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Abstract:

Laser-induced optoacoustic spectroscopy (LIOAS), diffuse reflectance laser flash photolysis (DRLFP), and laser-induced luminescence (LIL) have been applied in conjunction to the determination of triplet state quantum yields of Rose Bengal (RB) supported on microcrystalline cellulose, a strongly light-scattering solid. Among the three used methods, the only one capable of providing absolute triplet quantum yields is LIOAS, but DRLFP and LIL aid in demonstrating that the LIOAS signal arises in fact from the triplet state and confirm the trend found with RB concentration. The coherence found for the three techniques demonstrates the usefulness of the approach. Observed triplet quantum yields are nearly constant within a limited concentration range, after which they decay strongly due to the generation of inactive dye aggregates or energy trapping centers. When quantum yields are divided by the fraction of absorbed light exciting the dye, the quotient falls off steadily with concentration, following the same trend as the observed fluorescence quantum yield. The conditions that maximize triplet formation are determined as a compromise between the rising light absorption and the decrease of quantum yield with RB concentration. © 2014 American Chemical Society.

Registro:

Documento: Artículo
Título:Effect of concentration on the formation of Rose Bengal triplet state on microcrystalline cellulose: A combined Laser-induced optoacoustic spectroscopy, diffuse reflectance flash photolysis, and luminescence study
Autor:Litman, Y.; Voss, M.G.; Rodríguez, H.B.; Román, E.S.
Filiación:INQUIMAE (UBA-CONICET)/DQIAyQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires, Argentina
INIFTA (UNLP-CONICET), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Diag. 113 y Calle 64, La Plata, Argentina
Palabras clave:Cellulose; Crystalline materials; Dyes; Electromagnetic launchers; Electromagnetic wave absorption; Light; Light absorption; Light scattering; Luminescence; Photoacoustic spectroscopy; Photolysis; Quantum yield; Reflection; Concentration ranges; Diffuse reflectance; Fluorescence quantum yield; Laser flash photolysis; Laser-induced optoacoustic spectroscopy; Luminescence studies; Micro-crystalline cellulose; Triplet quantum yields; Quantum theory
Año:2014
Volumen:118
Número:45
Página de inicio:10531
Página de fin:10537
DOI: http://dx.doi.org/10.1021/jp5045095
Título revista:Journal of Physical Chemistry A
Título revista abreviado:J Phys Chem A
ISSN:10895639
CODEN:JPCAF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10895639_v118_n45_p10531_Litman

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Citas:

---------- APA ----------
Litman, Y., Voss, M.G., Rodríguez, H.B. & Román, E.S. (2014) . Effect of concentration on the formation of Rose Bengal triplet state on microcrystalline cellulose: A combined Laser-induced optoacoustic spectroscopy, diffuse reflectance flash photolysis, and luminescence study. Journal of Physical Chemistry A, 118(45), 10531-10537.
http://dx.doi.org/10.1021/jp5045095
---------- CHICAGO ----------
Litman, Y., Voss, M.G., Rodríguez, H.B., Román, E.S. "Effect of concentration on the formation of Rose Bengal triplet state on microcrystalline cellulose: A combined Laser-induced optoacoustic spectroscopy, diffuse reflectance flash photolysis, and luminescence study" . Journal of Physical Chemistry A 118, no. 45 (2014) : 10531-10537.
http://dx.doi.org/10.1021/jp5045095
---------- MLA ----------
Litman, Y., Voss, M.G., Rodríguez, H.B., Román, E.S. "Effect of concentration on the formation of Rose Bengal triplet state on microcrystalline cellulose: A combined Laser-induced optoacoustic spectroscopy, diffuse reflectance flash photolysis, and luminescence study" . Journal of Physical Chemistry A, vol. 118, no. 45, 2014, pp. 10531-10537.
http://dx.doi.org/10.1021/jp5045095
---------- VANCOUVER ----------
Litman, Y., Voss, M.G., Rodríguez, H.B., Román, E.S. Effect of concentration on the formation of Rose Bengal triplet state on microcrystalline cellulose: A combined Laser-induced optoacoustic spectroscopy, diffuse reflectance flash photolysis, and luminescence study. J Phys Chem A. 2014;118(45):10531-10537.
http://dx.doi.org/10.1021/jp5045095