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Abstract:

The natural attenuation of oil spill contaminated soils, with different exposure times, in Patagonian environment was evaluated by the use of several parameters to quantify the degree of changes in the composition. Column (CC) and gas chromatography (GC); UV-visible and 1H NMR techniques were used to determine compositional and structural indexes. The results show that the nC18/Phytane GC index, that was 1.5 for crude oil, decreased with exposure time to values between 0.97-0.17 in the residues. The percentages for the four aliphatic (H1 - H4) and the aromatic (HA) proton types, determined by 1H NMR, were: 12.9-34.4 (H1), 43.3-60.2 (H2), 4.24-24.2 (H3), 1.33-17.9 (H4), and 0.44-4.81 (HA), in crude oil and residues, respectively. Furthermore, the characterization of significant 1H NMR signals indicated the presence of carboxylic acid hydrogens in the polar fraction of the crude oil and of residues of two years age. The Principal Components Analysis (PCA) of the parameters determined by CC, GC and NMR showed that the first three principal components (1st, 2nd, and 3rd PC), accounted for more than 84% of variance. The 1st PC is largely influenced by H3, H1, H4, H2, and the nC18/Phytane GC parameter, in the order given. The evaluation of the different parameters by PCA suggests that 1H NMR is more useful than GC to evaluate the degree of the chemical transformations of oil spills in soils. © Taylor & Francis, 2008.

Registro:

Documento: Artículo
Título:Natural attenuation of oil spills in Patagonian soils. Characterization by 1H NMR spectroscopy
Autor:Ríos, S.M.; Nudelman, N.S.
Filiación:Department of Chemistry, Universidad Nacional de la Patagonia San Juan Bosco, Ciudad Universitaria, km4, Comodoro Rivadavia, (9004) Chubut, Argentina
Department of Organic Chemistry, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina
Palabras clave:Compositional parameters; Environmental exposure; NMR spectra of petroleum samples; Oil spill behavior; Patagonian soils; Petroleum residues; aliphatic compound; aromatic compound; carboxylic acid; hydrocarbon; petroleum; Gas chromatography; Nuclear magnetic resonance spectroscopy; Oil spills; Parameter estimation; Soil surveys; carboxylic acid; crude oil; gas chromatography; natural attenuation; nuclear magnetic resonance; oil spill; principal component analysis; soil pollution; transformation; analysis of variance; article; chemical analysis; chemical composition; column chromatography; environmental impact; exposure; gas chromatography; oil spill; parameter; principal component analysis; proton nuclear magnetic resonance; proton transport; quantitative analysis; soil analysis; soil pollution; ultraviolet radiation; Argentina; Biodegradation, Environmental; Chromatography, Gas; Fertilizers; Magnetic Resonance Spectroscopy; Petroleum; Principal Component Analysis; Soil; Soil Pollutants; Patagonia; South America
Año:2008
Volumen:29
Número:1
Página de inicio:23
Página de fin:33
DOI: http://dx.doi.org/10.1080/09593330802008446
Título revista:Environmental Technology
Título revista abreviado:Environ. Technol.
ISSN:09593330
CODEN:ENVTE
CAS:petroleum, 8002-05-9; Fertilizers; Petroleum; Soil; Soil Pollutants
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09593330_v29_n1_p23_Rios

Referencias:

