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Abstract:

The aim of this study was to evaluate polycyclic aromatic hydrocarbons (PAHs) contamination, distribution, and toxicity in “yerba mate” fractions, and to propose actions to reduce its pollution. Sixteen PAHs were quantified using a recently developed methodology by HPLC-DAD/FLD, obtaining recoveries higher than 84.5% and relative standard deviation of individual compounds from 0.2% to 9.6%. The PAHs distribution was not normal. The Inverse Gaussian, Birnbaum-Saunders, Lognormal, Gamma, and Weibull were the models that best described benzo(a)pyrene and PAH4 distribution. The fraction that was significantly less contaminated was stem. Also, there was significant difference between leaf and powder fractions, the latter being the one that presented higher PAHs concentration. This may be due to the products generated in the pyrolysis of wood, used in the drying process of “yerba mate.” If powder were removed, a reduction of ∼3.5% of ∑PAHs and 6.5% of TEQ would be achieved. Although eliminating powder could be a strategy to reduce PAHs contamination, this would not be enough to diminish PAHs levels below the regulatory limits. © 2018, © 2018 Taylor & Francis Group, LLC.

Registro:

Documento: Artículo
Título:Polycyclic Aromatic Hydrocarbons (PAHs) in “Yerba Mate” (Ilex paraguariensis) Fractions
Autor:García Londoño, V.A.; Pok, P.S.; Resnik, S.
Filiación:Departamentos de Química Orgánica e Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Autónoma de Buenos Aires, Argentina
Fundación de Investigaciones Científicas Teresa Benedictina de la Cruz, Luján, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas de la República Argentina, Ciudad Autónoma de Buenos Aires, Argentina
Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, La Plata, Argentina
Palabras clave:Benzopyrene; Ilex paraguariensis; organic contaminants; PAH; polycyclic aromatic hydrocarbons; “yerba mate”
Año:2018
DOI: http://dx.doi.org/10.1080/10406638.2018.1553193
Título revista:Polycyclic Aromatic Compounds
Título revista abreviado:Polycyclic Aromat. Compd.
ISSN:10406638
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10406638_v_n_p_GarciaLondono

Referencias:

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  • Gomes, Stir bar Sorptive Extraction and High-Performance Liquid Chromatography, pp. 2-10
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  • Whitaker, T., Slate, A., Adams, J., Birmingham, T., Giesbrecht, F., “Comparing the Performance of Sampling Plans That Use a Single Regulatory Limit Based upon Total Aflatoxins to Sampling Plans That Use Dual Limits Based upon B1 and Total Aflatoxins,” (2010) World Mycotoxin Journal, 3 (1), pp. 35-44

Citas:

---------- APA ----------
García Londoño, V.A., Pok, P.S. & Resnik, S. (2018) . Polycyclic Aromatic Hydrocarbons (PAHs) in “Yerba Mate” (Ilex paraguariensis) Fractions. Polycyclic Aromatic Compounds.
http://dx.doi.org/10.1080/10406638.2018.1553193
---------- CHICAGO ----------
García Londoño, V.A., Pok, P.S., Resnik, S. "Polycyclic Aromatic Hydrocarbons (PAHs) in “Yerba Mate” (Ilex paraguariensis) Fractions" . Polycyclic Aromatic Compounds (2018).
http://dx.doi.org/10.1080/10406638.2018.1553193
---------- MLA ----------
García Londoño, V.A., Pok, P.S., Resnik, S. "Polycyclic Aromatic Hydrocarbons (PAHs) in “Yerba Mate” (Ilex paraguariensis) Fractions" . Polycyclic Aromatic Compounds, 2018.
http://dx.doi.org/10.1080/10406638.2018.1553193
---------- VANCOUVER ----------
García Londoño, V.A., Pok, P.S., Resnik, S. Polycyclic Aromatic Hydrocarbons (PAHs) in “Yerba Mate” (Ilex paraguariensis) Fractions. Polycyclic Aromat. Compd. 2018.
http://dx.doi.org/10.1080/10406638.2018.1553193