Artículo
Di Santo, A.; Osiry, H.; Reguera, E.; Alborés, P.; Carbonio, R.E.; Ben Altabef, A.; Gil, D.M. "New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties" (2018) New Journal of Chemistry. 42(2):1347-1355
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Abstract:
Four coordination polymers obtained by the intercalation of 2-methylimidazole into transition metal nitroprussides T[Fe(CN)5NO] with T = Mn, Fe, Co and Ni were synthesized and characterized. The resulting hybrid inorganic-organic solids crystallize as dihydrates. All the solids were crystallized in an orthorhombic crystal system in the space group P212121. Their crystal structures were solved and refined from X-ray diffraction data, complemented by structural information derived from spectroscopic (IR, Raman and UV-Vis) and thermal data. The intercalated molecules occupy the axial coordination sites of the metal T(ii), while the Fe atom of the nitroprusside anion preserves the octahedral coordination geometry. In the interlayer region, the intercalated molecules retain their interaction through π-stacking interactions. The magnetic measurements indicate that all the solids show antiferromagnetic interactions at low temperatures due to intra-sheet antiferromagnetic exchange interactions of moderate strength. Only complexes with Fe(ii) and Mn(ii) show long-range inter-sheet ferromagnetic ordering. © 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Registro:
| Documento: | Artículo |
| Título: | New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties |
| Autor: | Di Santo, A.; Osiry, H.; Reguera, E.; Alborés, P.; Carbonio, R.E.; Ben Altabef, A.; Gil, D.M. |
| Filiación: | INQUINOA (CONICET-UNT), Instituto de Química Física, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, San Lorenzo 456, San Miguel de Tucumán, T4000CAN, Argentina Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada, Unidad Legaria, Instituto Politécnico Nacional, Mexico Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina INFIQC (CONICET-UNC), Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Haya de la Torre esquina Medina Allende, Córdoba, X5000HUA, Argentina |
| Palabras clave: | cobalt; imidazole derivative; iron; ligand; manganese; metal complex; methyl group; nickel; nitroprusside sodium; polymer; Article; chemical structure; crystal structure; crystallization; decomposition; differential thermal analysis; electron; hydrogen bond; infrared spectroscopy; low temperature; magnetic field; magnetism; priority journal; Raman spectrometry; structural model; synthesis; thermogravimetry; ultraviolet spectrophotometry; X ray powder diffraction |
| Año: | 2018 |
| Volumen: | 42 |
| Número: | 2 |
| Página de inicio: | 1347 |
| Página de fin: | 1355 |
| DOI: | http://dx.doi.org/10.1039/c7nj03585c |
| Título revista: | New Journal of Chemistry |
| Título revista abreviado: | New J. Chem. |
| ISSN: | 11440546 |
| CODEN: | NJCHE |
| CAS: | cobalt, 7440-48-4; iron, 14093-02-8, 53858-86-9, 7439-89-6; manganese, 16397-91-4, 7439-96-5; nickel, 7440-02-0; nitroprusside sodium, 14402-89-2, 15078-28-1 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_11440546_v42_n2_p1347_DiSanto |
Referencias:
- Corma, A., García, H., Llabrés Xamena, I.F.X., (2010) Chem. Rev., 110, p. 4606
- Stylianou, K.C., Heck, R., Chong, S.Y., Basca, J., Jones, J.T.A., Khimyak, Y.Z., Bradshaw, D., Rosseinsky, M.J., (2010) J. Am. Chem. Soc., 132, p. 4119
- Das, K., Mendiratta, S., Datta, A., Gajewska, M.J., Garribba, E., Akitsu, T., Sinha, C., (2016) ChemistrySelect, 1, p. 2192
- Li, Y., Liu, K., Li, W.J., Guo, A., Zhao, F.Y., Liu, H., Ruan, W.J., (2015) J. Phys. Chem. C, 119, p. 28544
- Morris, R.E., Wheatley, P.S., (2008) Angew. Chem., Int. Ed., 47, p. 4966
- Ferlay, S., Mallah, T., Ouahes, R., Veillet, P., Verdaguer, M., (1995) Nature, 378, p. 701