  • Nudelman, N., Ríos, S.M., Katusich, O., Interactions between crude oil and Patagonian soil as a function of the soil clay-water contents (2000) Environ. Technol, 21, pp. 437-447
  • Sugiura, K., Ishihara, M., Shimauchi, T., Harayama, S., Physicochemical properties and biodegradability of crude oil (1997) Environ. Sci. Technol, 31, pp. 45-51
  • Nudelman, N., Ríos, S.M., Interaction of oil residues in Patagonian soil (2002) Interfacial Applications in Environmental Engineering, Marcel Dekker Publication (ed.), pp. 139-164. , New York, U.S.A, pp
  • Dutta, T.K., Harayama, S., Fate of crude oil by the combination of photooxidation and biodegradation (2000) Environ. Sci. Technol, 34, pp. 1500-1505
  • Nudelman, N., Ríos, S.M., Katusich, O., Organic co-solvent effect on the estimation of the equilibrium aqueous concentrations of the oil residuals in Patagonian soils (2002) Environ. Technol, 23, pp. 961-971
  • Wild, S.R., Jones, K.C., Polynuclear aromatic hydrocarbons in the United Kingdon environment: A preliminary source inventory and budget (1995) Environ. Pollut, 88, pp. 91-108
  • Douglas, G.S., Bence, A.E., Prince, R.C., McMillen, S.J., Butler, E.L., Environmental stability of selected petroleum hydrocarbon source and weathering ratios (1996) Environ. Sci. Technol, 30, pp. 2332-2339
  • Barakat, A.O., Qian, Y., Kim, M., Kennicutt, M.C., Chemical characterization of naturally weathered oil residues in arid terrestrial environment in Al-Alamein, Egypt (2001) Environ. Int, 27, pp. 291-310
  • Karimi-Lotfabad, S., Pickard, M., Gray, M., Reactions of polynuclear aromatic hydrocarbons on soil (1996) Environ. Sci. Technol, 30, pp. 1145-1151
  • Tomczyk, N.A., Winans, R.E., On the nature and origin of acidic species in petroleum. 1. Detailed acid type distribution in a California crude oil (2001) Energ. Fuels, 15, pp. 1498-1504
  • Tang, J., Carroquino, M.J., Robertson, B.K., Alexandre, M., Combined effect of sequestration and bioremediation in reducing the bioavailability of polycyclic aromatic hydrocarbons in soil (1998) Environ. Sci. Technol, 32, pp. 3586-3590
  • Macleod, C.J.A., Semple, K.T., Influence of contact time on extractability and degradation of pyrene in soils (2000) Environ. Sci. Technol, 34, pp. 4952-4957
  • Northcott, G.L., Jones, K.C., Partitioning, extractability, and formation of nonextractable PAH residues in soil. 1. Compound differences in aging and sequestration (2001) Environ. Sci. Technol, 35, pp. 1103-1113
  • Northcott, G.L., Jones, K.C., Partitioning, extractability, and formation of nonextractable PAH residues in soil. 2. Effects on compound dissolution behavior (2001) Environ. Sci. Technol, 35, pp. 1111-1117
  • Short, J., Heintz, R., Identification of Exxon Valdez oil in sediments and tissues from Prince William Sound and the Northwestern Gulf of Alaska based on a PAH weathering model (1997) Environ. Sci. Technol, 31, pp. 2375-2384
  • Johnson, M.D., Keinath II, T.M., Weber, W.J., A distributed reactivity model for sorption by soils and sediments. 14. Characterization and modeling of phenanthrene desorption rates (2001) Environ. Sci. Technol, 35, pp. 1688-1695
  • Prince, R.C., Garrett, R.M., Bare, R.E., Grossman, M.J., Townsend, T., Suflita, J.M., Lee, K., Lessard, R.R., The roles of photooxidation and biodegradation in long-term weathering of crude and heavy fuel oils (2003) Spill Sci. Tech. Bull, 8 (2), pp. 145-156
  • Dutta, T.K., Harayama, S., Analysis of long-side-chain alkylaromatics in crude oil for evaluation of their fate in the environment (2001) Environ. Sci. Technol, 35, pp. 102-107
  • Rafenomanantsoa, A., Nicole, D., Rubini, P., Lauer, J.C., NMR and FIMS structural analysis of the oil obtained from the pyrolysis of Bemolanga tar-sand bitumen (Madagascar) according to a post combustion process (1998) Fuel, 77, pp. 33-41
  • Hairber, S., Buddrus, J., Isolated methyl groups as new structural parameters for petroleum crudes (2002) Fuel, 81, pp. 981-987
