The evolution during thermal treatment of the precursor obtained by a new method to synthezise barium hexaferrite by chemical coprecipitation is described; the method involves the precipitation froma strongly alkaline ferrate(VI) solution containing barium chloride. Barium hexaferrite may be formed by heating of the original superparamagnetic precursor at temperatures as low as 700°C as shown by XRD, Mössbauer spectra and DTA-TGA behaviour. The precursor does not contain appreciable amounts of carbonate, thus favouring the formation of the hexaferrite at lower temperatures. Scanning electron microscopy shows that the ferrite particles are less than 0.5 μm in diameter.
Documento: | Artículo |
Título: | The thermal evolution of a barium ferrite precursor obtained by a new chemical coprecipitation method |
Autor: | Jacobo, S.E.; Blesa, M.A. |
Filiación: | Facultad de Ingenieria, Universidad de Buenos Aires, Paseo Colón, 850 Buenos Aires, Argentina Unidad de Actividad Quimica, Comn. Natl. de Ener. Atomica, Av. Libertador 8250, 1429 Buenos Aires, Argentina INQUIMAE, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina |
Palabras clave: | Barium compounds; Differential thermal analysis; Heat treatment; Iron oxides; Mossbauer spectroscopy; Particle size analysis; Precipitation (chemical); Scanning electron microscopy; Sodium compounds; Synthesis (chemical); Thermogravimetric analysis; X ray diffraction analysis; Barium chloride; Barium hexaferrite; Chemical coprecipitation method; Ferrates; Sodium hypochlorite; Ferrites |
Año: | 1997 |
Volumen: | 7 |
Número: | 1 |
Página de inicio: | C1 |
Página de fin: | 319-C1-320 |
Título revista: | Journal De Physique. IV : JP |
Título revista abreviado: | J Phy IV JP |
ISSN: | 11554339 |
CODEN: | JPICE |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_11554339_v7_n1_pC1_Jacobo |