003;3(24):3014-3015.
http://dx.doi.org/10.1039/b308449c