Abstract:
We report the crystal structures of two novel coordination compounds with similar complex composition: [Cd(Ac)2(Bzimpy)] (I) and [Zn(Ac) 2(Bzimpy)]·H2O (II). Both compounds are monomeric. Compound I consists of a Cd(II) center heptacoordinated with three N atoms from a Bzimpy molecule and four O atoms from two bidentate acetato molecules. Compound II consists of a Zn(II) center pentacoordinated with three N atoms from a Bzimpy molecule and two O atoms from two monodentate acetato molecules. A non-coordinated water molecule completes the formula. In addition, we highlight some common features in the supramolecular assembly of both compounds and with similar structures deposited in the version 5.33 of the CSD. This assembly occur through H-bridges and π-π offset stacked interactions, giving rise to the formation of what we call "directed ring" of two types: two molecular components 2Rd and three molecular components 3Rd. Structures are viewed as composed of well defined substructures in order to analyze them. © 2013 Springer Science+Business Media New York.
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Documento: |
Artículo
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Título: | A recurrent motive in the supramolecular assembly of coordination compounds with 2,6-bis(benzimidazol-2-yl)piridine (Bzimpy) and two identical H-bond acceptor Co-ligands: [Cd(Ac)2(Bzimpy)], [Zn(Ac)2(Bzimpy)] ·H2O (Ac:Acetato) and related compounds |
Autor: | Harvey, M.A.; Baggio, S.; Suárez, S.A.; Doctorovich, F. |
Filiación: | Universidad Nacional de la Patagonia S.J.B., Centro Nacional Patagónico, CONICET, Bvd. Alte. Brown 3700, (9120) Puerto Madryn, Chubut, Argentina DQIAyQF/INQUIMAE-CONICET, FCEN, Ciudad Universitaria, Pab. II, Piso 3, C1428EHA Buenos Aires, Argentina
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Palabras clave: | 2,6-bis(benzimidazol-2-yl)pyridine coordination compounds; Supramolecular architecture; Supramolecular synthons |
Año: | 2013
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Volumen: | 43
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Número: | 5
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Página de inicio: | 275
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Página de fin: | 281
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DOI: |
http://dx.doi.org/10.1007/s10870-013-0415-0 |
Título revista: | Journal of Chemical Crystallography
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Título revista abreviado: | J. Chem. Crystallogr.
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ISSN: | 10741542
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CODEN: | JCCYE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10741542_v43_n5_p275_Harvey |
Referencias:
- Bocǎ, M., Jameson, R.F., Linert, W., (2011) Coordin Chem Rev, 255, p. 290. , 10.1016/j.ccr.2010.09.010
- Allen, F.H., (2002) Acta Cryst, 58, p. 380. , 1:CAS:528:DC%2BD38XktVOqu74%3D
- Sheldrick, G.M., (2008) Acta Cryst, 64, p. 112
- Macrae, C.F., Edgington, P.R., McCabe, P., Pidcock, E., Shields, G.P., Taylor, R., Towler, M., Van De Streek, J., Mercury: Visualization and analysis of crystal structures (2006) Journal of Applied Crystallography, 39 (3), pp. 453-457. , DOI 10.1107/S002188980600731X
- Harvey, M.A., Baggio, S., Baggio, R., (2006) Acta Cryst, 62, p. 1038
- Brown, I.D., Bond-length-bond-valence relationships in inorganic solids (1994) Structure Correlation, pp. 405-429. , H-B Bürgi J.D. Dunitz (eds) 2 VCH, Weinheim New York 10.1002/9783527616091.ch10
- Sony, S.M.M., Ponnuswamy, M.N., Nature of π-interactions in nitrogen-containing heterocyclic systems: A structural database analysis (2006) Crystal Growth and Design, 6 (3), pp. 736-742. , DOI 10.1021/cg050514f
