Artículo
Baldessari, A.; Mangone, C.P. "Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity" (2002) Biocatalysis and Biotransformation. 20(4):275-279
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Abstract:
A series of novel fatty acid derivatives of pyridoxine, one of the three members of the vitamin B6 group, has been prepared. These products were obtained using an enzymatic approach. Several lipases catalyzed esterification and transesterification reactions of pyridoxine with carboxylic acid or alkyl carboxylates showed a remarkable regioselective behavior; only monoacyl derivatives were obtained. The surfactant activity, composition and clean enzymatic methodology applied in the preparation of these products make them useful as ingredients in cosmetic and pharmaceutical formulations or food additives.
Registro:
| Documento: | Artículo |
| Título: | Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity |
| Autor: | Baldessari, A.; Mangone, C.P. |
| Filiación: | Departamento de Quimica Organica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina |
| Palabras clave: | Enzyme-catalyzed; Fatty acids; Pyridoxine; Surfactants; Biosynthesis; Carboxylic acids; Derivatives; Drug products; Enzymes; Esterification; Fatty acids; Food additives; Surface active agents; Vitamins; Regioselective; Nitrogen compounds; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyl 13 docosenoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyl 5,8,11,14 eicosatetraenoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyl 9 octadecanoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyl 9,12 octadecanoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyl 9,12,15 octadecatrienoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyleicosanoic acid; (5 hydroxy 4 hydroxymethyl 6 methylpyridin 3 yl)methyloctadecanoic acid; carboxylic acid; fatty acid derivative; food additive; pyridoxine derivative; surfactant; triacylglycerol lipase; unclassified drug; acylation; article; catalysis; cosmetic industry; drug activity; drug formulation; drug synthesis; enzymatic assay; enzyme substrate; nonhuman; pancreas; pharmaceutical engineering; swine; Sus scrofa |
| Año: | 2002 |
| Volumen: | 20 |
| Número: | 4 |
| Página de inicio: | 275 |
| Página de fin: | 279 |
| DOI: | http://dx.doi.org/10.1080/10242420290004910 |
| Título revista: | Biocatalysis and Biotransformation |
| Título revista abreviado: | Biocatal. Biotransform. |
| ISSN: | 10242422 |
| CODEN: | BOBOE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10242422_v20_n4_p275_Baldessari |
Referencias:
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Citas:
---------- APA ----------
Baldessari, A. & Mangone, C.P. (2002) . Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity. Biocatalysis and Biotransformation, 20(4), 275-279.http://dx.doi.org/10.1080/10242420290004910
---------- CHICAGO ----------
Baldessari, A., Mangone, C.P. "Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity" . Biocatalysis and Biotransformation 20, no. 4 (2002) : 275-279.http://dx.doi.org/10.1080/10242420290004910
---------- MLA ----------
Baldessari, A., Mangone, C.P. "Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity" . Biocatalysis and Biotransformation, vol. 20, no. 4, 2002, pp. 275-279.http://dx.doi.org/10.1080/10242420290004910
---------- VANCOUVER ----------
Baldessari, A., Mangone, C.P. Enzyme-catalyzed preparation of novel fatty acid derivatives of pyridoxine with surfactant activity. Biocatal. Biotransform. 2002;20(4):275-279.http://dx.doi.org/10.1080/10242420290004910
