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Abstract:

An industrial raw Kraft lignin was investigated to ascertain its potential use for removal of trace Ni(II) ion from wastewater by using dilute solutions (0.34-1.7 mM) as models. The effect of demineralisation on its metal sorption ability was examined by employing acid pre-treated samples. Under fixed pre-established equilibrium conditions, the raw lignin exhibited a lower effectiveness than the demineralised one, with the latter attaining an almost complete removal of Ni(II) ions. For both lignins, sorption kinetics was properly described by a pseudo-second order rate model. Equilibrium isotherms were also determined and adequately represented by conventional two-parameter models. The higher nickel sorption capacity for the demineralised lignin compared to the raw sample was consistent with enhancements in the negative magnitude of zeta potential, sodium sorption capacity, and content of phenolic hydroxyl groups occasioned by the acid pre-treatment. Accordingly, demineralisation appears as a readily convenient strategy to improve the behaviour of industrial Kraft lignin for potential use as a biosorbent of trace nickel from polluted water. © 2008 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralisation
Autor:Betancur, M.; Bonelli, P.R.; Velásquez, J.A.; Cukierman, A.L.
Filiación:Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas, Energía (PINMATE)-Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Intendente Guiraldes 2620, Ciudad Universitaria, C1428BGA Buenos Aires, Argentina
Grupo de Investigaciones Ambientales, Grupo Pulpa y Papel, Universidad Pontificia Bolivariana, Circular 1 Nro 70-01, Medellín, Colombia
Cátedra Farmacotecnia II-Tecnología Especial, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Junín 956, C1113AAD Buenos Aires, Argentina
Palabras clave:Biosorption; Demineralised lignin; Kraft lignin; Metal pollution; Wastewater; Acids; Atmospheric temperature; Biosorption; Chemical oxygen demand; Chemicals removal (water treatment); Kraft process; Lignin; Metal recovery; Nickel; Nickel alloys; Phenols; Sorption; Wastewater; Water pollution; Zeta potential; AS models; Biosorbent; Demineralisation; Demineralised lignin; Dilute solutions; Equilibrium conditions; Equilibrium isotherms; Kraft lignin; Kraft lignins; Metal pollution; Metal sorptions; Parameter models; Phenolic hydroxyl groups; Polluted waters; Pulping processes; Rate models; Second orders; Sorption capacities; Sorption kinetics; Industrial water treatment; lignin; nickel; phenol; sodium; water; lignin; nickel; pollutant removal; pulp and paper industry; reaction kinetics; sodium; sorption; wastewater; water pollution; article; comparative study; heavy metal removal; isotherm; kinetics; model; priority journal; pulping; sample; waste water; zeta potential; Absorption; Computer Simulation; Feasibility Studies; Lignin; Minerals; Models, Chemical; Nickel; Ultrafiltration; Water Pollutants, Chemical; Water Purification; Acids; Alkali Lignins; Alloy; Industrial Wastes; Kraft Pulping; Lignins; Nickel; Phenols; Sorption; Temperature; Water Pollution; Water Treatment; Zeta Potential
Año:2009
Volumen:100
Número:3
Página de inicio:1130
Página de fin:1137
DOI: http://dx.doi.org/10.1016/j.biortech.2008.08.023
Título revista:Bioresource Technology
Título revista abreviado:Bioresour. Technol.
ISSN:09608524
CODEN:BIRTE
CAS:lignin, 9005-53-2; nickel, 7440-02-0; phenol, 108-95-2, 3229-70-7; sodium, 7440-23-5; water, 7732-18-5; Lignin, 9005-53-2; Minerals; Nickel, 7440-02-0; Water Pollutants, Chemical
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09608524_v100_n3_p1130_Betancur

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Citas:

---------- APA ----------
Betancur, M., Bonelli, P.R., Velásquez, J.A. & Cukierman, A.L. (2009) . Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralisation. Bioresource Technology, 100(3), 1130-1137.
http://dx.doi.org/10.1016/j.biortech.2008.08.023
---------- CHICAGO ----------
Betancur, M., Bonelli, P.R., Velásquez, J.A., Cukierman, A.L. "Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralisation" . Bioresource Technology 100, no. 3 (2009) : 1130-1137.
http://dx.doi.org/10.1016/j.biortech.2008.08.023
---------- MLA ----------
Betancur, M., Bonelli, P.R., Velásquez, J.A., Cukierman, A.L. "Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralisation" . Bioresource Technology, vol. 100, no. 3, 2009, pp. 1130-1137.
http://dx.doi.org/10.1016/j.biortech.2008.08.023
---------- VANCOUVER ----------
Betancur, M., Bonelli, P.R., Velásquez, J.A., Cukierman, A.L. Potentiality of lignin from the Kraft pulping process for removal of trace nickel from wastewater: Effect of demineralisation. Bioresour. Technol. 2009;100(3):1130-1137.
http://dx.doi.org/10.1016/j.biortech.2008.08.023