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Abstract:

The synthesis, an improved refined crystal and molecular structure re-determination, and the thermal decomposition behavior of two Zn(II) derivatives of isocinchomeronic acid (2,5-pyridinedicarboxylic acid or H 22,5-pydc) are presented. [Zn(2,5-pydc)(H2O) 3Zn(2,5-pydc)(H2O)2]2 (1) crystallizes in the triclinic P-1 space group with a = 7.106(2), b = 11.450(2), c = 11.869(1) Å, α = 107.29(1), β = 104.08(1), γ = 90.32(2)°, and Z = 2. [Zn(2,5-pydc)(H2O)2] ·H2O (2) is orthorhombic (P21212 1 space group), with a = 7.342(1), b = 9.430(1), c = 13.834(2) Å, and Z = 4. The structures were refined to agreement R 1-factors of 0.0315 (1) and 0.0336 (2). Complex (1) is arranged as molecular Zn4(2,5-pydc)4(H2O)10 tetramers, the cages of which define channels that remain unblocked by anions. Compound (2) is polymeric with Zn(2,5-pydc)(H2O)2 and Zn(2,5-pydc)(H2O)3 units linked through bridging ligands. Both compounds were synthesized under mild conditions in aqueous media, without need to resort to hydrothermal media. Changing the pH from 4.51 to 5.75 suffices to direct the chemical processes toward the orthorhombic compound rather than to the triclinic one. © 2008 Springer Science+Business Media, LLC.

Registro:

Documento: Artículo
Título:Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid)
Autor:Sileo, E.E.; Piro, O.E.; Rigotti, G.; Blesa, M.A.; De Araujo, A.S.; Castellano, E.E.
Filiación:Departamento de Química Inorgánica, Analítica Y Química Física, Facultad de Ciencias Exactas Y Naturales, Pab. II, C1428EHA Buenos Aires, Argentina
Departamento de Física, Facultad de Ciencias Exactas, Instituto IFLP (CONICET), C.C. 67, (1900), La Plata, Argentina
Gerencia de Química, Comisión Nacional de Energía Atómica, CONICET, Av. Gral. Paz 1499, San Martín 1650, Argentina
Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, Sao Carlos, SP 13560, Brazil
Palabras clave:2,5-Pyridinedicarboxylate; Isocinchomeronate; Structure; Thermal properties; Zinc
Año:2008
Volumen:19
Número:4
Página de inicio:651
Página de fin:657
DOI: http://dx.doi.org/10.1007/s11224-008-9341-8
Título revista:Structural Chemistry
Título revista abreviado:Struct Chem
ISSN:10400400
CODEN:STCHE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10400400_v19_n4_p651_Sileo

Referencias:

