Artículo

Petroselli, G.; Mandal, M.K.; Chen, L.C.; Ruiz, G.T.; Wolcan, E.; Hiraoka, K.; Nonami, H.; Erra-Balsells, R. "Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS" (2012) Journal of Mass Spectrometry. 47(3):313-321
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Abstract:

A group of rhenium (I) complexes including in their structure ligands such as CF 3SO 3-, CH 3CO 2-, CO, 2,2′-bipyridine, dipyridil[3,2-a:2′3′-c]phenazine, naphthalene-2-carboxylate, anthracene-9-carboxylate, pyrene-1-carboxylate and 1,10-phenanthroline have been studied for the first time by mass spectrometry. The probe electrospray ionization (PESI) is a technique based on electrospray ionization (ESI) that generates electrospray from the tip of a solid metal needle. In this work, mass spectra for organometallic complexes obtained by PESI were compared with those obtained by classical ESI and high flow rate electrospray ionization assisted by corona discharge (HF-ESI-CD), an ideal method to avoid decomposition of the complexes and to induce their oxidation to yield intact molecular cation radicals in gas state [M] +. and to produce their reduction yielding the gas species [M] -.. It was found that both techniques showed in general the intact molecular ions of the organometallics studied and provided additional structure characteristic diagnostic fragments. As the rhenium complexes studied in the present work showed strong absorption in the UV-visible region, particularly at 355nm, laser desorption ionization (LDI) mass spectrometry experiments could be conducted. Although intact molecular ions could be detected in a few cases, LDI mass spectra showed diagnostic fragments for characterization of the complexes structure. Furthermore, matrix-assisted laser desorption ionization (MALDI) mass spectra were obtained. Nor-harmane, a compound with basic character, was used as matrix, and the intact molecular ions were detected in two examples, in negative ion mode as the [M] -. species. Results obtained with 2-[(2E)-3-(4-tert-buthylphenyl)-2-methylprop-2-enylidene] malononitrile (DCTB) as matrix are also described. LDI experiments provided more information about the rhenium complex structures than did the MALDI ones. © 2012 John Wiley & Sons, Ltd.

Registro:

Documento: Artículo
Título:Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS
Autor:Petroselli, G.; Mandal, M.K.; Chen, L.C.; Ruiz, G.T.; Wolcan, E.; Hiraoka, K.; Nonami, H.; Erra-Balsells, R.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellõn II, 3er P., 1428 Buenos Aires, Argentina
Clean Energy Research Center, University of Yamanashi Yamanashi, 4-3-11 Takeda, Kofu 400-8511, Japan
Instituto de Investigaciones Fisicoquímicas Teõricas y Aplicadas (INIFTA, UNLP, CCT la Plata-CONICET), Diag. 113 y 64, B1906ZAA La Plata, Argentina
Plant Biophysics/Biochemistry Research Laboratory, Faculty of Agriculture, Ehime University, Matsuyama 790-8566, Japan
Palabras clave:acetoxy rhenium complex; arylcarboxy rhenium complex; DCTB; high flow rate electrospray corona discharge; nor-harmane; polypyridil rhenium complex; trifluoromethanesulfoxy rhenium complex; arylcarboxy rhenium complex; DCTB; High-flow rate; nor-harmane; polypyridil rhenium complex; Rhenium complexes; trifluoromethanesulfoxy rhenium complex; Carbon dioxide; Carboxylation; Electric corona; Electrospray ionization; Experiments; Flow rate; Ion sources; Ionization of gases; Mass spectrometers; Mass spectrometry; Naphthalene; Organometallics; Rhenium; Rhenium compounds; organometallic compound; rhenium complex; article; chemical structure; comparative study; electrospray mass spectrometry; flow rate; human; intermethod comparison; mass spectrometry; matrix assisted laser desorption ionization time of flight mass spectrometry; oxidation; priority journal; probe electrospray ionization; radiation absorption; ultraviolet radiation; Organometallic Compounds; Rhenium; Spectrometry, Mass, Electrospray Ionization; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
Año:2012
Volumen:47
Número:3
Página de inicio:313
Página de fin:321
DOI: http://dx.doi.org/10.1002/jms.2965
Título revista:Journal of Mass Spectrometry
Título revista abreviado:J. Mass Spectrom.
ISSN:10765174
CODEN:JMSPF
CAS:Organometallic Compounds; Rhenium, 7440-15-5
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10765174_v47_n3_p313_Petroselli

Referencias:

