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Cazut, S.A.I.; Ramírez Maisuls, E.H.; Delfino, M.R.; Romero, J.M.; Jorge, N.L.; Castro, E.A. "Thermal decomposition of formaldehyde diperoxide in aqueous solution" (2009) Russian Journal of General Chemistry. 79(10):2187-2190
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Abstract:

Thermal decomposition of formaldehyde diperoxide (1,2,4,5-tetraoxane) in aqueous solution with an initial concentration of 6.22 × 10-3 M was studied in the temperatures range from 403 to 439 K. The reaction was found to follow first-order kinetic law, and formaldehyde was the major decomposition product. The activation parameters of the initial step of the reaction (ΔH ≠ = 15.25 ± 0.5 kcal mol-1, ΔS ≠ =-47.78 ± 0.4 cal mol-1K-1, E a = 16.09 ± 0.5 kcal mol-1) support a mechanism involving homolytic rupture of one peroxide bond in the 1,2,4,5-tetraoxane molecule with participation of the solvent and formation of a diradical intermediate. © 2009 Pleiades Publishing, Ltd.

Registro:

Documento: Artículo
Título:Thermal decomposition of formaldehyde diperoxide in aqueous solution
Autor:Cazut, S.A.I.; Ramírez Maisuls, E.H.; Delfino, M.R.; Romero, J.M.; Jorge, N.L.; Castro, E.A.
Filiación:Área Fisicoquímica, Facultad de Ciencias Exactas y Naturales y Agrimensura, Campus Universitario, Av. Libertad 5400, Corrientes 3400, Argentina
INIFTA, División Química Teórica, Facultad de Ciencias Exactas, Diagonal 113 y 64, Suc. 4, C.C. 16, La Plata, Buenos Aires 1900, Argentina
Idioma: Inglés
Año:2009
Volumen:79
Número:10
Página de inicio:2187
Página de fin:2190
DOI: http://dx.doi.org/10.1134/S107036320910017X
Título revista:Russian Journal of General Chemistry
Título revista abreviado:Russ. J. Gen. Chem.
ISSN:10703632
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10703632_v79_n10_p2187_Cazut

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Citas:

---------- APA ----------
Cazut, S.A.I., Ramírez Maisuls, E.H., Delfino, M.R., Romero, J.M., Jorge, N.L. & Castro, E.A. (2009) . Thermal decomposition of formaldehyde diperoxide in aqueous solution. Russian Journal of General Chemistry, 79(10), 2187-2190.
http://dx.doi.org/10.1134/S107036320910017X
---------- CHICAGO ----------
Cazut, S.A.I., Ramírez Maisuls, E.H., Delfino, M.R., Romero, J.M., Jorge, N.L., Castro, E.A. "Thermal decomposition of formaldehyde diperoxide in aqueous solution" . Russian Journal of General Chemistry 79, no. 10 (2009) : 2187-2190.
http://dx.doi.org/10.1134/S107036320910017X
---------- MLA ----------
Cazut, S.A.I., Ramírez Maisuls, E.H., Delfino, M.R., Romero, J.M., Jorge, N.L., Castro, E.A. "Thermal decomposition of formaldehyde diperoxide in aqueous solution" . Russian Journal of General Chemistry, vol. 79, no. 10, 2009, pp. 2187-2190.
http://dx.doi.org/10.1134/S107036320910017X
---------- VANCOUVER ----------
Cazut, S.A.I., Ramírez Maisuls, E.H., Delfino, M.R., Romero, J.M., Jorge, N.L., Castro, E.A. Thermal decomposition of formaldehyde diperoxide in aqueous solution. Russ. J. Gen. Chem. 2009;79(10):2187-2190.
http://dx.doi.org/10.1134/S107036320910017X