Abstract:
The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylene fluorophore. The compatibility of the photochromic compound in this medium and the non-destructive readout capability were demonstrated. The dye doped organogel was further used as a template and an innovative method was employed to grow fluorescent silica spherical nanoparticles with physically and chemically admixed perylene dye. © 2012 The Royal Society of Chemistry.
Registro:
Documento: |
Artículo
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Título: | A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles |
Autor: | Edelsztein, V.C.; Jares-Erijman, E.A.; Müllen, K.; Di Chenna, P.H.; Spagnuolo, C.C. |
Filiación: | CIHIDECAR-CONICET, Facultad de Ciencias Exactas y Naturales, Dto. Química Orgánica, 3er piso Pabellón II, Cdad. Universitaria, Buenos Aires, Argentina UMYMFOR(CONICET-UBA), Facultad de Ciencias Exactas y Natura-les, Dto. Química Orgánica, 3er piso Pabe-llón II, Cdad. Universitaria, Buenos Aires, Argentina Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128, Mainz, Germany
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Palabras clave: | Diarylethenes; Dye-doped; Fluorescence emission; Fluorescent nanoparticles; Innovative method; Low molecular weight; Non destructive; Organo-gelator; Organogels; Perylene dyes; Perylenes; Photochromic compound; Photoswitching; Spherical nanoparticles; Templated synthesis; Doping (additives); Nanoparticles; Photochromism; Polycyclic aromatic hydrocarbons; Silica; Fluorescence |
Año: | 2012
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Volumen: | 22
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Número: | 41
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Página de inicio: | 21857
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Página de fin: | 21861
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DOI: |
http://dx.doi.org/10.1039/c2jm34891h |
Título revista: | Journal of Materials Chemistry
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Título revista abreviado: | J. Mater. Chem.
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ISSN: | 09599428
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CODEN: | JMACE
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v22_n41_p21857_Edelsztein |
Referencias:
- Das, D., Kar, T., Das, P.K., (2012) Soft Matter, 8, p. 2348
- Steed, J.W., (2011) Chem. Commun., 47, p. 1379
- Ajayaghosh, A., Praveen, V.K., Vijayakumar, C., (2008) Chem. Soc. Rev., 37, p. 109
- Huebon, F.J.M., Jonkheijim, P., Meijer, E.W., Schenning, A.P.H.J., (2005) Chem. Soc. Rev., 105, p. 1491
- Li, X., Peng, J., Kang, J., Choy, J., Steinhart, M., Knoll, W., Kim, D., (2008) Soft Matter, 4, p. 515
- Sada, K., Takeuchi, M., Fujita, N., Numata, M., Shinkai, S., (2007) Chem. Soc. Rev., p. 415
- Yagai, S., Ishii, M., Karatsu, T., Kitamura, A., (2007) Angew. Chem., Int. Ed., 46, p. 1
- Huang, X., Weiss, R.G., (2007) Tetrahedron, 63, p. 7375
- Kawano, S., Fujita, N., Shinkai, S., (2003) Chem. Commun., p. 1352
- Llusar, M., Sanchez, C., (2008) Chem. Mater., 20, p. 782
- Sugiyasu, K., Fujita, N., Shinkai, S., (2004) Angew. Chem., Int. Ed., 43, p. 1229
- Edelsztein, V.C., Burton, G., Di Chenna, P.H., (2010) Tetrahedron, 66, p. 2162
- Weil, T., Vosch, T., Hofkens, J., Peneva, K., Müllen, K., (2010) Angew. Chem., Int. Ed., 49, p. 2
- Inokuchi, H., (1988) Angew. Chem., Int. Ed. Engl., 27, p. 1747
- Li, C., Schöneboom, J., Liu, Z., Pschirer, N.G., Erk, P., Herrmann, A., Müllen, K., (2009) Chem.-Eur. J., 15, p. 878
- Peneva, K., Mihov, G., Nolde, F., Rocha, S., Hotta, J.-I., Braeckmans, K., Hofkens, J., Müllen, K., (2008) Angew. Chem., Int. Ed., 47, p. 3372
- Würthner, F., Hanke, B., Lysetska, M., Lambright, G., Harms, G.S., (2005) Org. Lett., 7, p. 967
- Wu, H., Xue, L., Shi, Y., Chen, Y., Li, X., (2011) Langmuir, 27, pp. 3074-3082
- Brome, W.R., De Jong, J.J.D., Kudernac, T., Walko, M., Lucus, L.M., Uchida, K., Van Esch, J.H., Feringa, B.L., (2005) Chem.-Eur. J., 11, p. 6414
- Irie, M., (2000) Chem. Rev., 100, p. 1685
- Tsivgoulis, G.M., Lehn, J.-M., (1996) Chem.-Eur. J., 1, p. 285
- Fukaminato, T., Sasaki, T., Kawai, T., Tamai, T., Irie, M., (2004) J. Am. Chem. Soc., 126, p. 14843
- Giordano, L., Jovin, T.M., Irie, M., Jares-Erijman, E.A., (2002) J. Am. Chem. Soc., 124, p. 7481
- Matsuda, K., Irie, M., (2004) J. Photochem. Photobiol., C, 5, p. 169
- Raymo, F.M., Tomasulo, M., (2005) J. Phys. Chem. A, 109, p. 7343
- Tian, H., Yang, S., (2004) Chem. Soc. Rev., 33, p. 85
- Kobatake, S., Yamada, M., Yamada, T., Irie, M., (1999) J. Am. Chem. Soc., 121, p. 8450
- Bae, S.W., Tan, W., Hong, J., (2012) Chem. Commun., 48, p. 2270
- Chung, J.W., Yoon, S., Lim, S., An, B., Park, S.Y., (2009) Angew. Chem., Int. Ed., 48, p. 7030
- Schneider, M., Mu, K., (2000) Chem. Mater., 12, p. 352
Citas:
---------- APA ----------
Edelsztein, V.C., Jares-Erijman, E.A., Müllen, K., Di Chenna, P.H. & Spagnuolo, C.C.
(2012)
. A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles. Journal of Materials Chemistry, 22(41), 21857-21861.
http://dx.doi.org/10.1039/c2jm34891h---------- CHICAGO ----------
Edelsztein, V.C., Jares-Erijman, E.A., Müllen, K., Di Chenna, P.H., Spagnuolo, C.C.
"A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles"
. Journal of Materials Chemistry 22, no. 41
(2012) : 21857-21861.
http://dx.doi.org/10.1039/c2jm34891h---------- MLA ----------
Edelsztein, V.C., Jares-Erijman, E.A., Müllen, K., Di Chenna, P.H., Spagnuolo, C.C.
"A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles"
. Journal of Materials Chemistry, vol. 22, no. 41, 2012, pp. 21857-21861.
http://dx.doi.org/10.1039/c2jm34891h---------- VANCOUVER ----------
Edelsztein, V.C., Jares-Erijman, E.A., Müllen, K., Di Chenna, P.H., Spagnuolo, C.C. A luminescent steroid-based organogel: ON-OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles. J. Mater. Chem. 2012;22(41):21857-21861.
http://dx.doi.org/10.1039/c2jm34891h