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Abstract:

Major and trace elements, pH, electrical conductivity and organic matter were determined in groundwater and subsoil samples collected from an urban solid waste final disposal site (Gualeguaychú city, Argentina) in order to quantify leachate impact on the quality of these resources. Geochemical modeling results showed mixing process of pristine water and leachate in different proportions which promote, in turn, other processes in the free aquifer such as cation exchange, outgassing of carbon dioxide, precipitation and dissolution of minerals. Anomalous electrical conductivity values of subsoil samples confirmed the leachate impact too. Soilwater interaction allowed the development of natural attenuation processes in water: low dissolved organic carbon (DOC), iron and aluminum concentrations were associated with high amounts in subsoil. High clay content (smectites) and high cation exchange capacity, organic matter and metals analysis suggesting that the exchange and or sorption process were effective. aδ13 C-DOC constant values ratified the DOC sorption in sediments rather than oxidation. Other natural processes such evaporation and marine ingressions were detected through geochemical models. aδ18O y aδ2 H values suggested not only a meteoric origin for the groundwater but also evaporation and mix process of waters. aδ aδ31C-DIC demonstrated that CO2 outgassing could have happened during the mixing.

Registro:

Documento: Artículo
Título:Hydrogeochemistry and stable isotopes of a solid waste disposal area from gualeguaychú, entreríos, Argentina
Autor:Sanci, R.; Panarello, H.O.; Cravero, F.
Filiación:Instituto de Geocronología Y Geología Isotópica, Universidad Buenos Aires - Consejo Nacional de Investigaciones Científicas Y Técnicas, Pabellón INGEIS, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, C1428EHA, Argentina
CETMIC (Centro de Tecnología de Recursos Minerales Y Cerámica), Camino Centenario y 506, Gonnet, La Plata, B1897ZCA, Argentina
Palabras clave:Contamination; Environmental isotopes; Geochemical processes; Leachate; Aquifers; Biogeochemistry; Biological materials; Carbon dioxide; Contamination; Electric conductivity; Evaporation; Geochemistry; Groundwater; Groundwater resources; Hydrochemistry; Isotopes; Mixing; Natural attenuation; Organic carbon; Organic compounds; Positive ions; Soils; Solid wastes; Trace elements; Urban growth; Cation exchange capacities; Dissolution of minerals; Dissolved organic carbon; Electrical conductivity; Environmental isotopes; Geochemical process; Leachates; Major and trace elements; Waste disposal
Año:2016
Volumen:42
Número:2
Página de inicio:71
Página de fin:86
DOI: http://dx.doi.org/10.5276/JSWTM.2016.71
Título revista:Journal of Solid Waste Technology and Management
Título revista abreviado:J Solid Waste Technol Manage
ISSN:10881697
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10881697_v42_n2_p71_Sanci

Referencias:

