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Abstract:

A simple patterning method is presented, using dewetting as a surface exotemplate generating technique, to produce disk-like features of micron to submicron size. The localization of the templates is such that a large area of the substrate is covered when compared with other techniques like colloidal templating or nanosphere lithography. The method is accessible and convenient and can be used to pattern areas of several dm2. Hierarchically ordered mesoporous SiO2 thin films possessing submicron sized cavities were prepared by combining this patterning method with sol-gel and surfactant templation. The mesopore arrangement was found to be severely influenced by the constraints imposed by the surface topology, leading to a different crystalline orientation. © 2009 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films
Autor:Zelcer, A.; Wolosiuk, A.; Soler-Illia, G.J.A.A.
Filiación:Gerencia de Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral Paz 1499 (B1650KNA) San Martín, Buenos Aires, Argentina
DQIAyQF, FCEN, Ciudad Universitaria, Pabellón II C1428EHA, Buenos Aires, Argentina
CONICET, Centro Interdisciplinario de Nanociencia y Nanotecnología, Av. Rivadavia 1917 C1033AAJ, Buenos Aires, Argentina
Palabras clave:Colloidal templating; Crystalline orientations; De-wetting; Mesopore; Nano Sphere Lithography; Ordered mesoporous; Patterning methods; Submicron size; Submicron-sized; Surface patterning; Surface topology; Templation; Gelation; Silicon compounds; Surface active agents; Thin films
Año:2009
Volumen:19
Número:24
Página de inicio:4191
Página de fin:4196
DOI: http://dx.doi.org/10.1039/b902378j
Título revista:Journal of Materials Chemistry
Título revista abreviado:J. Mater. Chem.
ISSN:09599428
CODEN:JMACE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09599428_v19_n24_p4191_Zelcer

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Citas:

---------- APA ----------
Zelcer, A., Wolosiuk, A. & Soler-Illia, G.J.A.A. (2009) . Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films. Journal of Materials Chemistry, 19(24), 4191-4196.
http://dx.doi.org/10.1039/b902378j
---------- CHICAGO ----------
Zelcer, A., Wolosiuk, A., Soler-Illia, G.J.A.A. "Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films" . Journal of Materials Chemistry 19, no. 24 (2009) : 4191-4196.
http://dx.doi.org/10.1039/b902378j
---------- MLA ----------
Zelcer, A., Wolosiuk, A., Soler-Illia, G.J.A.A. "Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films" . Journal of Materials Chemistry, vol. 19, no. 24, 2009, pp. 4191-4196.
http://dx.doi.org/10.1039/b902378j
---------- VANCOUVER ----------
Zelcer, A., Wolosiuk, A., Soler-Illia, G.J.A.A. Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films. J. Mater. Chem. 2009;19(24):4191-4196.
http://dx.doi.org/10.1039/b902378j