  • Wolfe, D.A., Galt, J.A., Watabayashi, G., Short, J., Claire, C.O., Rice, S., Michel, J., Sale, D., The fate of the oil spilled from the Exxon Valdez (1994) Environ. Sci. Technol, 28, pp. 561-573
  • Dragun, J., (1998) The Soil Chemistry of Hazardous Materials, , 2nd Edition, Amhert Scientific Publishers, Amherst, Massachusetts
  • Commendatore, M.G., Estevez, J.L., Colombos, J.C., Hydrocarbons in coastal sediments of Patagonia, Argentina: Levels and probable sources (2000) Mar. Pollut. Bull, 40, pp. 989-998
  • Speight, J.G., (1991) The Chemistry and Technology of Petroleum, , Marcel Deccker, New Year
  • Kapur, G.S., Singh, A.P., Sarpal, A.S., Determination of aromatics and naphthenes in straight run gasoline by 1H NMR spectroscopy. Part I (2000) Fuel, 79, pp. 1023-1029
  • Yang, Y., Liu, B., Xi, H., Sun, X., Zhang, T., Study on relationship between the concentration of hydrocarbon groups in heavy oils and their structural parameter from 1H NMR spectra (2003) Fuel, 82, pp. 721-727
  • Burri, J., Crockett, R., Hany, R., Rentsch, D., Gasoline composition determined by 1H NMR spectroscopy (2003) Fuel, 83, pp. 187-193
  • Silverstein, R.M., Bassier, G.C., Morrill, T.C., (1991) Spectrometric Identification of Organic Compounds, , John Wiley and Sons, New York
  • Venkateswaran, K., Hoaki, T., Kato, M., Maruyama, T., Microbial degradation of resins fractionated from Arabian light crude oil (1995) Can. J. Microbiol, 41, pp. 418-424
  • Watson, J.S., Jones, D.M., Swannell, R.P.J., van Guin, A.C.T., Formation of carboxylic acids during aerobic biodegradation of crude oil and evidence of microbial oxidation of hopanes (2002) Org. Geochem, 33, pp. 1153-1169
  • Maki, H., Sasaki, T., Harayama, S., Photo-oxidation of biodegraded crude oil and toxicity of the photo-oxidized products (2001) Chemosphere, 44, pp. 1145-1151
  • Galimberti, R., Ghiselli, C., Chiaramonte, M.A., Acid polar compounds in petroleum: A new analytical methodology and applications as molecular migration indices (2000) Org. Geochem, 31, pp. 1375-1386
  • Ríos, S.M., Nudelman, N.S., Multilayer sorption model for the interactions between crude oil and clay in Patagonian soils (2005) J. Disp. Sci. Technol, 26, pp. 1-8
  • Yong, T.M., Mohamed, A., Warkentin, B., (1992) Principles of Contaminant Transport in Soils, , Elsevier, New York
  • Ríos, S.M., Nudelman, N.S., Katusich, O., Effects of solution and soil chemistry on the distribution of oil residual in Patagonian soil (2004) Latin Am. App. Res. J, 34, pp. 149-153
  • Ríos, S.M., (2005) PhD Diss. Abst, , Studies on the natural attenuation of oil spills in Patagonian soils. Universidad de Buenos Aires Argentine
  • Brandyik, J., Daling, S., Optimising oil spill dispersants as a function of oil type and weathering degree: A multivariate approach using partial least squares (PSL) (1998) Chemom. Intell. Lab. Syst, 42, pp. 73-91
  • Aske, N., Kallevik, H., Sjoblom, J., Water-in-crude oil emulsion stability studies by critical electric field measurement. Correlation to physico-chemical parameters and near-infrared spectroscopy (2002) J. Petrol. Sci. Eng, 36, pp. 1-17

Citas:

---------- APA ----------
Ríos, S.M. & Nudelman, N.S. (2008) . Natural attenuation of oil spills in Patagonian soils. Characterization by 1H NMR spectroscopy. Environmental Technology, 29(1), 23-33.
http://dx.doi.org/10.1080/09593330802008446
---------- CHICAGO ----------
Ríos, S.M., Nudelman, N.S. "Natural attenuation of oil spills in Patagonian soils. Characterization by 1H NMR spectroscopy" . Environmental Technology 29, no. 1 (2008) : 23-33.
http://dx.doi.org/10.1080/09593330802008446
---------- MLA ----------
Ríos, S.M., Nudelman, N.S. "Natural attenuation of oil spills in Patagonian soils. Characterization by 1H NMR spectroscopy" . Environmental Technology, vol. 29, no. 1, 2008, pp. 23-33.
http://dx.doi.org/10.1080/09593330802008446
---------- VANCOUVER ----------
Ríos, S.M., Nudelman, N.S. Natural attenuation of oil spills in Patagonian soils. Characterization by 1H NMR spectroscopy. Environ. Technol. 2008;29(1):23-33.
http://dx.doi.org/10.1080/09593330802008446