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Abstract:

The steam reforming reaction of hydrocarbons and organic fuels, in general, is followed by a two-stage reaction of water gas shift, which allows increasing the hydrogen yield and a final purification step for CO removal to use hydrogen in an ammonia plant or a PEM fuel cell. This paper is focused on the CO Preferential Oxidation, CO PROX (or CO selective oxidation in excess hydrogen) reaction, considered as the simplest and cost effective process to achieve the less than 10 ppm CO. The objective of this paper is to review the performances of noble metals (Pt, Ru, Rh, Pd), gold and transition metal oxides catalysts in this reaction. Although the results reported are largely influenced by the experimental conditions (reactant flow composition, mass of catalyst, duration of experiment...) a comparison of advantages and drawbacks for each type of catalysts is proposed in terms of activity and selectivity as well as of CO 2 and H2O influences. A special attention will be paid to copper-doped ceria catalysts which appear to be very active and selective in a range of temperatures appropriate for fuel cell application. The performances, the stability and the low cost of these formulations compared to noble metal-based catalysts make them very attractive for an industrial application. © Springer Science+Business Media, LLC 2008.

Registro:

Documento: Artículo
Título:Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over noble metals and transition metal oxides: Advantages and drawbacks
Autor:Bion, N.; Epron, F.; Moreno, M.; Mariño, F.; Duprez, D.
Filiación:Laboratoire de Catalyse en Chimie Organique, LACCO, Université de Poitiers, CNRS, 40, Av. Recteur Pineau, 86022 Poitiers Cedex, France
Laboratorio de Procesos Catalíticos, DIQ-FI, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:Copper-ceria catalysts; Gold catalysts; Hydrogen purification; Noble metal catalysts; Preferential oxidation of CO; Ammonia plants; Ceria catalysts; CO preferential oxidation; CO removal; CO selective oxidation; CO-PROX; Cost effective; Excess hydrogen; Experimental conditions; Fuel cell application; Gold catalysts; Hydrogen purification; Hydrogen yields; Low costs; Metal-based catalysts; Noble metal catalysts; Organic fuels; PEM fuel cell; Preferential oxidation of carbon monoxides; Preferential oxidation of CO; Reactant flows; Transition-metal oxides; Two stage; Water-gas shifts; Air purification; Carbon dioxide; Carbon monoxide; Cerium compounds; Chemicals removal (water treatment); Copper; Fuel cells; Gas fuel purification; Gold; Hydrocarbons; Hydrogen; Hydrogen production; Industrial applications; Inert gases; Metals; Oxidation; Palladium; Platinum; Rhodium; Steam engineering; Steam reforming; Transition metal compounds; Catalyst selectivity
Año:2008
Volumen:51
Número:1-4
Página de inicio:76
Página de fin:88
DOI: http://dx.doi.org/10.1007/s11244-008-9116-x
Título revista:Topics in Catalysis
Título revista abreviado:Top. Catal.
ISSN:10225528
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10225528_v51_n1-4_p76_Bion

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Citas:

---------- APA ----------
Bion, N., Epron, F., Moreno, M., Mariño, F. & Duprez, D. (2008) . Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over noble metals and transition metal oxides: Advantages and drawbacks. Topics in Catalysis, 51(1-4), 76-88.
http://dx.doi.org/10.1007/s11244-008-9116-x
---------- CHICAGO ----------
Bion, N., Epron, F., Moreno, M., Mariño, F., Duprez, D. "Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over noble metals and transition metal oxides: Advantages and drawbacks" . Topics in Catalysis 51, no. 1-4 (2008) : 76-88.
http://dx.doi.org/10.1007/s11244-008-9116-x
---------- MLA ----------
Bion, N., Epron, F., Moreno, M., Mariño, F., Duprez, D. "Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over noble metals and transition metal oxides: Advantages and drawbacks" . Topics in Catalysis, vol. 51, no. 1-4, 2008, pp. 76-88.
http://dx.doi.org/10.1007/s11244-008-9116-x
---------- VANCOUVER ----------
Bion, N., Epron, F., Moreno, M., Mariño, F., Duprez, D. Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over noble metals and transition metal oxides: Advantages and drawbacks. Top. Catal. 2008;51(1-4):76-88.
http://dx.doi.org/10.1007/s11244-008-9116-x