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Abstract:

The electron impact induced fragmentations observed in the mass spectra of eight 1,4‐diene‐3‐ketopregnane steroids are described. The effect of hydroxyl substituents in positions 11β, 17α and 21, on the typical fragmentation pattern is analysed; in particular the ‘long range’ effect of the 17α‐hydroxy group on the relative abundance of the ions m/z 121 and 122 is confirmed using specific deuterium labelling. Copyright © 1985 John Wiley & Sons, Ltd.

Registro:

Documento: Artículo
Título:Electron impact induced fragmentations of the 1,4‐diene analogues of steroid hormones and related steroids
Autor:Gonzalez, M.D.; Burton, G.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Umymfor, Conicet, Fcen, Argentina
Conicet, Fcen, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1428, Argentina
Palabras clave:steroid; mass spectrometry; methodology; nonhuman; pregna 1,4 diene 3,20 dione derivative; Deuterium; Magnetic Resonance Spectroscopy; Mass Fragmentography; Pregnadienes; Pregnenediones; Support, Non-U.S. Gov't
Año:1985
Volumen:12
Número:8
Página de inicio:405
Página de fin:408
DOI: http://dx.doi.org/10.1002/bms.1200120809
Título revista:Biological Mass Spectrometry
Título revista abreviado:Biol. Mass Spectrom.
ISSN:10529306
CAS:Deuterium, 7782-39-0; Pregnadienes; Pregnenediones
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10529306_v12_n8_p405_Gonzalez

Referencias:

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Citas:

---------- APA ----------
Gonzalez, M.D. & Burton, G. (1985) . Electron impact induced fragmentations of the 1,4‐diene analogues of steroid hormones and related steroids. Biological Mass Spectrometry, 12(8), 405-408.
http://dx.doi.org/10.1002/bms.1200120809
---------- CHICAGO ----------
Gonzalez, M.D., Burton, G. "Electron impact induced fragmentations of the 1,4‐diene analogues of steroid hormones and related steroids" . Biological Mass Spectrometry 12, no. 8 (1985) : 405-408.
http://dx.doi.org/10.1002/bms.1200120809
---------- MLA ----------
Gonzalez, M.D., Burton, G. "Electron impact induced fragmentations of the 1,4‐diene analogues of steroid hormones and related steroids" . Biological Mass Spectrometry, vol. 12, no. 8, 1985, pp. 405-408.
http://dx.doi.org/10.1002/bms.1200120809
---------- VANCOUVER ----------
Gonzalez, M.D., Burton, G. Electron impact induced fragmentations of the 1,4‐diene analogues of steroid hormones and related steroids. Biol. Mass Spectrom. 1985;12(8):405-408.
http://dx.doi.org/10.1002/bms.1200120809