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Yerba mate (YM) is massively produced and consumed as an infusion in South America and spreading all over the world. This product is obtained from dried leaves of Ilex paraguariensis Saint Hilaire, mixed with fragments of dried branches (sticks). For its commercialization, YM must have a minimum percentage of leaves because its presence determines YM quality and price. Till today, a mechanical methodology to determine the relative amount of components (sticks, leaves, and powder) is used. There is not any modern analytical method that provides information for quick characterization of the YM components. Typical saponin fingerprints for leaves and sticks were found by using ultraviolet matrix-assisted laser desorption ionization and ultraviolet laser desorption ionization mass spectrometry. Then, their possible application as useful tools for quick characterization of components of commercial YM (leaves and sticks) is presented. Furthermore, fingerprints obtained from authentic samples of Ilex paraguariensis and Ilex dumosa are also included and discussed. Each Ilex show typical saponin fingerprints for leaves and sticks. © 2018 John Wiley & Sons, Ltd.


Documento: Artículo
Título:MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
Autor:Petroselli, G.; Parapugna, T.L.; Lagorio, M.G.; Erra-Balsells, R.
Filiación:Facultad de Ciencias Exactas y Naturales. Departamento de Química Orgánica, Universidad de Buenos Aires, Buenos Aires, Argentina
Facultad de Ciencias Exactas y Naturales Pabellón II, CONICET, Universidad de Buenos Aires. Centro de Investigación en Hidratos de Carbono (CIHIDECAR), Buenos Aires, Argentina
Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Buenos Aires, Argentina
Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Ilex dumosa; Ilex paraguariensis Saint Hilaire; LDI-MS; MALDI-MS; matesaponin fingerprint; Desorption; Ionization; Mass spectrometry; Ultraviolet lasers; Ilex dumosa; Ilex paraguariensis; LDI-MS; MALDI-MS; matesaponin fingerprint; Metabolites; saponin derivative; Article; electrospray mass spectrometry; fast atom bombardment mass spectrometry; Ilex paraguariensis; isomer; isomerism; laser desorption ionization mass spectrometry; matrix-assisted laser desorption-ionization mass spectrometry; molecular weight; nuclear magnetic resonance spectroscopy; plant leaf; plant stick; plant structures; plant tissue; principal component analysis; priority journal; ultra performance liquid chromatography; ultraviolet radiation
Página de inicio:195
Página de fin:203
Título revista:Journal of Mass Spectrometry
Título revista abreviado:J. Mass Spectrom.


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---------- APA ----------
Petroselli, G., Parapugna, T.L., Lagorio, M.G. & Erra-Balsells, R. (2019) . MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis). Journal of Mass Spectrometry, 54(2), 195-203.
---------- CHICAGO ----------
Petroselli, G., Parapugna, T.L., Lagorio, M.G., Erra-Balsells, R. "MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)" . Journal of Mass Spectrometry 54, no. 2 (2019) : 195-203.
---------- MLA ----------
Petroselli, G., Parapugna, T.L., Lagorio, M.G., Erra-Balsells, R. "MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)" . Journal of Mass Spectrometry, vol. 54, no. 2, 2019, pp. 195-203.
---------- VANCOUVER ----------
Petroselli, G., Parapugna, T.L., Lagorio, M.G., Erra-Balsells, R. MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis). J. Mass Spectrom. 2019;54(2):195-203.