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Micaela Gonzalez, M.; Arnbjerg, J.; Paula Denofrio, M.; Erra-Balsells, R.; Ogilby, P.R.; Cabrerizo, F.M. "One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics" (2009) Journal of Physical Chemistry A. 113(24):6648-6656
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Abstract:

β-Carboline (βC) alkaloids are present in a wide range of biological systems and play a variety of significant photodependent roles. In this work, a study of the aqueous solution-phase photochemistry, photophysics, and spectroscopy of three important βCs [norharmane (nHo), harmane (Ho), and harmine (Ha)] and two βC derivatives [N-methylnorharmane (N-Me-nHo) and N-methylharmane (N-Me-Ho)] upon one- and two-photon excitation is presented. The results obtained depend significantly on pH, the ambient oxygen concentration, and the βC substituent and provide unique insight into a variety of fundamental photophysical phenomena. The data reported herein should not only help to understand the roles played by βC alkaloids in biological systems but should also help in the development of methods by which the photoinduced behavior of these important compounds can be controlled. © 2009 American Chemical Society.

Registro:

Documento: Artículo
Título:One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics
Autor:Micaela Gonzalez, M.; Arnbjerg, J.; Paula Denofrio, M.; Erra-Balsells, R.; Ogilby, P.R.; Cabrerizo, F.M.
Filiación:CIHIDECAR-CONICET, Departamento de Química Orgánica, Ciudad Universitaria, 1428 - Buenos Aires, Argentina
Center for Oxygen Microscopy and Imaging, Department of Chemistry, Aarhus University, DK-8000 Arhus, Denmark
INIFTA-CONICET-CIC, Departamento de Química, Universidad Nacional de la Plata, Casilla de Correo 16, Sucursal 4, 1900 La Plata, Argentina
Palabras clave:Ambient oxygen concentrations; Aqueous solutions; Carbolines; Harmane; PH-dependent; Photo-induced; Photophysical phenomena; Photophysics; Two-photon excitations; Cesium; Holmium; Oxygen; Photons; Biological systems; carboline derivative; hydrogen peroxide; water; article; chemical structure; chemistry; fluorescence; high performance liquid chromatography; methodology; pH; photochemistry; photon; quantum theory; solution and solubility; time; ultraviolet spectrophotometry; Carbolines; Chromatography, High Pressure Liquid; Fluorescence; Hydrogen Peroxide; Hydrogen-Ion Concentration; Molecular Structure; Photochemistry; Photons; Quantum Theory; Solutions; Spectrophotometry, Ultraviolet; Time Factors; Water
Año:2009
Volumen:113
Número:24
Página de inicio:6648
Página de fin:6656
DOI: http://dx.doi.org/10.1021/jp902105x
Título revista:Journal of Physical Chemistry A
Título revista abreviado:J Phys Chem A
ISSN:10895639
CODEN:JPCAF
CAS:hydrogen peroxide, 7722-84-1; water, 7732-18-5; Carbolines; Hydrogen Peroxide, 7722-84-1; Solutions; Water, 7732-18-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10895639_v113_n24_p6648_MicaelaGonzalez

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Citas:

---------- APA ----------
Micaela Gonzalez, M., Arnbjerg, J., Paula Denofrio, M., Erra-Balsells, R., Ogilby, P.R. & Cabrerizo, F.M. (2009) . One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics. Journal of Physical Chemistry A, 113(24), 6648-6656.
http://dx.doi.org/10.1021/jp902105x
---------- CHICAGO ----------
Micaela Gonzalez, M., Arnbjerg, J., Paula Denofrio, M., Erra-Balsells, R., Ogilby, P.R., Cabrerizo, F.M. "One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics" . Journal of Physical Chemistry A 113, no. 24 (2009) : 6648-6656.
http://dx.doi.org/10.1021/jp902105x
---------- MLA ----------
Micaela Gonzalez, M., Arnbjerg, J., Paula Denofrio, M., Erra-Balsells, R., Ogilby, P.R., Cabrerizo, F.M. "One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics" . Journal of Physical Chemistry A, vol. 113, no. 24, 2009, pp. 6648-6656.
http://dx.doi.org/10.1021/jp902105x
---------- VANCOUVER ----------
Micaela Gonzalez, M., Arnbjerg, J., Paula Denofrio, M., Erra-Balsells, R., Ogilby, P.R., Cabrerizo, F.M. One- and two-photon excitation of β-carbolines in aqueous solution: ph-dependent spectroscopy, photochemistry, and photophysics. J Phys Chem A. 2009;113(24):6648-6656.
http://dx.doi.org/10.1021/jp902105x