  • (2007), http://www.anmat.gov.ar/alimentos/normativas_alimentos_caa.asp, ANMAT; Auge, M., Sánchez, C., Santi, M., Hidrogeología de la región arrocera de Entre Ríos. IV Congreso Hidrogeológico Argentino (2005) Actas CGO, pp. 1-9. , Río Cuarto, Argentina
  • Baedecker, M., Back, W., Hydrogeological process and chemical reactions at a landfill (1979) Groundwater, 17, pp. 417-429
  • Barlaz, M.A., Ham, R.K., Leachate and gas generation (1993) Geotechnical Practice for Waste Disposal, p. 113. , D. E Daniel (Ed.) London: Chapman and Hall
  • Bjerg, P.L., Albrechtsen, H.J., Kjeldsen, P., Christensen, T.H., The groundwater of waste disposal facilities (2005) Tratise on Geochemistry, 9, pp. 579-612. , B. S Lollar (Ed.) Environmental Geochemistry NewYork: Springer
  • Bocanegra, E., Massone, H., Martinez, D., Civit, E., Farenga, M., Groundwater contamination: Risk management and assessment for landfills in Mar del Plata, Argentina (2001) Environmental Geology, 40 (6), pp. 732-741
  • Boujon, P., Sanci, R., Evaluación de la vulnerabilidad del acuífero libre en la cuenca del Arroyo El Cura, Gualeguaychú, Entre Ríos (2014) Revista de la Asociación Geológica Argentina, 71 (2), pp. 274-289
  • Boujon, P., (2014) Estudio de la Contaminación de Aguas Subterráneas por Métodos Geofísicos e Hidrogeológicos, , Tesis doctoral, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires
  • Boujon, P., Sanci, R., Stöckli, F., Dapeña, C.Y., (2006) Caracterización Hidroquímica e Isotópica de las Aguas Subterráneas de la Ciudad de Gualeguaychú, entre Ríos, Argentina, , VIII Congreso Latinoamericano de Hidrogeología (ALSHUD), Memorias Anais: 32, Asunción, Paraguay
  • Boujon, P., Pomposiello, C., Sanci, R., (2011) Estudios Geofísicos en Sitio de Disposición Final de Residuos Sólidos Urbanos Ciudad de Gualeguaychú, entre Ríos, Argentina: Evidencia de Contaminación, pp. 205-212. , VII Congreso de Hidrogeología y V Seminario Hispano Latinoamericano sobre temas actuales de la Hidrología Subterránea. Hidrogeología Regional y Exploración Hidrogeológica Salta, Argentina
  • Bower, C.A., Wilcox, L.V., Soluble salts (1965) Methods of Soil Analysis, pp. 933-940. , C. A, Black (Ed.) Madison, WI, USA: American Society of Agronomy
  • Bozkurt, S., Moreno, L., Neretnieks, I., Long-term processes in waste deposits (2000) The Science of the Total Environment, 250, pp. 101-121
  • Castañeda, S.S., Sucgang, R.J., Almoneda, R.V., Mendoza, N.D.S., David, C.P.C., Environmental isotopes and major ions for tracing leachate contamination from a municipal landfill in Metro Manila, Philippines (2012) Journal of Environmental Radioactivity, 110, pp. 30-37
  • Chapman, H.D., Cation exchange capacity (1965) Methods of Soil Analysis, pp. 891-900. , C.A. Black (Ed.) Madison, WI, USA: American Society of Agronomy
  • Christensen, T.H., Kjeldsen, P., Albrechtsen, H.J., Heron, G., Nielsen, P.H., Attenuation of landfill leachate pollutants in aquifers (1994) Critical Reviews in Environmental Science & Technology, 24, pp. 119-202
  • Christensen, T.H., Kjeldsen, P., Bjerg, P.L., Jensen, D.L., Christensen, J.B., Baun, A., Albrechtsen, H.J., Heron, G., Biogeochemistry of landfill leachate plumes (2001) Applied Geochemistry, 16, pp. 659-718
  • Clark, I.D., Fritz, M., (1997) Environmental Isotopes in Hydrogeology, , New York, Lewis Publishers
  • Conti, M., Materia orgánica (2007) Principios de Edafología, Buenos Aires, pp. 67-85. , En M. Conti (Ed) Facultad de Agronomia, UBA
  • Dapeña, Isótopos estables livianos (2007) Su Aplicación en Hidrología e Hidrogeología, , Tesis doctoral, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires
  • Dapeña, C., Panarello, H.O., Composición isotópi-ca de la lluvia de Buenos Aires. Su importancia para el estudio de los sistemas hidrológicos pampeanos (2004) Revista Latino-Americana de Hidrogeología, 4, pp. 17-25
  • Dapeña, C., Panarello, H.O., (2007) Estación Santa Fe. Red Nacional de Colectores Argentina (Resumen), pp. 187-198. , V Congreso Argentino de Hidrogeología, Paraná, Entre Ríos, IAH Universidad Nacional de Entre Ríos
  • Farquar, G.J., Rovers, F.A., Gas production during refuse decomposition (1973) Water Air and Soil Pollution, 2, pp. 483-495
  • Gandhi, H., Wiegner, T.N., Ostrom, P.H., Kaplan, L.A., Ostrom, N.E., Isotopic (13 C) analysis of dissolved organic carbon in stream water using an elemental analyzer coupled to a stable isotope ratio mass (2004) Rapid Communications in Mass Spectrometry, 18, pp. 903-906
  • Dorronsoro, G.I.C., (2005) Contaminación por Metales Pesados, , http://edafologia.ugr.es, Tecnología de Suelos. Universidad de Granada. Departamento de Edafología y Química Agrícola
  • Gat, J.R., (2010) Isotope Hydrology. A Study of the Water Cycle, , Centre for Environmental Technology. London: Imperial College
  • González, G.N.M., (1984) Evidencias Paleoestuáricas en El Sudoeste de entre Ríos, su Evolución Con Niveles Marinos Relativamente Elevados del Pleistoceno Superior y Holoceno, pp. 577-594. , 9° Congreso Geológico Argentino, Actas 3 Bariloche
