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Pereyra-Irujo, G.A.; Izquierdo, N.G.; Covi, M.; Nolasco, S.M.; Quiroz, F.; Aguirrezábal, L.A.N. "Variability in sunflower oil quality for biodiesel production: A simulation study" (2009) Biomass and Bioenergy. 33(3):459-468
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Abstract:

Biodiesel is an alternative fuel made from vegetable oils or animal fats. The fatty acid composition of the feedstock, which varies among and within species, is the main determinant of biodiesel quality. In this work we analyze the variability in biodiesel quality (density, kinematic viscosity, heating value, cetane number and iodine value) obtained from sunflower oil, by means of a validated crop model that predicts the fatty acid composition of one high-oleic, and three traditional (high-linoleic) sunflower hybrids. The model was run with a 10-year average weather data from 56 weather stations in Argentina, and simulation results were compared to the biodiesel standards of Argentina, USA and Europe. We show that biodiesel produced from sunflower oil does not have one fixed quality, but different qualities depending on weather conditions and agricultural practices, and that intraspecific variation in biodiesel quality can be larger than interspecific differences. Our results suggest that (a) sunflower oil from high-oleic hybrids is suitable for biodiesel production (within limits of all analyzed standards), regardless of growing conditions and (b) sunflower oil from traditional hybrids is suitable for biodiesel production under the standards of Argentina and USA, while only certain hybrids grown in warm regions (e.g., Northern Argentina, Southern USA, China, India, Pakistan) are suitable for biodiesel production according to the European standard. © 2008 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Variability in sunflower oil quality for biodiesel production: A simulation study
Autor:Pereyra-Irujo, G.A.; Izquierdo, N.G.; Covi, M.; Nolasco, S.M.; Quiroz, F.; Aguirrezábal, L.A.N.
Filiación:Unidad Integrada Balcarce, Facultad de Ciencias Agrarias, Universidad Nacional de Mar del Plata, CC 276, 7620 Balcarce Buenos Aires, Argentina
Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Guiraldes 2160, Ciudad Universitaria, C1428EGA Buenos Aires, Argentina
Facultad de Ingeniería, Universidad Nacional, Centro de la Provincia de Buenos Aires, Avda. del Valle 7537, B7400JWI Olavarría, Argentina
Palabras clave:Biodiesel; Cetane number; High-oleic hybrid; Iodine value; Quality; Sunflower (Helianthus annuus L.); Temperature; Cetane number; High-oleic hybrid; Iodine value; Quality; Sunflower (Helianthus annuus L.); Acids; Alternative fuels; Fatty acids; Fuel oils; Industrial chemicals; Iodine; Plants (botany); Standards; Vegetable oils; Well stimulation; Biodiesel; agricultural practice; biofuel; climate conditions; herb; iodine; modeling; vegetable oil; Argentina; Eurasia; Europe; North America; South America; United States; Animalia; Helianthus; Helianthus annuus
Año:2009
Volumen:33
Número:3
Página de inicio:459
Página de fin:468
DOI: http://dx.doi.org/10.1016/j.biombioe.2008.07.007
Título revista:Biomass and Bioenergy
Título revista abreviado:Biomass Bioenergy
ISSN:09619534
CODEN:BMSBE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09619534_v33_n3_p459_PereyraIrujo

Referencias:

  • Izquierdo, N., Aguirrezabal, L., Andrade, F., Pereyra, V., Night temperature affects fatty acid composition in sunflower oil depending on the hybrid and the phenological stage (2002) Field Crops Research, 77, pp. 115-126
  • Izquierdo, N., Aguirrezábal, L., Genetic variability of the response of fatty acid composition to temperature (2008) Field Crops Research, 106, pp. 116-125
  • Knothe, G., Analyzing biodiesel: standards and other methods (2006) Journal of the American Oil Chemists' Society, 83, pp. 823-833
  • Pereyra-Irujo, G., Aguirrezábal, L., Sunflower yield and oil quality interactions and variability: analysis through a simple simulation model (2007) Agricultural and Forest Meteorology, 143, pp. 252-265
  • Leon, A., Lee, M., Andrade, F., Quantitative trait loci for growing degree days to flowering and photoperiod response in sunflower (Helianthus annuus L.) (2001) Theoretical and Applied Genetics, 102, pp. 497-503
  • Van Gerpen, J., Shanks, B., Pruszko, R., Clements, D., Knothe, G., (2004) Biodiesel analytical methods: NREL/SR-510-36240, , National Renewable Energy Laboratory, Colorado, USA
  • Clements, L., (1996) Blending rules for formulating biodiesel fuel, , The National Biodiesel Board
  • Knothe, G., Matheaus, A., Ryan III, T., Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester small star, filled (2003) Fuel, 82, pp. 971-975
  • Azian, M., Mustafa Kamal, A., Panau, F., Ten, W., Viscosity estimation of triacylglycerols and of some vegetable oils, based on their triacylglycerol composition (2001) Journal of the American Oil Chemists' Society, 78, pp. 1001-1005
  • Allen, C., Watts, K., Ackman, R., Pegg, M., Predicting the viscosity of biodiesel fuels from their fatty acid ester composition (1999) Fuel, 78, pp. 1319-1326
  • Knothe, G., Steidley, K., Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components (2005) Fuel, 84, pp. 1059-1065
  • Knothe, G., Structure indices in FA chemistry. How relevant is the iodine value? (2002) Journal of the American Oil Chemists' Society, 79, pp. 847-854
  • American Oil Chemists' Society (1998) Official Methods and Recommended Practices of the AOCS (Method Cd 1c-85). 5th ed., , AOCS Press, Champaign
  • Kobayashi, K., Salam, M.U., Comparing simulated and measured values using mean squared deviation and its components (2000) Agronomy Journal, 92, pp. 345-352
  • Cressie, N.A.C., (1991) Statistics for spatial data, , John Wiley and Sons, Inc., New York 900 pp
  • Chang, D.Y.Z., Van Gerpen, J.H., Lee, I., Johnson, L.A., Hammond, E.G., Marley, S.J., Fuel properties and emissions of soybean oil esters as diesel fuel (1996) Journal of the American Oil Chemists' Society, 73, pp. 1549-1555
  • San José Alonso, J.F., López Sastre, J.A., Romero-Ávila, C., López Romero-Ávila, E., Izquierdo Iglesias, C., Using mixtures of diesel and sunflower oil as fuel for heating purposes in Castilla y León (2005) Energy, 30, pp. 573-582
  • Azam, M., Waris, A., Nahar, N., Prospects and potential of fatty acid methyl esters of some non-traditional seed oils for use as biodiesel in India (2005) Biomass and Bioenergy, 29, pp. 293-302
  • Schwab, A.W., Bagby, M.O., Freedman, B., Preparation and properties of diesel fuels from vegetable oils (1987) Fuel, 66, pp. 1372-1378
  • Pischinger, G.H., Falcon, A.M., Siekmann, R.W., Fernandes, F.R., Methylesters of plant oils as diesel fuels, either straight or in blends (1982) Vegetable oil fuels, pp. 198-208. , Amer. Soc. Agric. Engrs., St. Joseph, MI, USA ASAE Publication 4-82
  • Sobrino, E., Tarquis, A.M., Cruz Díaz, M., Modeling the oleic acid content in sunflower oil (2003) Agronomy Journal, 95, pp. 329-334
  • Muratorio, A., Cabello, R., Gonzalez, L., Racca, E., Composición de ácidos grasos del aceite de girasol obtenido de semillas certificadas sembradas en distintas zonas de la Republica Argentina. Cosecha 2001-02 (2003) Aceites & Grasas, 3, pp. 430-435
  • Hasan, F.U., Ahmad, R.A., Effects of seasonal variations on oil and fatty acid profile of sunflower (2003) Helia, 26 (38), pp. 159-166
  • Barros, V., Grimm, A., Doyle, M., Relationship between temperature and circulation in southern South America and its influence from El Niño and La Niña events (2002) Journal of the Meteorological Society of Japan, 80, pp. 33-44
  • Rusticucci, M., Barrucand, M., Observed trends and changes in temperature extremes over Argentina (2004) Journal of Climate, 17, pp. 4099-4107
  • IPCC (Intergovernmental Panel on Climate Change), (2001) Climate change, , http://www.ipcc.ch, Available at
  • Lagravere, T., Kleiber, D., Dayde, J., Conduites culturales et performances agronomiques du tournesol oléique : Réalités et perspectives (1998) OCL - Oleagineux Corps gras Lipides, 5, pp. 477-485
  • Baldini, M., Giovanardi, R., Tahmasebi-Enferadi, S., Vannozzi, G., Effects of water regime on fatty acid accumulation and final fatty acid composition in the oil of standard and high oleic sunflower hybrids (2003) Italian Journal of Agronomy, 6, pp. 119-126
  • Steer, B., Seiler, G., Changes in fatty acid composition of sunflower (Helianthus annuus L.) seeds in response to time of nitrogen application, supply rates and defoliation (1990) Journal of the Science of Food and Agriculture, 51, pp. 11-26
  • Izquierdo, N., Aguirrezabal, L., Andrade, F., Cantarero, M., Modeling the response of fatty acid composition to temperature in a traditional sunflower hybrid (2006) Agronomy Journal, 98, pp. 451-461
  • Knothe, G., Dunn, R.O., Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals (2003) Journal of the American Oil Chemists' Society, 80, pp. 1021-1026
  • Hoogenboom, G., Jones, J., Boote, K., Pickering, N., Bowen, W., Batchelor, W., A new and improved soybean simulation model: CROPGRO-Soybean (1994) World soybean research conference, 5, pp. 20-27. , Chiang Mai, Thailand; Feb
  • Gabrielle, B., Denoroy, P., Gosse, G., Justes, E., Andersen, M., Development and evaluation of a CERES-type model for winter oilseed rape (1998) Field Crops Research, 57, pp. 95-111
  • Oliva, M., Shannon, J., Sleper, D., Ellersieck, M.R., Cardinal, A.J., Paris, R.L., Stability of fatty acid profile in soybean genotypes with modified seed oil composition (2006) Crop Science, 2069, p. 46
  • Luján, J., Facultad de Ciencias Agropecuarias, UNCor, Argentina and Sebastián Zuil, EEA Reconquista, Instituto Nacional de Tecnología Agropecuaria, Argentina, Personal communication; 2007

