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Abstract:

The photochemical reaction of N-acetyl carbazole was studied in ethanol and dichloromethane solution. The reaction products consist of the usual photo-Fries rearrangement products (1-acetyl and 3-acetyl carbazole), carbazole, 4-acetyl carbazole and 3,N-diacetyl carbazole. The photoproducts were identified by gas chromatography-mass spectrometry. They were isolated and analysed by UV and IR spectroscopy, mass spectroscopy and nuclear magnetic resonance spectroscopy, which provided evidence for their structural identification. Electron donor-acceptor (EDA) complex formation was observed in ethanol and dichloromethane and the relationship between the photochemical reactivity and the EDA formation is briefly discussed. © 1991.

Registro:

Documento: Artículo
Título:Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I
Autor:Bonesi, S.M.; Erra-Balsells, R.
Filiación:Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, c.c. 74-Suc. 30, 1430 Buenos Aires, Argentina
Año:1991
Volumen:56
Número:1
Página de inicio:55
Página de fin:72
DOI: http://dx.doi.org/10.1016/1010-6030(91)80006-4
Título revista:Journal of Photochemistry and Photobiology, A: Chemistry
Título revista abreviado:J. Photochem. Photobiol. A Chem.
ISSN:10106030
CODEN:JPPCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10106030_v56_n1_p55_Bonesi

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Citas:

---------- APA ----------
Bonesi, S.M. & Erra-Balsells, R. (1991) . Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I. Journal of Photochemistry and Photobiology, A: Chemistry, 56(1), 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4
---------- CHICAGO ----------
Bonesi, S.M., Erra-Balsells, R. "Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I" . Journal of Photochemistry and Photobiology, A: Chemistry 56, no. 1 (1991) : 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4
---------- MLA ----------
Bonesi, S.M., Erra-Balsells, R. "Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I" . Journal of Photochemistry and Photobiology, A: Chemistry, vol. 56, no. 1, 1991, pp. 55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4
---------- VANCOUVER ----------
Bonesi, S.M., Erra-Balsells, R. Product study of the photolysis of N-acetyl carbazole in ethanol and dichloromethane solution. Part I. J. Photochem. Photobiol. A Chem. 1991;56(1):55-72.
http://dx.doi.org/10.1016/1010-6030(91)80006-4