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Abstract:

The feasibility of using cypress cone chips from Cupressus sempervirens as a low-cost biosorbent for the removal of two representative basic dyes, methylene blue (MB) and rhodamine B (RhB), from aqueous solutions was investigated in batch and continuous modes. Dyes biosorption was strongly dependent on the solution's pH. Sorption kinetics was determined and properly described by the pseudo-second-order rate model. Experimental equilibrium isotherms fitted the Langmuir model, showing maximum biosorption capacities of 0.62. mmol/g for MB and 0.24. mmol/g for RhB. Competitive experiments from a binary solution of the dyes demonstrated the preference of the cone chips for biosorbing MB. Very low desorption efficiencies were obtained for both dyes. Dynamic experiments showed that the breakthrough time was three times higher for MB biosorption than for RhB for the same conditions. Breakthrough curves were properly represented by a mathematical model. © 2010 Elsevier Ltd.

Registro:

Documento: Artículo
Título:Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes
Autor:Fernandez, M.E.; Nunell, G.V.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energia, PINMATE, Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, C1428BGA Buenos Aires, Argentina
Cátedra de Farmacotecnia II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, C113AAD Buenos Aires, Argentina
Palabras clave:Basic dyes; Biosorption; Cypress cone chips; Textile wastewater treatment; Up-flow column; Aqueous solutions; Basic dyes; Binary solutions; Biosorbents; Biosorption capacity; Break through curve; Breakthrough time; Competitive experiments; Continuous mode; Cypress cone chips; Desorption efficiency; Dynamic experiment; Dynamic modes; Equilibrium isotherms; Langmuir models; Methylene blue; Pseudo second order rate model; Rhodamine B; Sorption kinetics; Textile wastewater treatment; Up-flow column; Adsorption; Biosorption; Desorption; Dyes; Mathematical models; Solutions; Textiles; Wastewater; Wastewater treatment; Water treatment plants; Stripping (dyes); absorbent; cypress cone chip; methylene blue; rhodamine B; unclassified drug; adsorption; aqueous solution; breakthrough curve; coniferous tree; desorption; dye; experimental study; feasibility study; isotherm; numerical model; pH; pollutant removal; reaction kinetics; textile industry; wastewater; aqueous solution; article; biosorption; Cupressus; Cupressus semperviren; desorption; isotherm; mathematical model; pH; priority journal; upflow reactor; Adsorption; Biodegradation, Environmental; Coloring Agents; Cupressus; Hydrogen-Ion Concentration; Kinetics; Methylene Blue; Models, Chemical; Rhodamines; Solutions; Temperature; Water Purification; Cupressus; Cupressus sempervirens
Año:2010
Volumen:101
Número:24
Página de inicio:9500
Página de fin:9507
DOI: http://dx.doi.org/10.1016/j.biortech.2010.07.102
Título revista:Bioresource Technology
Título revista abreviado:Bioresour. Technol.
ISSN:09608524
CODEN:BIRTE
CAS:methylene blue, 61-73-4; rhodamine B, 81-88-9; Coloring Agents; Methylene Blue, 61-73-4; Rhodamines; Solutions; rhodamine B, 14899-08-2
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09608524_v101_n24_p9500_Fernandez

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Citas:

---------- APA ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R. & Cukierman, A.L. (2010) . Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes. Bioresource Technology, 101(24), 9500-9507.
http://dx.doi.org/10.1016/j.biortech.2010.07.102
---------- CHICAGO ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. "Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes" . Bioresource Technology 101, no. 24 (2010) : 9500-9507.
http://dx.doi.org/10.1016/j.biortech.2010.07.102
---------- MLA ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. "Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes" . Bioresource Technology, vol. 101, no. 24, 2010, pp. 9500-9507.
http://dx.doi.org/10.1016/j.biortech.2010.07.102
---------- VANCOUVER ----------
Fernandez, M.E., Nunell, G.V., Bonelli, P.R., Cukierman, A.L. Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes. Bioresour. Technol. 2010;101(24):9500-9507.
http://dx.doi.org/10.1016/j.biortech.2010.07.102