  • Fox, M.A., Chanon, M., (1988) Photoinduced Electron Transfer, , Elsevier, Amsterdam
  • Balzani, V., Bolletta, F., Gandolfi, M., Maestri, M., Bimolecular electron transfer reactions of the excited states of transition metal complexes (1978) Organic Chemistry and Theory, 75, pp. 1-64. , Springer: Berlin / Heidelberg
  • Grätzel, M., (1983) Energy Resources Through Photochemistry and Catalysis, , Academic Press: New York
  • Kalyanasundaram, K., Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues (1982) Coord. Chem. Rev., 46, p. 159
  • Kalyanasundaram, K., Grätzel, M., (1993) Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds, , Kluwer Academic Publishers: Dordrecht
  • Sacksteder, L., Lee, M., Demas, J.N., Degraff, B.A., Long-lived, highly luminescent rhenium(I) complexes as molecular probes: Intra- and intermolecular excited-state interactions (1993) J. Am. Chem. Soc., 115, p. 8230
  • Yam, V.W.-W., Wong, K.M.-C., Lee, V.W.-M., Lo, K.K.-W., Cheung, K.-K., Synthesis, photophysics, ion-binding studies, and structural characterization of organometallic rhenium(I) crown complexes (1995) Organometallics, 14, p. 4034
  • Yoon, D.I., Berg-Brennan, C.A., Lu, H., Hupp, J.T., Synthesis and preliminary photophysical studies of intramolecular electron transfer in crown-linked donor-(chromophore-) acceptor complexes (1992) Inorg. Chem., 31, p. 3192
  • Calabrese, J.C., Tam, W., Organometallics for non-linear optics: Metal-pyridine and bipyridine complexes (1987) Chem Phys. Lett., 133, p. 244
  • Ehler, T.T., Malmberg, N., Carron, K., Sullivan, B.P., Noe, L.J., Studies of organometallic self-assembled monolayers on Ag and Au using surface plasmon spectroscopy (1997) J. Phys. Chem. B, 101, p. 3174
  • Yam, V.W.-W., Lau, V.C.-Y., Cheung, K.-K., Synthesis, photophysics and photochemistry of novel luminescent rhenium(I) photoswitchable materials (1995) J. Chem. Soc., Chem. Commun., 2, p. 259
  • Higgins, B., Degraff, B.A., Demas, J.N., Luminescent transition metal complexes as sensors: Structural effects on pH response (2005) Inorg. Chem., 44, p. 6662
  • Biver, T., Secco, F., Venturini, M., Mechanistic aspects of the interaction of intercalating metal complexes with nucleic acids (2008) Coord. Chem. Rev., 252, p. 1163
  • Ruiz, G.T., Juliarena, M.P., Lezna, R.O., Wolcan, E., Feliz, M.R., Ferraudi, G., Intercalation of fac-[(4,4′-bpy)ReI(CO) 3(dppz)]+, dppz=dipyridyl[3,2-a:2′3′-c] phenazine, in polynucleotides. on the UV-vis photophysics of the Re(I) intercalator and the redox reactions with pulse radiolysis-generated radicals (2007) Dalton Trans., 20, p. 2020
  • Henderson, W., McIndoe, J.S., (2005) Mass Spectrometry of Inorganic, Coordination and Organometallic Compounds: Tools - Techniques - Tips, , Wiley: Wiltshire
  • Wyatt, M.F., MALDI-TOFMS analysis of coordination and organometallic complexes: A nic(h)e area to work in (2011) J. Mass Spectrom., 46, p. 712
  • Wyatt, M.F., Stein, B.K., Brenton, A.G., Characterization of various analytes using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and 2-[(2E)-3-(4-tert- butylphenyl) -2-methylprop-2-enylidene] malononitrile matrix (2006) Anal. Chem., 78, p. 199
  • Henderson, W., Nicholson, B.K., McCaffey, L.J., Applications of electrospray mass spectrometry in organometallic chemistry (1998) Polyhedron, 17, p. 4291
  • Traeger, J.C., Electrospray mass spectrometry of organometallic compounds (2000) Int'l J. Mass Spectrom., 200, p. 387
  • Hori, H., Ishihara, J., Koile, K., Takeuchi, K., Ibusuki, T., Ishitani, O., Electrospray mass spectrometric detection of neutral rhenium bipyridine complexes using NaNO 3 as an ionization agent (1997) Chem. Lett., 3, p. 273
  • Van Berkel, G.J., Mc Luckey, S.A., Glish, G.L., Electrochemical origin of radical cations observed in electrospray ionization mass spectra (1992) Anal. Chem., 64, p. 1586
  • Hop, C.E.C.A., Saulys, D.A., Gaines, D.F., Electrospray mass spectrometry of borane salts: The electrospray needle as an electrochemical cell (1995) J. Am. Soc. Mass Spectrom., 6, p. 860
