Abstract:
Large-pore TiO2 and ZrO2 mesoporous films with 2D-Hex or cubic mesostructures were prepared by dip-coating. Organic bifunctional molecules presenting an organic function and a complexing grafting group (phosphate, carboxylate) were explored as surface modifiers. The incorporation of these functions into the mesoporous network was monitored by crossed FT-IR and EDS techniques. Leaching experiments in different conditions were performed to assess the anchoring of the grafted groups. While phosphate or phosphonate groups are strongly grafted, carboxylate functions can be released in a pH-dependent way.
Registro:
Documento: |
Artículo
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Título: | Hybrid non-silica mesoporous thin films |
Autor: | Angelomé, P.C.; Aldabe-Bilmes, S.; Calvo, M.E.; Crepaldi, E.L.; Grosso, D.; Sanchez, C.; Soler-Illia, G.J.A.A. |
Filiación: | Unidad de Actividad Química, Comision Nacional de Energia Atomica, Centro Atómico Constituyentes, Av. Gral Paz 1499, San Martin, B1650KNA Buenos Aires, Argentina INQUIMAE-DQIAQF, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, C1428EHA Buenos Aires, Argentina Lab. de Chim. de la Matiere Cond., CNRS UMR 7574, Universite Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France
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Palabras clave: | carboxylic acid; organic compound; phosphate; phosphonic acid derivative; silicon dioxide; titanium dioxide; zirconium oxide; article; chemical structure; composite material; energy dispersion spectroscopy; film; infrared spectroscopy; leaching; pH; porosity; priority journal; spectroscopy; synthesis |
Año: | 2005
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Volumen: | 29
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Número: | 1
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Página de inicio: | 59
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Página de fin: | 63
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DOI: |
http://dx.doi.org/10.1039/b415324c |
Título revista: | New Journal of Chemistry
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Título revista abreviado: | New J. Chem.
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ISSN: | 11440546
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CODEN: | NJCHE
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CAS: | phosphate, 14066-19-4, 14265-44-2; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9; titanium dioxide, 1317-70-0, 1317-80-2, 13463-67-7, 51745-87-0; zirconium oxide, 1314-23-4, 53801-45-9
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_11440546_v29_n1_p59_Angelome |
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Citas:
---------- APA ----------
Angelomé, P.C., Aldabe-Bilmes, S., Calvo, M.E., Crepaldi, E.L., Grosso, D., Sanchez, C. & Soler-Illia, G.J.A.A.
(2005)
. Hybrid non-silica mesoporous thin films. New Journal of Chemistry, 29(1), 59-63.
http://dx.doi.org/10.1039/b415324c---------- CHICAGO ----------
Angelomé, P.C., Aldabe-Bilmes, S., Calvo, M.E., Crepaldi, E.L., Grosso, D., Sanchez, C., et al.
"Hybrid non-silica mesoporous thin films"
. New Journal of Chemistry 29, no. 1
(2005) : 59-63.
http://dx.doi.org/10.1039/b415324c---------- MLA ----------
Angelomé, P.C., Aldabe-Bilmes, S., Calvo, M.E., Crepaldi, E.L., Grosso, D., Sanchez, C., et al.
"Hybrid non-silica mesoporous thin films"
. New Journal of Chemistry, vol. 29, no. 1, 2005, pp. 59-63.
http://dx.doi.org/10.1039/b415324c---------- VANCOUVER ----------
Angelomé, P.C., Aldabe-Bilmes, S., Calvo, M.E., Crepaldi, E.L., Grosso, D., Sanchez, C., et al. Hybrid non-silica mesoporous thin films. New J. Chem. 2005;29(1):59-63.
http://dx.doi.org/10.1039/b415324c