- Werner, J., Runčevski, T., Dinnebier, R., Ebbinghaus, S.G., Suckert, S., Näther, C., (2015) Eur. J. Inorg. Chem., p. 3236
- González, M., Lemus-Santana, A.A., Rodríguez-Hernández, J., Knobel, M., Reguera, E., (2013) J. Solid State Chem., 197, p. 317
- Niel, V., Martinez-Agudo, J.M., Muñoz, M.C., Gaspar, A.B., Real, J.A., (2001) Inorg. Chem., 40, p. 3838
- Agustí, G., Cobo, S., Gaspar, A.B., Molnár, G., Moussa, N.O., Szilágyi, P.A., Pálfi, V., Bousseksou, A., (2008) Chem. Mater., 20, p. 6721
- Southon, P.D., Liu, L., Fellows, E.A., Price, D.J., Halder, G.J., Chapman, K.W., Moubaraki, B., Kepert, C.J., (2009) J. Am. Chem. Soc., 131, p. 10998
- González, M., Lemus-Santana, A.A., Rodríguez-Hernández, J., Aguirre-Velez, C.I., Knobel, M., Reguera, E., (2013) J. Solid State Chem., 204, p. 128
- Echeverría, F., Lemus-Santana, A.A., González, M., Rodríguez-Hernández, J., Reguera, E., (2015) Polyhedron, 95, p. 75
- Osiry, H., Cano, A., Lemus-Santana, A.A., Rodríguez, A., Carbonio, R.E., Reguera, E., (2015) J. Solid State Chem., 230, p. 374
- Gil, D.M., Osiry, H., Rodrígez, A., Lemus-Santana, A.A., Carbonio, R.E., Reguera, E., (2016) Eur. J. Inorg. Chem., p. 1690
- Louer, D., Vargas, R., (1982) J. Appl. Crystallogr., 15, p. 540
- Le Bail, A., Duroy, H., Fourquet, J.L., (1988) Mater. Res. Bull., 23, p. 447
- Sheldrick, G.M., (1997) Program for Crystal Structure Determination, , University of Göttingen, Germany
- Young, R.A., (1995) The Rietveld Method, , Oxford University Press, New York
- Rodriguez Carvajal, J., (1993) Physica B, 192, p. 55
- Mullica, D.B., Trippin, D.F., Sappenfield, E.L., (1990) Inorg. Chim. Acta, 174, p. 129
- Mullica, D.B., Trippin, D.F., Sappenfield, E.L., (1992) J. Coord. Chem., 25, p. 175
- Nakamoto, K., (2009) Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part B, Applications in Coordination, Organometallic, and Bioinorganic Chemistry, , John Wiley
- Manoharan, P.T., Gray, H.B., (1965) J. Am. Chem. Soc., 87, p. 3340
- Smekal, Z., Maris, T., Korabik, M., (2014) J. Coord. Chem., 67, p. 3167
- Peresypkina, E.V., Vostrikova, K.E., (2012) Dalton Trans., 41, p. 4100
- Yang, C., Wang, Q.L., Ma, Y., Tang, G.T., Liao, D.Z., Yan, S.P., Yang, G.M., Cheng, P., (2010) Inorg. Chem., 49, p. 2047
- You, Y.S., Yoon, J.H., Lim, J.H., Kim, H.C., Hong, C.S., (2007) Inorg. Chim. Acta, 360, p. 2523
- Shevchenko, D.V., Petrusenko, S.R., Kokozay, V.N., Tomkiewicz, A., Klak, J., Mrozinski, J., Krasovska, M.V., Linert, W., (2007) Inorg. Chim. Acta, 360, p. 2846
- Chen, X.Y., Shi, W., Xia, J., Cheng, P., Zhao, B., Song, H.B., Wang, H.G., Jiang, Z.H., (2005) Inorg. Chem., 44, p. 4263
- Shyu, H.L., Wei, H.H., (1999) J. Coord. Chem., 47, p. 319
Citas:
---------- APA ----------
Di Santo, A., Osiry, H., Reguera, E., Alborés, P., Carbonio, R.E., Ben Altabef, A. & Gil, D.M. (2018) . New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties. New Journal of Chemistry, 42(2), 1347-1355.http://dx.doi.org/10.1039/c7nj03585c
---------- CHICAGO ----------
Di Santo, A., Osiry, H., Reguera, E., Alborés, P., Carbonio, R.E., Ben Altabef, A., et al. "New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties" . New Journal of Chemistry 42, no. 2 (2018) : 1347-1355.http://dx.doi.org/10.1039/c7nj03585c
---------- MLA ----------
Di Santo, A., Osiry, H., Reguera, E., Alborés, P., Carbonio, R.E., Ben Altabef, A., et al. "New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties" . New Journal of Chemistry, vol. 42, no. 2, 2018, pp. 1347-1355.http://dx.doi.org/10.1039/c7nj03585c
---------- VANCOUVER ----------
Di Santo, A., Osiry, H., Reguera, E., Alborés, P., Carbonio, R.E., Ben Altabef, A., et al. New coordination polymers based on 2-methylimidazole and transition metal nitroprusside containing building blocks: Synthesis, structure and magnetic properties. New J. Chem. 2018;42(2):1347-1355.http://dx.doi.org/10.1039/c7nj03585c