  • Hackley, K.C., Liu, C.L., Coleman, D.D., Environmental isotope characteristics of landfill leachates and gases (1996) Ground Water, 34 (5), pp. 827-836
  • Hornibrook, E.R.C., Longstaffe, F.J., Fyfe, W.S., Evolution of stable carbon isotope compositions for methane and carbon dioxide in freshwater wetlands and other anaerobic environments (2000) Geochimica et Cosmochimica Acta, 64 (6), pp. 1013-1027
  • Iriondo, M., El Cuaternario de Entre Ríos (1980) Revista de la Asociación de Ciencias Naturales del Litoral, 11, pp. 125-141
  • Kahle, M., Kleber, R.M., Retention of dissolved organic matter by phyllosilicate and soil clay fractions in relation to mineral properties (2004) Organic Geochemistry, 35, pp. 269-276
  • Kalbitz, K., Schmerwitz, J., Schwesig, D., Biodegradation of soil-derived dissolved organic matter as related to its properties (2003) Geoderma, 113, pp. 273-291
  • Kawahigashi, M., Kaiser, K., Rodionov, A., Guggenberger, G., Sorption of dissolved organic matter by mineral soils of the Siberian forest tundra (2006) Global Change Biology, 12, pp. 1868-1877
  • Kjeldsen, P., Morton, A., Barlaz, A., Rooker, P., Baun, A., Ledin, A., Christensen, T.H., Present and Long-Term Composition of MSW Landfill Leachate: A Review (2002) Critical Reviews in Environmental Science & Technology, 32 (4), pp. 297-336
  • Lomond, J.S., Tong, A.Z., Rapid Analysis of Dissolved Methane, Ethylene, Acetylene and Ethane using Partition Coefficients and Headspace-Gas Chromatography (2011) Journal of Chromatographic Science, 49, pp. 469-475
  • MacCrea, J.M., On the isotopic chemistry of carbonates and paleotemperature scale (1950) Journal of Chemical Physics, UME18 (6), pp. 849-857
  • McLean, J.E., Bledsoe, B.E., (1992) Behavior of Metals in Soils, , Technology Innovation Office, Office of Solid Waste and Emergency Response, 1992 - Hazardous waste sites - EPA/540/S-92/018, 25 pages
  • Mook, W.G., Natural abundance of the stable isotopes of C, O and H (2000) Environmental Isotopes in the Hydrological Cycle, pp. 89-120. , W. G Mook, (Ed.) Principles and applications Paris: UNESCO
  • Nicolli, H.B., Bundschuh, J., Blanco, M.C., Tujhneider, O.F., Panarello, H.O., Dapeña, C., Rusanski, J.E., Arsenic and associated trace-elements in groundwater from the Chaco-Pampean plain, Argentina, Results from 100 years of research (2012) Science of the total Environment, 429, pp. 36-56
  • North, J.C., Frew, R.D., Peake, B.M., The use of carbon and nitrogen isotope ratios to identify landfill leachate contamination: Green Island Landfill (2004) Environment International, 30 (5), pp. 631-637. , Dunedin, New Zealand
  • Ogundiran, O.O., Afolabi, T.A., Assessment of the physicochemical parameters and heavy metals toxicity of leachates from municipal solid waste open dumpsite (2008) International Journal of Environmental Science & Technology, 5 (2), pp. 243-250
  • Panarello, H.O., Garcia, C.M., Valencia, S.A., Linares, E., (1982) Determinación de la Composición Isotópica del Carbono en Carbonatos, su Utilización en Hidrogeología y Geología, 35 (4), pp. 460-466. , Revista de la Asociación Geológica Argentina
  • Plummer, L.N., Prestemon, E.C., Parkhurst, D.L., An interactive code (NETPATH) for modeling NET geochemical reactions along a flow PATH (1991) U.S. Geological Survey Water-Resources Investigations Report, p. 227
  • Plummer, L.N., Prestemon, E.C., Parkhurst, D.L., An interactive code NETPATH for modeling NET geochemical reactions along a flow PATH (1994) U.S. Geological Survey Water-Resources Investigations Report, p. 130
  • Qualls, R.G., Haines, B.L., Biodegradability of dissolved organic matter in forest through fall, soil solution, and stream water (1992) Soil Science Society of America Journal, 56, pp. 578-586
  • Richter, M., Wistinghausen, E., Unterscheidbarkeit von humusfraktione in boden bei unterscheidlicher bewirtschaftung (1981) Z. Pflanz. Bodenkunde, 144, pp. 395-406
  • Sanci, R., Panarello, H.O., Ostera, H., CO2 emissions from a municipal site for final disposal of solid waste in Gualeguaychú (2012) Environmental Earth Science, 66, pp. 519-528. , Entre Rios Province, Argentina
  • Staff Soil Survey (2014) Keys to Soil Taxonomy, , 12th ed. USDA-Natural Resources Conservation Service, Washington, DC
  • Stumm, W., Morgan, J.J., Chemical Equilibria and Rates in Natural Waters (1996) Aquatic Chemistry, pp. 764-768. , In John Wiley & Sons (Ed. ) New York
  • Valencio, S., Ostera, H., Panarello, H., Monitoring13C in CO2 soil gas from a landfill: First results from a case study (2003) IV South American Symposium on Isotope Geology, pp. 128-130. , Salvador, Brasil
  • Van Breukelen, B.M., Roling, F.M., Groen, J., Griffioen, J., Van Verseveld, H.W., Biogechemestry and isotope geochemistry of a landfill leachate plume (2003) Journal of Contamination of Hydrology, 65, pp. 245-268

