Abstract:
The performance of an electrochemical sensor based on the ability of a probe to cross a mesoporous membrane partially blocked by an analyte is predicted using a numerical model. The system comprehends a membrane placed close to the working electrode and the signal is generated by applying square wave voltammetry. The digital simulation allows comparing the responses for different situations regarding the way in which the membrane is blocked by the sample. The developed model is compared with experimental results. The effect of the sizes of the pore, analyte and probe on the system response is evaluated. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Registro:
Documento: |
Artículo
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Título: | Modeling the electrochemical response of mesoporous materials toward its application to biomolecular detection |
Autor: | Peinetti, A.S.; González, G.A.; Battaglini, F. |
Filiación: | INQUIMAE - Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactasy Naturales, Universidad de Buenos Aires,Ciudad Universitaria, PabellOn 2, C1428EHA Buenos Aires, Argentina
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Palabras clave: | Amperometric sensors; Digital simulation; Label-free sensing; Membranes; Mesoporous membranes; Sensors; Square wave voltammetry |
Año: | 2010
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Volumen: | 22
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Número: | 12
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Página de inicio: | 1329
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Página de fin: | 1336
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DOI: |
http://dx.doi.org/10.1002/elan.200900572 |
Título revista: | Electroanalysis
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Título revista abreviado: | Electroanalysis
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ISSN: | 10400397
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CODEN: | ELANE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10400397_v22_n12_p1329_Peinetti |
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Citas:
---------- APA ----------
Peinetti, A.S., González, G.A. & Battaglini, F.
(2010)
. Modeling the electrochemical response of mesoporous materials toward its application to biomolecular detection. Electroanalysis, 22(12), 1329-1336.
http://dx.doi.org/10.1002/elan.200900572---------- CHICAGO ----------
Peinetti, A.S., González, G.A., Battaglini, F.
"Modeling the electrochemical response of mesoporous materials toward its application to biomolecular detection"
. Electroanalysis 22, no. 12
(2010) : 1329-1336.
http://dx.doi.org/10.1002/elan.200900572---------- MLA ----------
Peinetti, A.S., González, G.A., Battaglini, F.
"Modeling the electrochemical response of mesoporous materials toward its application to biomolecular detection"
. Electroanalysis, vol. 22, no. 12, 2010, pp. 1329-1336.
http://dx.doi.org/10.1002/elan.200900572---------- VANCOUVER ----------
Peinetti, A.S., González, G.A., Battaglini, F. Modeling the electrochemical response of mesoporous materials toward its application to biomolecular detection. Electroanalysis. 2010;22(12):1329-1336.
http://dx.doi.org/10.1002/elan.200900572