Abstract:
The photochemical reaction of N-acetyl carbazole was studied in ethanol and dichloromethane solution. The reaction products consist of the usual photo-Fries rearrangement products (1-acetyl and 3-acetyl carbazole), carbazole, 4-acetyl carbazole and 3,N-diacetyl carbazole. The photoproducts were identified by gas chromatography-mass spectrometry. They were isolated and analysed by UV and IR spectroscopy, mass spectroscopy and nuclear magnetic resonance spectroscopy, which provided evidence for their structural identification. Electron donor-acceptor (EDA) complex formation was observed in ethanol and dichloromethane and the relationship between the photochemical reactivity and the EDA formation is briefly discussed. © 1991.
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Citas:
---------- APA ----------
Bonesi, S.M. & Erra-Balsells, R.
(1991)
. Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I. Journal of Photochemistry and Photobiology, A: Chemistry, 56(1), 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4---------- CHICAGO ----------
Bonesi, S.M., Erra-Balsells, R.
"Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I"
. Journal of Photochemistry and Photobiology, A: Chemistry 56, no. 1
(1991) : 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4---------- MLA ----------
Bonesi, S.M., Erra-Balsells, R.
"Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I"
. Journal of Photochemistry and Photobiology, A: Chemistry, vol. 56, no. 1, 1991, pp. 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4---------- VANCOUVER ----------
Bonesi, S.M., Erra-Balsells, R. Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I. J. Photochem. Photobiol. A Chem. 1991;56(1):55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4