Citas:

---------- APA ----------
Sanci, R., Panarello, H.O. & Cravero, F. (2016) . Hydrogeochemistry and stable isotopes of a solid waste disposal area from gualeguaychú, entreríos, Argentina. Journal of Solid Waste Technology and Management, 42(2), 71-86.
http://dx.doi.org/10.5276/JSWTM.2016.71
---------- CHICAGO ----------
Sanci, R., Panarello, H.O., Cravero, F. "Hydrogeochemistry and stable isotopes of a solid waste disposal area from gualeguaychú, entreríos, Argentina" . Journal of Solid Waste Technology and Management 42, no. 2 (2016) : 71-86.
http://dx.doi.org/10.5276/JSWTM.2016.71
---------- MLA ----------
Sanci, R., Panarello, H.O., Cravero, F. "Hydrogeochemistry and stable isotopes of a solid waste disposal area from gualeguaychú, entreríos, Argentina" . Journal of Solid Waste Technology and Management, vol. 42, no. 2, 2016, pp. 71-86.
http://dx.doi.org/10.5276/JSWTM.2016.71
---------- VANCOUVER ----------
Sanci, R., Panarello, H.O., Cravero, F. Hydrogeochemistry and stable isotopes of a solid waste disposal area from gualeguaychú, entreríos, Argentina. J Solid Waste Technol Manage. 2016;42(2):71-86.
http://dx.doi.org/10.5276/JSWTM.2016.71