  • Sileo, E.E., Rigotti, G., Rivero, B.E., Blesa, M.A., (1997) J Phys Chem Solids, 58, p. 1127. , 10.1016/S0022-3697(96)00237-5
  • Sileo, E.E., Rigotti, G., Rivero, B.E., Castellano, E.E., Blesa, M.A., (1996) Polyhedron, 15, p. 4531. , 10.1016/0277-5387(96)00189-1
  • Sileo, E.E., Rigotti, G., Piro, O.E., (1999) Acta Chem Scand, 53, p. 535
  • Sileo, E.E., De Araujo, A.S., Rigotti, G., Piro, O.E., Castellano, E.E., (2003) J Mol Struct, 644, p. 67. , 10.1016/S0022-2860(02)00450-7
  • Sileo, E.E., Vega, D., Baggio, R., Garland, M.T., Blesa, M.A., (1999) Aust J Chem, 52, p. 205. , 10.1071/C98120
  • Yaghi, O.M., O'Keeffe, M.N., Ockwig, W., Chae, H.K., Eddaoudi, M., Kim, J., (2003) Nature, 425, p. 705. , 10.1038/nature01650
  • Janiak, C., (2003) Dalton Trans, p. 2781. , doi: 10.1039/b305705b
  • Moulton, B., Zaworotko, M.J., (2001) Chem Rev, 101, p. 1629. , 10.1021/cr9900432
  • Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O'Keeffe, M.O., (2001) Acc Chem Res, 34, p. 319. , 10.1021/ar000034b
  • Robson, R., (2000) J Chem Soc, Dalton Trans, p. 3735. , doi: 10.1039/b003591m
  • MacDonald, J.C., Dorrestein, P.C., Pilley, M.M., Foote, M.M., Lundburg, J.L., Henning, R.W., (2000) J Am Chem Soc, 122, p. 11692. , 10.1021/ja002102v
  • Görbitz, C.H., Etter, M.C., (1992) J Am Chem Soc, 114, p. 627. , 10.1021/ja00028a031
  • Zeng, T., (2002) Angew Chem Int Ed, 42, p. 48
  • Shiu, K., Chen, Z., Liao, F., Wang, S., (2003) Acta Crystallogr, 59, p. 1072
  • Min, D., Yoon, S.S., Jung, D., Lee, C.Y., Kim, Y., Han, W.S., (2001) Inorg Chim Acta, 324, p. 293. , 10.1016/S0020-1693(01)00621-1
  • Platter, M.J., Foreman, M.R.St.J., Howie, R.A., Lackowski, E.E., (1998) J. Chem Res (S), p. 754
  • Tian, G., Zhu, G., Yang, X., Fang, Q., Xue, M., Sun, J., (2005) Chem Commun, p. 1396. , (Camb) doi: 10.1039/b417184e
  • Zhang, X., Huang, D., Chen, C., Liu, Q., Liao, D., Li, L., (2006) Inorg Chem Commun, 8, p. 22. , 10.1016/j.inoche.2004.10.014
  • Sun, L., Niu, S., Jin, J., Yang, G., Ye, L., (2006) Eur J Inorg Chem, p. 5130. , doi: 10.1002/ejic.200600721
  • Zeng, M., Gao, S., Chen, X., (2003) N J Chem, 27, p. 1599. , 10.1039/b306872b
  • Liang, Y., Hong, M., Cao, R., (2001) Acta Crystallogr, 57, p. 145
  • Wang, X., Qin, C., Wang, E., Hu, C., Xu, L., (2004) J Mol Struct, 698, p. 75. , 10.1016/j.molstruc.2004.04.020
  • Mahata, P., Natarajan, S., (2005) Eur J Inorg Chem, p. 2156. , doi: 10.1002/ejic.200400937
  • Wei, Y., Hou, H., Li, L., Fan, Y., Zhu, Y., (2005) Cryst Growth des, 5, p. 1405. , 10.1021/cg049596i
  • (1997) COLLECT, , Enraf-Nonius Nonius BV, Delft, The Netherlands
  • Harms, K., Wocadlo, S., (1995) XCAD4-CAD4 Data Reduction, , University of Marburg Germany
  • Spek, A.L., (1998) PLATON, a Multipurpose Crystallographic Tool, , Utrecht University Utrecht, The Netherlands
  • Sheldrick, G.M., (1997) SHELXS-97. Program for Crystal Structure Resolution, , University of Göttingen Germany
  • Sheldrick, G.M., (1997) SHELXL-97. Program for Crystal Structures Analysis, , University of Göttingen Germany
  • Johnson, C.K., (1976) ORTEP-II. a Fortran Thermal-ellipsoid Plot Program. Report ORNL-5138, , Oak Ridge National Laboratory Tennessee, USA

Citas:

---------- APA ----------
Sileo, E.E., Piro, O.E., Rigotti, G., Blesa, M.A., De Araujo, A.S. & Castellano, E.E. (2008) . Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid). Structural Chemistry, 19(4), 651-657.
http://dx.doi.org/10.1007/s11224-008-9341-8
---------- CHICAGO ----------
Sileo, E.E., Piro, O.E., Rigotti, G., Blesa, M.A., De Araujo, A.S., Castellano, E.E. "Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid)" . Structural Chemistry 19, no. 4 (2008) : 651-657.
http://dx.doi.org/10.1007/s11224-008-9341-8
---------- MLA ----------
Sileo, E.E., Piro, O.E., Rigotti, G., Blesa, M.A., De Araujo, A.S., Castellano, E.E. "Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid)" . Structural Chemistry, vol. 19, no. 4, 2008, pp. 651-657.
http://dx.doi.org/10.1007/s11224-008-9341-8
---------- VANCOUVER ----------
Sileo, E.E., Piro, O.E., Rigotti, G., Blesa, M.A., De Araujo, A.S., Castellano, E.E. Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid). Struct Chem. 2008;19(4):651-657.
http://dx.doi.org/10.1007/s11224-008-9341-8