- Yang, Y., Zeng, M.H., Zhang, S.H., Liang, H., (2007) Wuji Huaxue Xuebao (Chin) (Chin JInorg Chem), 23, p. 1435. , 1:CAS:528:DC%2BD2sXhtVehtbvJ
- Yang, Y., Zeng, M.-H., Zhang, L.-J., Liang, H., (2008) Jiegou Huaxue (Chin J Struct Chem), 27, p. 749. , 1:CAS:528:DC%2BD1cXotlynsbw%3D
- Yang, Y., Zeng, M.-H., Zhang, S.-H., Liang, H., (2007) Chin J Chem, 26, p. 1121. , 10.1002/cjoc.200790209
- Bernardinelli, G., Hopfgartner, G., Williams, A.F., (1990) Acta Cryst, 46, p. 1642. , 1:CAS:528:DyaK3cXmt1Wrsbo%3D
- Cariou, R., Chirinos, J.J., Gibson, V.C., Jacobsen, G., Tomov, A.K., Britovsek, G.J.P., White, A.J.P., (2010) Dalton Trans, 39, p. 9039. , 10.1039/c0dt00402b 1:CAS:528:DC%2BC3cXhtFygur7E
- Liu, S.-G., Zuo, J.-L., Li, Y.-Z., You, X.-Z., Syntheses, crystal structures of blue luminescent complexes based on 2,6-bis(benzimidazolyl) pyridine (2004) Journal of Molecular Structure, 705 (1-3), pp. 153-157. , DOI 10.1016/j.molstruc.2004.07.006, PII S0022286004005253
- Liu, S.-G., Zuo, J.-L., Wang, Y., Li, Y.-Z., You, X.-Z., Synthesis, crystal structure and blue electroluminescence of a new zinc complex based on 2,6-bis(benzimidazolyl)pyridine (2005) Journal of Physics and Chemistry of Solids, 66 (5), pp. 735-740. , DOI 10.1016/j.jpcs.2004.10.004, PII S0022369704003762
- Wang, S., Zhu, Y., Zhang, F., Wang, Q., Wang, L., (1992) Polyhedron, 11, p. 1909. , 10.1016/S0277-5387(00)83739-0 1:CAS:528:DyaK38Xms1emt7Y%3D
- Liu, X.-M., Mu, X.-Y., Xia, H., Su, Q., Ye, L., Chen, C., Gao, W., Mu, Y., (2007) Chem Res Chin Univ, 23, p. 159. , 10.1016/S1005-9040(07)60033-6
- Harvey, M.A., Baggio, S., Garland, M.T., Baggio, R., X-ray study of two new cadmium acetato complexes (2005) Journal of Coordination Chemistry, 58 (3), pp. 243-253. , DOI 10.1080/00958970512331334232
- Hu, J., Zhang, J., Zhang, W., Zhang, C., (2011) Acta Cryst, 67, p. 61
Citas:
---------- APA ----------
Harvey, M.A., Baggio, S., Suárez, S.A. & Doctorovich, F.
(2013)
. A recurrent motive in the supramolecular assembly of coordination compounds with 2,6-bis(benzimidazol-2-yl)piridine (Bzimpy) and two identical H-bond acceptor Co-ligands: [Cd(Ac)2(Bzimpy)], [Zn(Ac)2(Bzimpy)] ·H2O (Ac:Acetato) and related compounds. Journal of Chemical Crystallography, 43(5), 275-281.
http://dx.doi.org/10.1007/s10870-013-0415-0---------- CHICAGO ----------
Harvey, M.A., Baggio, S., Suárez, S.A., Doctorovich, F.
"A recurrent motive in the supramolecular assembly of coordination compounds with 2,6-bis(benzimidazol-2-yl)piridine (Bzimpy) and two identical H-bond acceptor Co-ligands: [Cd(Ac)2(Bzimpy)], [Zn(Ac)2(Bzimpy)] ·H2O (Ac:Acetato) and related compounds"
. Journal of Chemical Crystallography 43, no. 5
(2013) : 275-281.
http://dx.doi.org/10.1007/s10870-013-0415-0---------- MLA ----------
Harvey, M.A., Baggio, S., Suárez, S.A., Doctorovich, F.
"A recurrent motive in the supramolecular assembly of coordination compounds with 2,6-bis(benzimidazol-2-yl)piridine (Bzimpy) and two identical H-bond acceptor Co-ligands: [Cd(Ac)2(Bzimpy)], [Zn(Ac)2(Bzimpy)] ·H2O (Ac:Acetato) and related compounds"
. Journal of Chemical Crystallography, vol. 43, no. 5, 2013, pp. 275-281.
http://dx.doi.org/10.1007/s10870-013-0415-0---------- VANCOUVER ----------
Harvey, M.A., Baggio, S., Suárez, S.A., Doctorovich, F. A recurrent motive in the supramolecular assembly of coordination compounds with 2,6-bis(benzimidazol-2-yl)piridine (Bzimpy) and two identical H-bond acceptor Co-ligands: [Cd(Ac)2(Bzimpy)], [Zn(Ac)2(Bzimpy)] ·H2O (Ac:Acetato) and related compounds. J. Chem. Crystallogr. 2013;43(5):275-281.
http://dx.doi.org/10.1007/s10870-013-0415-0