Citas:

---------- APA ----------
Pereyra-Irujo, G.A., Izquierdo, N.G., Covi, M., Nolasco, S.M., Quiroz, F. & Aguirrezábal, L.A.N. (2009) . Variability in sunflower oil quality for biodiesel production: A simulation study. Biomass and Bioenergy, 33(3), 459-468.
http://dx.doi.org/10.1016/j.biombioe.2008.07.007
---------- CHICAGO ----------
Pereyra-Irujo, G.A., Izquierdo, N.G., Covi, M., Nolasco, S.M., Quiroz, F., Aguirrezábal, L.A.N. "Variability in sunflower oil quality for biodiesel production: A simulation study" . Biomass and Bioenergy 33, no. 3 (2009) : 459-468.
http://dx.doi.org/10.1016/j.biombioe.2008.07.007
---------- MLA ----------
Pereyra-Irujo, G.A., Izquierdo, N.G., Covi, M., Nolasco, S.M., Quiroz, F., Aguirrezábal, L.A.N. "Variability in sunflower oil quality for biodiesel production: A simulation study" . Biomass and Bioenergy, vol. 33, no. 3, 2009, pp. 459-468.
http://dx.doi.org/10.1016/j.biombioe.2008.07.007
---------- VANCOUVER ----------
Pereyra-Irujo, G.A., Izquierdo, N.G., Covi, M., Nolasco, S.M., Quiroz, F., Aguirrezábal, L.A.N. Variability in sunflower oil quality for biodiesel production: A simulation study. Biomass Bioenergy. 2009;33(3):459-468.
http://dx.doi.org/10.1016/j.biombioe.2008.07.007