Abstract:
The influence of the opposite effects (generation and annealing of crystal defects) on the dissolution of reactor irradiated metal oxides was studied. Kinetic parameters were calculated, using a model proposed for the dissolution process, and the relation between the structure of the irradiated oxides and their behavior upon dissolution was discussed. (C) 2000 Elsevier Science Ltd. The influence of the opposite effects on the dissolution of reactor irradiated metal oxides was studied. The kinetic parameters were calculated, using a model proposed for the dissolution process, and the relation between the structure of the irradiated oxides and their behavior upon dissolution was discussed. The results obtained for the oxidative dissolution of Cr2O3 and for the reductive dissolution of MnO2 were reported.
Registro:
Documento: |
Artículo
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Título: | Model for dissolution of irradiated metal oxides: Reactivity and structure |
Autor: | Dos Santos Afonso, M.; Di Risio, D.R. |
Ciudad: | Exeter, United Kingdom |
Filiación: | INQUIMAE - Depto. de Quim. Inorg., Analitica Y Quim. Fis., Fac. Cie. E., Buenos Aires, Argentina Depto. de Quim. Inorgánica, Analitica Y Quim. Fis., Fac. Cie. E., Buenos Aires, Argentina
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Palabras clave: | Chromium compounds; Dissolution; Gamma rays; Manganese compounds; Mathematical models; Chromium oxide; Manganese dioxide; Radiation chemistry; chromium derivative; manganese dioxide; metal oxide; article; chemical analysis; chemical reaction; chemical structure; dissolution; gamma radiation; irradiation; kinetics; model; nuclear reactor; oxidation; radiation dose |
Año: | 2000
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Volumen: | 58
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Número: | 3
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Página de inicio: | 261
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Página de fin: | 265
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DOI: |
http://dx.doi.org/10.1016/S0969-806X(99)00374-6 |
Título revista: | Radiation Physics and Chemistry
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Título revista abreviado: | Radiat. Phys. Chem.
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ISSN: | 0969806X
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CODEN: | RPCHD
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CAS: | manganese dioxide, 1313-13-9
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0969806X_v58_n3_p261_DosSantosAfonso |
Referencias:
- Blesa, M.A., Morando, P.J., Regazzoni, A.E., (1994) Chemical Dissolution of Metal Oxides, , Boca Raton, FL: CRC Press
- Chang, R., (1992) Química 4th Ed., , New York: McGraw-Hill
- Dos Santos Afonso, M., Di Risio, C.D., Roitberg, A., Marqués, R.O., Blesa, M.A., Reductive dissolution of neutron- And gamma-irradiated magnetite (1990) Int. J. Radiat. Appl. Instrum. Part C Radiat Phys. Chem., 36, p. 457
- Dos Santos Afonso, M., Morando, P.J., Blesa, M.A., Banwart, S., Stumm, W., The reductive dissolution of iron oxides by ascorbate (1990) J. Colloid Interface Sci., 138, p. 74
- Dos Santos Afonso, M., Di Risio, C., Zysmilich, M., Marqués, R.O., Blesa, M.A., A model of the annealing and activation of dissolution sites in magnetite exposed (γ+n) radiation (1996) Radiat. Phys. Chem., 48, p. 715
- Reartes, G.B., Morando, P.J., Blesa, M.A., Hewlett, P., Matijevic, E., Reactivity of chromium oxide in aqueous solutions. Part I. Oxidative dissolution (1991) Chem. Mater., 3, p. 1101
- Regazzoni, A.E., Urrutia, G.A., Blesa, M.A., Maroto, A.J.G., Some observations on the composition and morphology of synthetic magnetite obtained by different roots (1981) J. Inorg. Nucl. Chem., 43, p. 1489
- Shriver, D.F., Atkins, P., Langford, C.H., (1997) Inorganic Chemistry 2nd Ed., , New York: Freeman
- Stone, A.T., Morgan, J.J., Reduction and dissolution of manganese(III) and manganese(IV) oxides by organics. 1. Reaction with hydroquinone (1984) Environ. Sci. Technol., 18, pp. 450-459
- Stone, A.T., Morgan, J.J., Reduction and dissolution of manganese(III) and manganese(IV) oxides by organics. 2. Survey of the reactivity of the organics (1984) Environ. Sci. Technol., 18, pp. 617-624
- Stumm, W., Morgan, J.J., (1996) Aquatic Chemistry 3rd Ed., , New York: Wiley
Citas:
---------- APA ----------
Dos Santos Afonso, M. & Di Risio, D.R.
(2000)
. Model for dissolution of irradiated metal oxides: Reactivity and structure. Radiation Physics and Chemistry, 58(3), 261-265.
http://dx.doi.org/10.1016/S0969-806X(99)00374-6---------- CHICAGO ----------
Dos Santos Afonso, M., Di Risio, D.R.
"Model for dissolution of irradiated metal oxides: Reactivity and structure"
. Radiation Physics and Chemistry 58, no. 3
(2000) : 261-265.
http://dx.doi.org/10.1016/S0969-806X(99)00374-6---------- MLA ----------
Dos Santos Afonso, M., Di Risio, D.R.
"Model for dissolution of irradiated metal oxides: Reactivity and structure"
. Radiation Physics and Chemistry, vol. 58, no. 3, 2000, pp. 261-265.
http://dx.doi.org/10.1016/S0969-806X(99)00374-6---------- VANCOUVER ----------
Dos Santos Afonso, M., Di Risio, D.R. Model for dissolution of irradiated metal oxides: Reactivity and structure. Radiat. Phys. Chem. 2000;58(3):261-265.
http://dx.doi.org/10.1016/S0969-806X(99)00374-6