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Abstract:

Highly ordered hybrid metallic-polymeric assemblies were prepared by simultaneously combining two organization-directing tools: the liquid crystalline behavior of high aspect ratio silver nanowires (Ag-NWs) dispersed in poly(vinyl alcohol) (PVA) aqueous solutions and a cryogenic technique based on the directional freezing of the liquid crystal-like systems. This combination allowed us to render highly oriented Ag-NWs inside macroporous PVA scaffolds. As a consequence of the compact self-assembly of NWs into the structured composites, electrically conductive metallic-polymeric hybrid materials were obtained. © 2012 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds
Autor:Romeo, H.E.; Hoppe, C.E.; López-Quintela, M.A.; Williams, R.J.J.; Minaberry, Y.; Jobbágy, M.
Filiación:Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), Universidad Nacional de Mar Del Plata, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), 7600 Mar del Plata, Argentina
Departamento de Química Física, Facultad de Química, Universidad de Santiago de Compostela (USC), 15782 Santiago de Compostela, Spain
Instituto de Química Física de Los Materiales, Medio Ambiente y Energía, Universidad de Buenos Aires, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), C1428EHA Buenos Aires, Argentina
Palabras clave:Aqueous dispersions; Cryogenic techniques; Electrically conductive; High aspect ratio; Liquid crystalline system; Macroporous; Poly(vinyl alcohol) (PVA); Silver nanowires; Aspect ratio; Freezing; Hybrid materials; Liquid crystals; Polymers; Silver
Año:2012
Volumen:22
Número:18
Página de inicio:9195
Página de fin:9201
DOI: http://dx.doi.org/10.1039/c2jm16329b
Título revista:Journal of Materials Chemistry
Título revista abreviado:J. Mater. Chem.
ISSN:09599428
CODEN:JMACE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v22_n18_p9195_Romeo

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Citas:

---------- APA ----------
Romeo, H.E., Hoppe, C.E., López-Quintela, M.A., Williams, R.J.J., Minaberry, Y. & Jobbágy, M. (2012) . Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds. Journal of Materials Chemistry, 22(18), 9195-9201.
http://dx.doi.org/10.1039/c2jm16329b
---------- CHICAGO ----------
Romeo, H.E., Hoppe, C.E., López-Quintela, M.A., Williams, R.J.J., Minaberry, Y., Jobbágy, M. "Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds" . Journal of Materials Chemistry 22, no. 18 (2012) : 9195-9201.
http://dx.doi.org/10.1039/c2jm16329b
---------- MLA ----------
Romeo, H.E., Hoppe, C.E., López-Quintela, M.A., Williams, R.J.J., Minaberry, Y., Jobbágy, M. "Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds" . Journal of Materials Chemistry, vol. 22, no. 18, 2012, pp. 9195-9201.
http://dx.doi.org/10.1039/c2jm16329b
---------- VANCOUVER ----------
Romeo, H.E., Hoppe, C.E., López-Quintela, M.A., Williams, R.J.J., Minaberry, Y., Jobbágy, M. Directional freezing of liquid crystalline systems: From silver nanowire/PVA aqueous dispersions to highly ordered and electrically conductive macroporous scaffolds. J. Mater. Chem. 2012;22(18):9195-9201.
http://dx.doi.org/10.1039/c2jm16329b