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Calvo, R.; Rapp, R.E.; Sartoris, R.P.; Santana, R.C.; Perec, M. "Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study" (2009) Journal of Physical Chemistry A. 113(31):8830-8833
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Abstract:

We report powder EPR measurements at 9.48 GHz and temperatures of 4 K ≤ T ≤ 300 K and at 33.86 GHz and T = 300 K for the polymeric compound {[Cu 2Er2(L)10(H2O)4].3H 2O)n (HL = frans-2-butenoic acid) having alternate Cu 2 and Er2 dinuclear units bridged by carboxylates along a chain. Above 70 K, when the ErIII resonance is unobservable and uncoupled from the CuII ions, the spectrum arises from the excited triplet state of antiferromagnetic Cu2 units, decreasing in intensity as T decreases, and disappearing when these units condensate into the singlet ground state. Fit of a model to the spectra at 9.48 and 33.86 GHz and 300 K gives gcu| = 2.379, gcu- = 2.065, DCu = -0.340 cm-1, and ECu ∼ 0 for the g-factors and zero field splitting parameters. From the T dependence of the intensity of the spectrum above 70 K, we obtain Jcu-cu; = -336(11) cm-1 for the intradinuclear exchange interaction. Below 50 K, a spectrum attributed to Er2 units appears, narrows, and resolves as T decreases, due to the increase of the spin-lattice relaxation time T1. The spectrum at 4 K allows calculating g values g1 = 1.489, g2 = 2.163, and g 3 = 5.587 and zero field splitting parameters DEr = -0.237 cm-1 and EEr = 0.020 cm-1. The results are discussed in terms of the properties of the Cu and Er ions, and the crystal structure of the compound. © 2009 American Chemical Society.

Registro:

Documento: Artículo
Título:Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study
Autor:Calvo, R.; Rapp, R.E.; Sartoris, R.P.; Santana, R.C.; Perec, M.
Filiación:Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina
Instituto de Física, Universidade Federal do Rio de Janeiro, 21941-972, Rio de Janeiro, RJ, Brazil
Instituto de Física, Universidade Federal de Goiás, CP 131, 74001-970, Goiania, GO, Brazil
Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:Antiferromagnetics; Dinuclear units; EPR measurements; EPR studies; Excited triplet state; G factors; G-values; Polymeric compounds; Singlet ground state; Spin carriers; Unobservable; Zero-field splitting parameters; Antiferromagnetism; Carboxylation; Crystal structure; Electron resonance; Electron spin resonance spectroscopy; Erbium; Paramagnetic resonance; Quantum theory; Spin dynamics; Erbium compounds; carboxylic acid; copper; erbium; chemistry; electron spin resonance; letter; magnetism; temperature; Carboxylic Acids; Copper; Electron Spin Resonance Spectroscopy; Erbium; Magnetics; Temperature
Año:2009
Volumen:113
Número:31
Página de inicio:8830
Página de fin:8833
DOI: http://dx.doi.org/10.1021/jp905310t
Título revista:Journal of Physical Chemistry A
Título revista abreviado:J Phys Chem A
ISSN:10895639
CODEN:JPCAF
CAS:copper, 15158-11-9, 7440-50-8; erbium, 7440-52-0; Carboxylic Acids; Copper, 7440-50-8; Erbium, 7440-52-0
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10895639_v113_n31_p8830_Calvo

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Citas:

---------- APA ----------
Calvo, R., Rapp, R.E., Sartoris, R.P., Santana, R.C. & Perec, M. (2009) . Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study. Journal of Physical Chemistry A, 113(31), 8830-8833.
http://dx.doi.org/10.1021/jp905310t
---------- CHICAGO ----------
Calvo, R., Rapp, R.E., Sartoris, R.P., Santana, R.C., Perec, M. "Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study" . Journal of Physical Chemistry A 113, no. 31 (2009) : 8830-8833.
http://dx.doi.org/10.1021/jp905310t
---------- MLA ----------
Calvo, R., Rapp, R.E., Sartoris, R.P., Santana, R.C., Perec, M. "Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study" . Journal of Physical Chemistry A, vol. 113, no. 31, 2009, pp. 8830-8833.
http://dx.doi.org/10.1021/jp905310t
---------- VANCOUVER ----------
Calvo, R., Rapp, R.E., Sartoris, R.P., Santana, R.C., Perec, M. Alternate Cu2 and Er2 spin carriers in a carboxylate-bridged chain: EPR study. J Phys Chem A. 2009;113(31):8830-8833.
http://dx.doi.org/10.1021/jp905310t