  • Van Berkel, G.J., Zhou, F., Electrospray as a controlled-current electrolytic cell: Electrochemical ionization of neutral analytes for detection by electrospray mass spectrometry (1995) Anal. Chem., 67, p. 3958
  • Hop, C.E.C.A., Brady, J.T., Bakhtiar, R., Transformation of neutral rhenium compounds during electrospray ionization mass spectrometry (1997) J. Am. Soc. Mass Spectrom., 8, p. 191
  • Hiraoka, K., Nishidate, K., Mori, K., Asakawa, D., Suzuki, S., Development of probe electrospray using a solid needle (2007) Rapid Commun. Mass Spectrom., 21, p. 3139
  • Chen, L.C., Nishidate, K., Saito, Y., Mori, K., Asakawa, D., Takeda, S., Kubota, T., Hiraoka, K., Application of probe electrospray to direct ambient analysis of biological samples (2008) Rapid Commun. Mass Spectrom., 22, p. 2366
  • Chen, L.C., Nishidate, K., Saito, Y., Mori, K., Asakawa, D., Takeda, S., Kubota, T., Hiraoka, K., Characteristics of probe electrospray generated from a solid needle (2008) J. Phys. Chem. B, 112, p. 11164
  • Zhan, Y., Chen, L.C., Suzuki, H., Ariyada, O., Erra-Balsells, R., Nonami, H., Hiraoka, K., Direct profiling of phytochemicals in tulip tissues and in vivo monitoring of the change of carbohydrate content in tulip bulbs by probe electrospray ionization mass spectrometry (2009) J. Am. Soc. Mass Spectrom., 20, p. 2304
  • Wolcan, E., Torchia, G., Tocho, J., Piro, O.E., Juliarena, P., Ruiz, G., Féliz, M.R., Photoinduced charge separation in R-CO 2-Re(CO) 3(2,2′-bipyridine) complexes. Two emitting charge transfer excited states (2002) J. Chem. Soc. Dalton Trans., 10, p. 2194
  • Wolcan, E., Ferraudi, G., Photochemical and photophysical properties of Fac-Re(I) tricarbonyl complexes: A comparison of monomer and polymer species with - Re(I) (CO) 3phen chromophores (2000) J. Phys. Chem. A, 104, p. 9281
  • Juliarena, M.P., Ruiz, G.T., Wolcan, E., Lezna, R.O., Féliz, M.R., Ferraudi, G., Inhibition of the fac-(RCO 2)Re(I) (CO) 3(bis-azine) photodecarboxylation of the carboxylate ligand, RCO 2 -, when R is a strongly electron donating group: Thermal and photochemical properties of complexes where R=ferrocene, 4-(dimethylamino)benzyl (2007) Organometallics, 26, p. 272
  • Chen, L.C., Yoshimura, K., Yu, Z., Iwata, R., Ito, H., Suzuki, H., Mori, K., Hiraoka, K., Ambient imaging mass spectrometry by electrospray ionization using solid needle as sampling probe (2009) J. Mass Spectrom., 44, p. 1469
  • Nonami, H., Fukui, S., R Erra-Balsells. β-Carboline alkaloids as matrices for matrix-assisted Ultraviolet Laser Desorption Time-of flight Mass Spectrometry of proteins and sulfated oligosaccharides: A comparative study using phenylcarbonyl compounds, carbazoles and classical matrices (1997) J. Mass Spectrom., 32, p. 287

Citas:

---------- APA ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Ruiz, G.T., Wolcan, E., Hiraoka, K., Nonami, H.,..., Erra-Balsells, R. (2012) . Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS. Journal of Mass Spectrometry, 47(3), 313-321.
http://dx.doi.org/10.1002/jms.2965
---------- CHICAGO ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Ruiz, G.T., Wolcan, E., Hiraoka, K., et al. "Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS" . Journal of Mass Spectrometry 47, no. 3 (2012) : 313-321.
http://dx.doi.org/10.1002/jms.2965
---------- MLA ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Ruiz, G.T., Wolcan, E., Hiraoka, K., et al. "Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS" . Journal of Mass Spectrometry, vol. 47, no. 3, 2012, pp. 313-321.
http://dx.doi.org/10.1002/jms.2965
---------- VANCOUVER ----------
Petroselli, G., Mandal, M.K., Chen, L.C., Ruiz, G.T., Wolcan, E., Hiraoka, K., et al. Mass spectrometry of rhenium complexes: A comparative study by using LDI-MS, MALDI-MS, PESI-MS and ESI-MS. J. Mass Spectrom. 2012;47(3):313-321.
http://dx.doi.org/10.1002/jms.2965